Pharmaceutical Pollutants: Ecotoxicological Impacts and the Use of Agro-Industrial Waste for Their Removal from Aquatic Environments DOI Creative Commons
Ana Gabriela Estrada-Almeida,

María Luisa Castrejón-Godínez,

Patricia Mussali-Galante

et al.

Journal of Xenobiotics, Journal Year: 2024, Volume and Issue: 14(4), P. 1465 - 1518

Published: Oct. 15, 2024

Medicines are pharmaceutical substances used to treat, prevent, or relieve symptoms of different diseases in animals and humans. However, their large-scale production use worldwide cause release the environment. Pharmaceutical molecules currently considered emerging pollutants that enter water bodies due inadequate management, affecting quality generating adverse effects on aquatic organisms. Hence, alternatives for pharmaceuticals removal from have been sought; among them, agro-industrial wastes has proposed, mainly because its high availability low cost. This review highlights ecotoxicological related presence environments analyzes 94 investigations, 2012 2024, 17 antibiotics, highlighting sulfamethoxazole as most reported, well 6 non-steroidal anti-inflammatory drugs (NSAIDs) such diclofenac ibuprofen, 27 with pharmacological activities. The these was evaluated using wheat straw, mung bean husk, bagasse, bamboo, olive stones, rice pinewood, others. On average, 60% were transformed into biochar be a biosorbents removal. diversity experimental conditions studies makes it difficult stablish which waste greatest capacity; therefore, this review, drug mass rate (DMRR) calculated, parameter comparative purposes. Almond shell-activated showed highest antibiotics (1940 mg/g·h), while cork powder (CP) (10,420 mg/g·h) NSAIDs. Therefore, scientific evidence demonstrates is promising alternative substances.

Language: Английский

The Application of Chitosan-Based Adsorbents for the Removal of Hazardous Pollutants from Aqueous Solutions—A Review DOI Open Access
Małgorzata A. Kaczorowska, Daria Bożejewicz

Sustainability, Journal Year: 2024, Volume and Issue: 16(7), P. 2615 - 2615

Published: March 22, 2024

The development of simple, effective, economical, and environmentally friendly methods for removing hazardous substances anthropogenic origin from aquatic systems is currently one the greatest challenges, among others, due to variety pollutants transformations they may undergo in environment. In recent years, there has been an increased interest adsorption based on use natural polymers, including non-toxic chitosan (CS), which characterized by good coating properties, biocompatibility, biodegradability. This review concerns latest developments (since 2019) application novel chitosan-based materials removal (e.g., metal metalloid ions, synthetic dyes, pharmaceuticals) aqueous solutions, with particular emphasis their most important advantages limitations, as well potential impact sustainability.

Language: Английский

Citations

27

Immobilization: the promising technique to protect and increase the efficiency of microorganisms to remove contaminants DOI
Aya A. Najim, Ahmed Y. Radeef,

Ibrahim al‐Doori

et al.

Journal of Chemical Technology & Biotechnology, Journal Year: 2024, Volume and Issue: 99(8), P. 1707 - 1733

Published: March 8, 2024

Abstract Biodegradation of pollutants is one the most economical methods for their removal and usually accompanied by no production toxic by‐products. In general, this approach favored over others because it offers reduced expenses potential complete mineralization. order to enhance viability longevity bioremediation agents within polluted areas, becomes necessary immobilize cells. Cell immobilization refers procedure confining intact cells specific areas a device or material, without compromising essential biological functions. A wide variety carriers approaches have been used restriction various Immobilization techniques, such as microencapsulation, opened up new possibilities in biotechnology facilitating development artificial organs, cell therapies drug delivery systems. Researchers found promising outcomes applications through microorganisms. This enhances stability, reusability catalytic efficiency, making valuable strategy biocatalysis, other biotechnological processes. Notably, use immobilized microorganisms has led significant improvements pollutants, with some studies achieving 100% efficiency. When comparing degradation between free same time period, results demonstrated that achieved efficiency >21% more than microbial consortia. The primary objective review give an overview key scientific aspects related using cells, particular focus on techniques entrap © 2024 Society Chemical Industry (SCI).

Language: Английский

Citations

17

Recent insights into mechanism of modified bio-adsorbents for the remediation of environmental pollutants DOI
A. Saravanan,

S. Karishma,

P. Senthil Kumar

et al.

Environmental Pollution, Journal Year: 2023, Volume and Issue: 339, P. 122720 - 122720

Published: Oct. 13, 2023

Language: Английский

Citations

26

Future trends in dye removal by metal oxides and their Nano/Composites: A comprehensive review DOI Open Access
Meriem Kasbaji, Islam Ibrahim, Mehdi Mennani

et al.

Inorganic Chemistry Communications, Journal Year: 2023, Volume and Issue: 158, P. 111546 - 111546

Published: Oct. 4, 2023

Language: Английский

Citations

23

Research progress on the application of natural adsorbents in the treatment of livestock wastewater DOI Creative Commons

Jianle Li,

Yongde Liu,

Jiaxu Wang

et al.

