Microchemical Journal, Journal Year: 2022, Volume and Issue: 185, P. 108301 - 108301
Published: Dec. 6, 2022
Language: Английский
Biosensors and Bioelectronics, Journal Year: 2022, Volume and Issue: 205, P. 113943 - 113943
Published: Jan. 7, 2022
Language: Английский
Citations
188
Small, Journal Year: 2022, Volume and Issue: 19(2)
Published: Nov. 22, 2022
Abstract MXene emerged as decent 2D material and has been exploited for numerous applications in the last decade. The remunerations of ideal metallic conductivity, optical absorbance, mechanical stability, higher heterogeneous electron transfer rate, good redox capability have made a potential candidate biosensing applications. hydrophilic nature, biocompatibility, antifouling, anti‐toxicity properties opened avenues to perform vitro vivo analysis. In this review, concept, operating principle, detailed mechanism, characteristic are comprehensively assessed compiled along with breakthroughs fabrication conjugation strategies development unique electrochemical biosensors. Further, current challenges summarized suggested future aspects. This review article is believed shed some light on will open new opportunities advanced translational application bioassays.
Language: Английский
Citations
122
ECS Sensors Plus, Journal Year: 2022, Volume and Issue: 1(3), P. 034401 - 034401
Published: June 28, 2022
Hydrogen peroxide (H 2 O ) is extensively used for sterilization purposes in the food industries and pharmaceuticals as an antimicrobial agent. According to Food Agriculture Organization (FAO), permissible level of H milk range 0.04 0.05% w/v, so it has been prohibited use a preservative Herein, we reported electrochemical sensing samples using activated glassy carbon electrode (AGCE). For this purpose, activation GCE was carried out 0.1 M SO 4 by continuous potential sweeping between −0.7 1.8 V 25 cycles. The AGCE showed redox peak at -0.18 neutral medium corresponding quinone functional groups present on surface. studied (pH 7.4) PBS electro-catalysis . surface analysed Raman spectroscopy contact angle measurements. In addition, surface, found be 85° which indicated hydrophilic nature different optimization parameters such (1) effect electrolyte ions, (2) electrooxidation cycles, (3) oxidation windows were improve process. Finally, detect from 10 mM limit detection (LOD) 0.053 with linear correlation coefficient (R 0.9633. selectivity sensor towards presence other interferents. sensitivity calculated 17.16 μ A mol cm −2 commercial application verified testing recovery 95%–98%.
Language: Английский
Citations
96
ACS Applied Nano Materials, Journal Year: 2022, Volume and Issue: 5(3), P. 3252 - 3264
Published: March 2, 2022
As nanomaterials have a high surface-to-volume ratio, they very specific features and therefore can be employed in variety of applications. The development electrochemical sensors based on novel nanocatalysts for detecting hazardous compounds is primary concern. In the present work, we proposed synthesis protocol MoS2 sphere-combined sulfur-doped Ti3C2 MXene nanocatalyst (MoS2/S-Ti3C2) evaluated its sensing performance. structural characterization this revealed that it was successfully synthesized using hydrothermal process. addition, activity different quantities MoS2/S-Ti3C2 loaded onto laser-induced graphene electrode (LGE) investigated, discovered 8 μL has highest activity. as-fabricated MoS2/S-Ti3C2/LGE used as medium aristolochic acid (AA) roxarsone (ROX) detection. Interestingly, sensor exhibited sensitivity 69.955 32.488 μA μM–1 cm–2 AA 56.972 19.688 ROX with detection limit 1.65 2.31 nM, respectively, concentration range 0.01–875.01 μM. influence few selected potential interferences does not show significant effect ROX, making best device practicability analysis. Moreover, practical application fabricated asarum sieboldii, human urine, blood serum samples recovery rate 97.00–99.00%.
