Remediation of Caffeine from Aqueous Solutions Using Waste-Derived Adsorbents: A Polyaniline/Cuttlefish Bone Nanocomposite for Pollutant Removal DOI Creative Commons

Esraa Salama,

Samar M. Mahgoub, Ahmed A. Allam

et al.

Colloids and Interfaces, Journal Year: 2024, Volume and Issue: 9(1), P. 1 - 1

Published: Dec. 26, 2024

Caffeine is commonly used in pharmaceutical and personal care products, where it serves both therapeutic cosmetic purposes. However, its widespread presence wastewater from the industries has raised concerns about environmental contamination. This study explores use of a polyaniline (PANI)/cuttlefish bone (CB) nanocomposite as an effective adsorbent for removal caffeine aqueous solutions. The was synthesized by incorporating (PANI) onto cuttlefish flakes, resulting material with hybrid morphology consisting layered nanosheets flaky structures. Adsorption experiments were conducted to determine optimal conditions removal, results showing best adsorption efficiency at pH 7 dosage 0.1 g/L nanocomposite, achieving 80.73% efficiency. maximum capacity 108.33 mg/g—significantly higher than pure CB (55.05 mg/g) PANI (57.71 mg/g). process followed pseudo-second-order kinetic model Langmuir isotherm, indicating chemisorption mechanism monolayer adsorption. Additionally, demonstrated excellent reuse capacity, maintaining over 85% initial after multiple adsorption–desorption cycles, highlighting potential sustainable long-term use. work demonstrates using waste-derived materials like support development low-cost, adsorbents pollutant remediation wastewater. Future studies will explore adsorbent’s applicability other contaminants antimicrobial properties.

Language: Английский

Classical and advanced isotherms to model the adsorption of drugs, dyes and metals on activated carbonaceous materials: a review DOI
Issam Mechnou, Sarra Meskini, Esseddik Elqars

et al.

Environmental Chemistry Letters, Journal Year: 2024, Volume and Issue: 22(5), P. 2375 - 2404

Published: June 13, 2024

Language: Английский

Citations

10

Statistical physics and fractal like kinetic modelling for adsorption of acetaminophen on MgO/aminated β-cyclodextrin: Variables optimization using Box-Behnken Design DOI
Mohd Nasir Mohd Desa,

Sara Chishti,

Atif Afroz

et al.

Journal of Industrial and Engineering Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Language: Английский

Citations

1

Ball-Milled Spent Coffee Ground Biochar Effectively Removes Caffeine from Water DOI Open Access
Yicheng Yang, Yongshan Wan, Jianjun Chen

et al.

Water, Journal Year: 2025, Volume and Issue: 17(6), P. 881 - 881

Published: March 19, 2025

Caffeine in aquatic ecosystems is an emerging contaminant causing significant environmental concern. In this work, spent coffee ground (SCG) was pyrolyzed at 300, 450, and 600 °C to produce pristine SCG biochars (CG), which were then ball-milled (BMCG). A batch experiment with showed that 450 had the highest capacities adsorb caffeine. Subsequently, CG450 (BMCG450) selected for further analysis. The results ball milling dramatically augmented specific surface area oxygen-containing functional groups of biochar. Langmuir maximum caffeine adsorption capacity 82.65 mg/g. Both solution pH ionic strength affected removal by BMCG450. As increased, increased electrostatic repulsion limited onto However, increase ion slightly enhanced because screening effect cations. biochar also high efficiency a completely mixed flow reactor under continuous conditions. Our study indicates can serve as viable sorbent from water.

Language: Английский

Citations

0

Cypress cones solid waste derived biochar for efficient uptake of paracetamol from synthetic wastewater: characterization, kinetic, isotherm, and thermodynamic studies DOI

Imane Akacha,

Abdelkrim Merzouguı, Khadidja Bouzid

et al.

Biomass Conversion and Biorefinery, Journal Year: 2025, Volume and Issue: unknown

Published: March 27, 2025

Language: Английский

Citations

0

Pomegranate peel adsorbents for water pollutants removal: preparation, characterization and applications DOI

Mohammed Awwal Suleiman,

Muhammad Abbas Ahmad Zaini, Nuhu Dalhat Mu’azu

et al.

