The Impact of Dual‐Salt Electrolyte with Low Fluorine Content on the Performance of Layered Transition Metal Oxides for Sodium‐Ion Batteries DOI Creative Commons

Yiyue Lu,

M. Aslam, Christian Leibing

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: May 8, 2025

Abstract In this work, the characterization of novel electrolytes based on combination propylene carbonate (PC) solvent with sodium bis(fluorosulfonyl)imide (NaFSI) and difluoro(oxalato)borate (NaDFOB), as well their application in sodium‐ion batteries (SIBs) is presented. The results show that dual‐salt have a wide electrochemical stability window, excellent transport properties, mostly suppress anodic dissolution. When combined P2‐Na 2/3 Al 1/9 Fe Mn Ni O 2 (P2‐AFMNO) cathode electrode for SIBs operating at 4.3 V vs Na + /Na, they enable high performance stability. XPS investigation revealed related to formation thin homogeneous electrolyte interphase (CEI) surface.

Language: Английский

Diffusion Kinetics of ‘‘Layered“ Na-TMO2: regulation of Na+ layer stability by dual ion doping in hybrid electrolyte DOI Creative Commons
Nikita Bhardwaj,

Kazuyuki Dan,

Deependra Jhankal

et al.

Deleted Journal, Journal Year: 2025, Volume and Issue: unknown, P. 100055 - 100055

Published: March 1, 2025

Language: Английский

Citations

0

Boron Nanoengineering: Unveiling Breakthroughs and Challenges in Next-Generation Lithium Batteries DOI
Felipe M. de Souza, Phuong V. Pham, Ram K. Gupta

et al.

Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 179844 - 179844

Published: March 1, 2025

Language: Английский

Citations

0

Assessing the Efficacy of Seawater Batteries Using NASICON Solid Electrolyte DOI Creative Commons
Mihaela Iordache, Anișoara Oubraham,

Mihaela Bazga

et al.

Applied Sciences, Journal Year: 2025, Volume and Issue: 15(7), P. 3469 - 3469

Published: March 21, 2025

The need to reduce greenhouse gas emissions and guarantee a stable reliable energy supply has resulted in an increase the demand for sustainable storage solutions over last decade. Rechargeable batteries with solid-state electrolytes (SSE) have become focus area due their potential increased density, longer cycle life, safety conventional liquid electrolytic batteries. superionic sodium conductor (NASICON) Na3Zr2Si2PO12 gained lot of attention among ESS because its exceptional electrochemical properties, which make it promising candidate sodium-ion NASICON’s open frame structure makes possible transport ions efficiently even at room temperature, while wide window enables high-voltage operation reduces side reactions, resulting safer battery performance. Furthermore, NASICON is more compatible ion systems, can help electrode interface issues, simple process. characteristics highly desirable vital material aim this study prepare characterize ceramic membranes that contain Na3.06Zr2Si2PO12 Na3.18Zr2Si2PO12, measure stability seawater serve as solid electrolytes. surface analysis revealed powder specific 7.17 m2 g−1, than Na3.18Zr2Si2PO12 powder’s 6.61 g−1. During measurement, samples showed ionic conductivities 8.5 × 10−5 6.19 10−4 S cm−1. Using platinum/carbon (Pt/C) catalyst source cathodes (Na+), were charged discharged using different current values (50 100 µA) testing. In cell, membrane Pt/C catalysts 0.00033 g platinum content was used assess reproducibility constant 2 h. After h operation, charging discharging voltage efficiency 71% (50/100 83.5% (100 µA). electric power level observed number operating cycles.

Language: Английский

Citations

0

Effect of In Situ-Generated CeO2 in Na0.67MnO2 cathode material for High-Rate and high-capacity Na-ion batteries: An experimental and theoretical study DOI

Min Shen,

Mingyi Su,

Bingbing Huang

et al.

Ceramics International, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Language: Английский

Citations

0

Recent advances in Sodium-ion battery research: Materials, performance, and commercialization prospects DOI
Razu Shahazi,

Mashrufa Akther,

Joy Malo

et al.

Deleted Journal, Journal Year: 2025, Volume and Issue: 3(1), P. 2951 - 2951

Published: April 10, 2025

Sodium-ion (Na-ion) batteries are becoming more popular as a budget-friendly and eco-friendly substitute for lithium-ion batteries, thanks to the plentiful supply of sodium its reduced raw material expenses. Recent developments in sodium-ion battery research have concentrated on enhancing performance crucial elements such cathodes, anodes, electrolytes. Important advancements been achieved creation high-capacity including layered transition metal oxides, Prussian blue analogs, polyanionic compounds, well anode materials like hard carbon alloy-based compounds. Research electrolytes, solid-state ionic liquid options, aims improve conductivity, cycle stability, prevent issues dendrite formation. Although generally lower energy density compared lithium-based they exhibit significant potential large-scale uses grid storage, where cost life important than density. This review highlights recent breakthroughs Na-ion technology discusses growing prospects commercialization near future.

Language: Английский

Citations

0

Anion engineering of Na3V2(PO4)2F3 nanosheets coexisting with OCNTs for high performance in sodium-ion batteries DOI
Wenjun Luo, C. Ji, Chuanyang Li

et al.

Journal of Solid State Electrochemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 14, 2025

Language: Английский

Citations

0

Polymer-assisted yttrium surface-enrichment doping of O3-type NaNi1/3Fe1/3Mn1/3O2 cathodes to enhance high voltage and air stability in sodium-ion batteries DOI

Yeonghun Park,

Yun Hee Noh,

Wonchang Choi

et al.

Journal of Materials Chemistry A, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Y-surface-doped NaNi 1/3 Fe Mn O 2 was used as a cathode for Na-ion battery. A uniform Y surface-enriched region successfully formed with the assistance of PVA.

Language: Английский

Citations

0

Prussian blue analogues in sodium-ion batteries: comparison with lithium technologies, recent advances, and prospects DOI
Anna Komenda, Jędrzej Piątek

Renewable and Sustainable Energy Reviews, Journal Year: 2025, Volume and Issue: 217, P. 115677 - 115677

Published: April 11, 2025

Language: Английский

Citations

0

Introducing symmetry breaking to regulate the band structure for achieving superior rate performance in iron-based phosphate cathode for sodium-ion batteries DOI

Hexiao Zhang,

Yuhang Xin, Yingshuai Wang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162831 - 162831

Published: April 1, 2025

Language: Английский

Citations

0

Core–shell Ni/Fe/Mn@Cu micron particles with high tap density serving as an effective precursor for preparing high-performance cathode materials for sodium-ion battery DOI
Lunlun Gong, Rensheng Liu, Juan Li

et al.

Journal of Materials Science, Journal Year: 2025, Volume and Issue: unknown

Published: April 20, 2025

Language: Английский

Citations

0