Ruthenium-catalyzed electrochemical C–H activation for organic synthesis DOI Creative Commons

Rajaram Maayuri,

Parthasarathy Gandeepan

Electrochemistry, Journal Year: 2024, Volume and Issue: unknown, P. 219 - 244

Published: Nov. 27, 2024

Transition metal-catalyzed C–H activation is a powerful tool in organic synthesis, providing high atom and step economy while reducing waste. Among the 4d 5d transition metals, ruthenium stands out for its affordability effectiveness under mild reaction conditions diverse reactions. Recently, advances metallaelectrocatalysis have allowed ruthenium-catalyzed transformations to use electricity instead of traditional oxidants, enhancing selectivity costs This review highlights recent progress electrochemical functionalization reactions, showcasing key developments innovations.

Language: Английский

Implementation of 2,2′-azobispyridine radical mono- and dianions in dinuclear rare earth metal complexes DOI Creative Commons
Francis Delano, Selvan Demir

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(82), P. 11702 - 11705

Published: Jan. 1, 2024

The seminal isolation of a dinuclear rare earth metal complex comprising bridging 2,2'-azobispyridyl radical anion, [(Cp

Language: Английский

Citations

0
Ruthenium-catalyzed electrochemical C–H activation for organic synthesis DOI Creative Commons

Rajaram Maayuri,

Parthasarathy Gandeepan

Electrochemistry, Journal Year: 2024, Volume and Issue: unknown, P. 219 - 244

Published: Nov. 27, 2024

Transition metal-catalyzed C–H activation is a powerful tool in organic synthesis, providing high atom and step economy while reducing waste. Among the 4d 5d transition metals, ruthenium stands out for its affordability effectiveness under mild reaction conditions diverse reactions. Recently, advances metallaelectrocatalysis have allowed ruthenium-catalyzed transformations to use electricity instead of traditional oxidants, enhancing selectivity costs This review highlights recent progress electrochemical functionalization reactions, showcasing key developments innovations.

Language: Английский

Citations

0