Desalination and Water Treatment, Journal Year: 2024, Volume and Issue: 317, P. 100018 - 100018

Published: Jan. 1, 2024

With the increase of scale animal husbandry, negative effect nitrogen and phosphorus, antibiotics, heavy metals other pollutants in livestock wastewater has been increasing. Natural adsorption materials are a new type environmental protection that have attracted attention recent years. Many researchers developed natural using microorganisms, algae, plant derivatives industrial agricultural wastes. However, there no systematic review regarding adsorbents for purpose to treat wastewater. In this paper, their hazards were reviewed. The characteristics such introduced detail, research progress adsorbent on treatment was summarized. This is intended provide ideas references development application adsorbent.

Language: Английский

Citations

12

Photocatalytic Degradation of Maxilon Dye Pollutants using Nano‐Architecture Functional Materials: A Review DOI
Stephen Sunday Emmanuel, Ademidun Adeola Adesibikan, Christopher Olusola Olawoyin

et al.

ChemistrySelect, Journal Year: 2024, Volume and Issue: 9(15)

Published: April 17, 2024

Abstract The most essential task in the twenty‐first century is to fight alarming growing pollution aquatic body which effluent of one colouring dye categories called maxilon a major contributor. This review thus specifically focuses on use nanoparticles (NPs) for photocatalytic degradation contaminants water bodies. work empirically presented performance evaluation NPs degrading dyes under light irradiation alongside underlying operational mechanism. stability was also critically analyzed by looking at regenerability and reusability expended NPs. From study, it discovered that ⋅OH O 2 ⋅ played vital role genesis oxidizing capacity breakdown dye. Moreover, found greater than 80 % shortest period < 1 hour with pseudo‐first‐order (PFO) being common kinetic best‐fit describe adsorption process occurred shortly before during operation. At end, knowledge gaps were identified area regenerability, lifecycle analyses nano‐photocatalyst fabrication utilization, cost analysis industrial scale‐up, ecotoxicological pathways. findings this study can open up insightful innovation readers industries are interested pursuing zero insecurity.

Language: Английский

Citations

11

NiAlFe LTH /MoS2 p-n junction heterostructure composite as an effective visible-light-driven photocatalyst for enhanced degradation of organic dye under high alkaline conditions DOI
Chang‐Min Kim,

Mir Ferdous Chowdhury,

Hong Rae Im

et al.

Chemosphere, Journal Year: 2024, Volume and Issue: 358, P. 142094 - 142094

Published: April 20, 2024

Language: Английский

Citations

8

Influential lead uptake using dried and inactivated-fungal biomass obtained from Panaeolus papilionaceus: biological activity, equilibrium, and mechanism DOI Creative Commons
Zeynep Mine Şenol,

Zehra Saba Keskin,

Emine Dinçer

et al.

Biomass Conversion and Biorefinery, Journal Year: 2024, Volume and Issue: 15(5), P. 7283 - 7294

Published: April 15, 2024

Abstract In this study, the use of fungal ( Panaeolus papilionaceus ) biomass as a biosorbent was investigated to effectively remove Pb 2+ ions from aquatic medium. The removal using examined in batch system terms initial solution pH, temperature, time, and concentration. Optimal operating conditions for biosorption ions; pH: 4.5, T: 25 °C, t: 24 h. max capacity found be 31.2 mg g −1 Langmuir model. Thermodynamic studies showed that into possible, spontaneous, endothermic. Additionally, antimicrobial activity antibiofilm extract fungus were also investigated. It determined did not have properties. On other hand, has been shown potential prevent biofilm formation. 1 prevented formation Staphylococcus aureus by 87.85%. observed mechanism includes steps surface biosorption, film diffusion, intra-particle diffusion.

Language: Английский

Citations

7

Sustainable synthesis and dual adsorption of methyl orange and cadmium ions using biogenic silica-based fibrous silica functionalized with crown ether ionic liquid DOI
Hashem O. Alsaab,

Saeed Shirazian,

Niloofar Pirestani

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 679, P. 555 - 568

Published: Oct. 19, 2024

Language: Английский

Citations

7

Evaluation of biosorbent properties of Teucrium polium seeds in Rhodamine B removal; isotherm, kinetic, thermodynamic studies DOI

Rabia Yılmaz,

Zehra Seba Keskin

Chemical Engineering Communications, Journal Year: 2024, Volume and Issue: 211(8), P. 1139 - 1156

Published: April 12, 2024

Water pollution is a major environmental concern worldwide, particularly due to industrial paint waste. Therefore, treating wastewater from various sources crucial restoring quality. In this study, batch biosorption system was used investigate the of Rhodamine B (RhB), highly toxic dye, on Teucrium polium seeds (TPS). The study examined effects different parameters such as initial dye concentration, contact time, pH, temperature, and biosorbent amount RhB removal. To determine physicochemical properties TPS, scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), Fourier transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller (BET), zero charge point (PZC) characterization analyses were performed. maximum capacity TPS at pH = 5.5 25 °C found be 4.18 mg g−1. that removal rate 93.3% an concentration 200 L−1. experimental data showed Langmuir isotherm model (R2 0.940) most compatible for biosorption, while kinetic mechanism proceeded through pseudo-second-order (PSO) 0.925). Additionally, intraparticle diffusion, pore film diffusion effective in mechanism. Thermodynamic studies revealed endothermic (ΔH0>0), spontaneous (ΔS0>0), entropy-increasing (ΔG0 <0). As result, which has suitable adsorbent RhB, can recommended new, cost-effective, abundant potential biosorbent.

Language: Английский

Citations

5