Materials, Journal Year: 2024, Volume and Issue: 17(24), P. 6115 - 6115
Published: Dec. 14, 2024
Copper flotation tailings (FTs), resulting from the separation and beneficiation processes of ores, are a significant source environmental pollution (acid mine drainage, toxic elements leaching, dust generation). The most common disposal method for this industrial waste is dumping. However, due to their favorable physical chemical properties—the high content aluminosilicate minerals (60–90%)—flotation can be effectively treated reused through geopolymerization technology, thereby adding value waste. objective study was evaluate potential utilizing FTs produce sustainable materials. Geopolymers based on natural zeolite (NZ), sodium-modified (NaZ), fly ash (FA) were prepared using 20%, 35%, 50% FTs, activated with 10 M NaOH solution. investigated influence Ca/Si, Si/Al, Na/Al molar ratios structural, thermal, mechanical properties (XRD, TG/DTG unconfined compressive strength, UCS), contaminant immobilization (TCLP method) geopolymers. Geochemical modeling via PHREEQC program employed interpret results. findings indicated that UCS decreased in zeolite-based geopolymers as FT increased inertness low calcium system (Ca/Si ≤ 0.3), contrast FA-based geopolymer. highest 44.3 MPa recorded an geopolymer containing tailings, optimal 0.4 3.0 1.1 Na/Al. In conclusion, process has been determined suitable technological approach treatment reuse FTs.
Language: Английский