Recent advancements in Ni/photoredox dual catalysis for the Csp3-Csp3 cross-coupling reactions DOI Creative Commons

Qi-Yun Huang,

Min Shi

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(17), P. 4913 - 4925

Published: Jan. 1, 2024

This minireview highlights recent advancements in the past five years (since 2019) Ni/photoredox dual catalysis for Csp 3 –Csp cross-coupling reactions.

Language: Английский

Halogen‐Atom Transfer Enabled Catalytic Enantioselective Coupling to Chiral Trifluoromethylated Alkynes via Dual Nickel and Photocatalysis DOI

Shanya Lu,

Zihao Hu,

Dong Wang

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(28)

Published: April 15, 2024

With halogen-atom transfer as an effective tool, a novel catalytic enantioselective protocol to generate chiral trifluoromethylated alkynes has been established by cooperative photoredox and nickel catalysis system, providing straightforward modular route access this type of product in good yields enantioselectivities. The process is essential for the reaction strategy offers another promising way utilize alkyl halides with highly negative reduction potentials. It firstly expands nickel-catalyzed asymmetric reductive cross-couplings organohalides from traditional single-electron transfer.

Language: Английский

Citations

10
Dual Nickel- and Photoredox-Catalyzed Asymmetric Reductive Cross-Couplings: Just a Change of the Reduction System? DOI

Wenhao Xu,

Tao Xu

Accounts of Chemical Research, Journal Year: 2024, Volume and Issue: 57(14), P. 1997 - 2011

Published: July 4, 2024

ConspectusIn recent years, nickel-catalyzed asymmetric coupling reactions have emerged as efficient methods for constructing chiral C(sp

Language: Английский

Citations

7
Mechanistic Insights into the Visible-Light-Driven O–Arylation of Carboxylic Acids Catalyzed by Xanthine-Based Nickel Complexes DOI Creative Commons
Rafael E. Rodríguez‐Lugo,

J. Sander,

Simon Dietzmann

et al.

Chemical Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Experimental and theoretical investigations were conducted to gain insight into the mechanism of light-driven Ni-catalyzed arylation carboxylates.

Language: Английский

Citations

0
Enantioconvergent Cross-Electrophile Coupling of 2-Aryloxetanes with Aryl and Vinyl Halides, or Anhydrides DOI
Linli Zhang, Wei‐Chen Wang, Chaoren Shen

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 7578 - 7587

Published: April 22, 2025

Language: Английский

Citations

0
From Structure to Function: Designing Iridium Catalysts with Spin-Forbidden Excitation for Low-Energy Light-Driven Reactions DOI
Eva Bednářová, Robin Grotjahn,

Chenxi Lin

et al.

Journal of the American Chemical Society, Journal Year: 2025, Volume and Issue: unknown

Published: April 7, 2025

Herein we describe a comprehensive study of ligand effects on optoelectronic properties series Ir(III) catalysts which undergo formally spin-forbidden excitation using low-energy light. We demonstrate that electronic and steric tuning several variables can be explained by their impact the HOMO LUMO energies complex. Density functional theory calculations catalysts' adiabatic triplet agree with experimental results to within 0.05 eV average. As many these subtle are independent each other, merger them in single complex tends have an additive effect thus succeeded developing family highly oxidizing iridium photocatalysts operate excitation.

Language: Английский

Citations

0
Nickel-Catalyzed Enantioselective Three-Component 1,2-Alkylarylation of Alkenes with Arylboronic Acids as Arylation Reagents DOI
Zhaodong Zhu, Jingjing Wu

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 7833 - 7841

Published: April 25, 2025

Language: Английский

Citations

0
Nickel-catalyzed C(sp2)−C(sp3) cross-coupling to access benzyl Bpins of arylboronic acids with α-halo boronic esters DOI Creative Commons

Yang Sun,

Chongwei Zhu, Hui Wang

et al.

Communications Chemistry, Journal Year: 2025, Volume and Issue: 8(1)

Published: May 6, 2025

Language: Английский

Citations

0
Halogen‐Atom Transfer Enabled Catalytic Enantioselective Coupling to Chiral Trifluoromethylated Alkynes via Dual Nickel and Photocatalysis DOI

Shanya Lu,

Zihao Hu,

Dong Wang

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: 136(28)

Published: April 15, 2024

Abstract With halogen‐atom transfer as an effective tool, a novel catalytic enantioselective protocol to generate chiral trifluoromethylated alkynes has been established by cooperative photoredox and nickel catalysis system, providing straightforward modular route access this type of product in good yields enantioselectivities. The process is essential for the reaction strategy offers another promising way utilize alkyl halides with highly negative reduction potentials. It firstly expands nickel‐catalyzed asymmetric reductive cross‐couplings organohalides from traditional single‐electron transfer.

Language: Английский

Citations

1
Recent advancements in Ni/photoredox dual catalysis for the Csp3-Csp3 cross-coupling reactions DOI Creative Commons

Qi-Yun Huang,

Min Shi

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(17), P. 4913 - 4925

Published: Jan. 1, 2024

This minireview highlights recent advancements in the past five years (since 2019) Ni/photoredox dual catalysis for Csp 3 –Csp cross-coupling reactions.

Language: Английский

Citations

0