Language: Английский
Citations
78
Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(26)
Published: March 24, 2023
Abstract With the demand for low‐power‐operating artificial intelligence systems, bio‐inspired memristor devices exhibit potential in terms of high‐density memory functions and emulation synaptic dynamics human brain. The 2D material MXene attracts considerable interest use resistive‐switching synapse owing to its excellent physicochemical properties devices. However, few memristive that display increased switching performances are reported, with no significant results. Herein, conductivity (Ti 3 C 2 T x ) is engineered via etching oxidation enhance performance device. exceptional partially oxidized memristors include large windows low threshold biases, complex spike‐timing‐dependent plasticity rules also emulated. distribution, reliable retention time (10 4 s), distinct resistance states a high ON–OFF ratio (>10 main memory‐related features this experimentally determined potentials optimized device uniformly distributed, according statistical probability‐based approach. This investigation may promote essential non‐volatile storage systems field innovative nanoelectronic
Language: Английский
Citations
60
Progress in Materials Science, Journal Year: 2023, Volume and Issue: 139, P. 101169 - 101169
Published: July 28, 2023
The excessive inlet of contaminants into water is affecting its quality adversely which not recommended for health. Therefore, investigating economical, scalable, efficient, and faster approaches treatment crucual. In this direction, nanostructures (NSs) due to easy fabrication tailored properties are emerging technology management via detecting, monitoring, removing the targeted contaminants. Among several NSs, metal oxides (MO)-NSs have performed desired sensing remediation Considering state-of-the-art, review a first-time attempt explore design development available smart MO-NSs investigated management. This comprehensive article presents careful critical discussion decade (2011 2022) advancements based on (via electrochemical optical signalling), eradication adsorption, photocatalytic degradation, ultrasound-assisted-catalytic degradation/adsorption, ultrafiltration), simultaneous detection pollutants, disinfection. Moreover, challenges associated with focused state-of-the-art management, alternative approaches, possible future aspects critically delineated. Finally, project MO-NSs-based futuristic approach as green technologies deliver clean everyone greatly contributes community concerned per United Nations Sustainable Development Goal 6 (SDG6).
Language: Английский
Citations
59
PhotoniX, Journal Year: 2023, Volume and Issue: 4(1)
Published: May 5, 2023
Abstract Sensing devices are key nodes for information detection, processing, and conversion widely applied in different fields such as industrial production, environmental monitoring, defense. However, increasing demand of these has complicated the application scenarios diversified detection targets thereby promoting continuous development sensing materials methods. In recent years, Ti n+1 C n T x ( = 1, 2, 3) MXenes with outstanding optical, electrical, thermal, mechanical properties have been developed ideal candidates to apply physical, chemical, biological fields. this review, depending on optical electrical signals, we systematically summarize nine categories sensors strain, gas, fluorescence sensors. The excellent allow its further emerging intelligent bionic devices, including smart flexible E-skin, neural network coding learning, soft robot, well artificial eardrum, which all discussed briefly review. Finally, present a positive outlook potential future challenges perspectives MXene-based shown vigorous momentum applications can drive an number new technologies.
Language: Английский
Citations
54
Catalysts, Journal Year: 2023, Volume and Issue: 13(5), P. 802 - 802
Published: April 26, 2023
The development of transition metal (TM) catalysts to replace precious metals has garnered increasing interest. Specifically, platinum (Pt)-based have been extensively investigated for their electrochemical performance in hydrogen evolution reaction (HER), which offer a clean means producing fuel without carbon emissions. However, the reliance on Pt-based hindered progress HER development. Therefore, researchers explored metal-organic frameworks (MOFs) as substitute noble address this issue. Nevertheless, low electroconductivity pure MOFs restricts application fields. To overcome limitation, MXenes emerged promising two-dimensional (2D) material coupling with create an electrocatalyst high electrical conductivity, large surface area, and tunable structure. In study, we report synthesis Ti3C2Tx (MXene) nanosheet-encapsulated catalyst (Ti3C2Tx@ZIF-8) activity cost by encapsulating precursor ZIF-8 alkaline media. exhibits overpotential only 507 mV at 20 mA/cm2 Tafel slope value 77 mV/dec. Additionally, cyclic voltammetry (CV) indicates active area (ECSA) 122.5 cm2, chronopotentiometry demonstrates stable nature over h any significant changes value. excellent properties Ti3C2Tx@ZIF-8 suggest its potential energy conversion applications.
Language: Английский
Citations
42
ACS Nano, Journal Year: 2024, Volume and Issue: 18(18), P. 11675 - 11687
Published: April 23, 2024
Ultrathin MXene-based films exhibit superior conductivity and high capacitance, showing promise as electrodes for flexible supercapacitors. This work describes a simple method to enhance the performance of supercapacitors by expanding stabilizing interlayer space between MXene flakes while controlling functional groups improve conductivity. Ti
Language: Английский
Citations
36
Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 507, P. 215746 - 215746
Published: Feb. 29, 2024
Language: Английский
Citations
29