International Journal of Phytoremediation, Journal Year: 2025, Volume and Issue: unknown, P. 1 - 21

Published: April 4, 2025

Pomegranate peel waste in the forms of raw biomass, biochar and activated carbon has been explored as adsorbents water treatment. This review examined discussed published works between 2008 2024 that focused on utilization pomegranate with emphasis preparation strategies, characterization techniques applications. The thermal chemical activation have shown to improve structural properties resultant adsorbent materials effectively adsorb various pollutants such dyes, heavy metals, organics, inorganic nonmetals, pharmaceuticals from water. performance was compared avenues for future research highlighted shed insight into potential environmental protection.

Language: Английский

Citations

0

Equilibrium adsorption, kinetic, thermodynamic, and breakthrough curves modelling of acetaminophen on Elaeagnus Angustifolia L. seeds-based granular activated carbon DOI
Mounira Kolli, Fatiha Benmahdi, Sami Khettaf

et al.

International Journal of Environmental & Analytical Chemistry, Journal Year: 2024, Volume and Issue: unknown, P. 1 - 20

Published: July 10, 2024

Language: Английский

Citations

3

Pharmaceutical Pollutants: Ecotoxicological Impacts and the Use of Agro-Industrial Waste for Their Removal from Aquatic Environments DOI Creative Commons
Ana Gabriela Estrada-Almeida,

María Luisa Castrejón-Godínez,

Patricia Mussali-Galante

et al.

Journal of Xenobiotics, Journal Year: 2024, Volume and Issue: 14(4), P. 1465 - 1518

Published: Oct. 15, 2024

Medicines are pharmaceutical substances used to treat, prevent, or relieve symptoms of different diseases in animals and humans. However, their large-scale production use worldwide cause release the environment. Pharmaceutical molecules currently considered emerging pollutants that enter water bodies due inadequate management, affecting quality generating adverse effects on aquatic organisms. Hence, alternatives for pharmaceuticals removal from have been sought; among them, agro-industrial wastes has proposed, mainly because its high availability low cost. This review highlights ecotoxicological related presence environments analyzes 94 investigations, 2012 2024, 17 antibiotics, highlighting sulfamethoxazole as most reported, well 6 non-steroidal anti-inflammatory drugs (NSAIDs) such diclofenac ibuprofen, 27 with pharmacological activities. The these was evaluated using wheat straw, mung bean husk, bagasse, bamboo, olive stones, rice pinewood, others. On average, 60% were transformed into biochar be a biosorbents removal. diversity experimental conditions studies makes it difficult stablish which waste greatest capacity; therefore, this review, drug mass rate (DMRR) calculated, parameter comparative purposes. Almond shell-activated showed highest antibiotics (1940 mg/g·h), while cork powder (CP) (10,420 mg/g·h) NSAIDs. Therefore, scientific evidence demonstrates is promising alternative substances.

Language: Английский

Citations

3

Valorization and Upcycling of Acid Mine Drainage and Plastic Waste via the Preparation of Magnetic Sorbents for Adsorption of Emerging Contaminants DOI Creative Commons

Bongiwe Apatia Mvala,

Tshimangadzo S. Munonde, Anele Mpupa

et al.

ACS Omega, Journal Year: 2024, Volume and Issue: 9(32), P. 34700 - 34718

Published: Aug. 2, 2024

Plastic waste poses a serious environmental risk, but it can be recycled to produce variety of nanomaterials for water treatment. In this study, poly(ethylene terephthalate) (PET) and acid mine drainage were used in the preparation magnetic mesoporous carbon (MMC) nanocomposites adsorptive removal pharmaceuticals personal care products (PPCPs) from samples. The latter then characterized using Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDX), transmission (TEM), Brunauer-Emmett-Teller (BET), ζ potential. results isotherms revealed high specific surface areas 404, 664, 936 m

Language: Английский

Citations

1

Enhancing micropollutant removal efficiency using sustainable activated charcoal DOI
Taher Selmi, Solène Gentil, Vanessa Fierro

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(6), P. 114855 - 114855

Published: Nov. 18, 2024

Language: Английский

Citations

0

Synthesis, Characterisation Of Agricultural Biomass Derived Activated Carbon And Its Applications DOI Creative Commons
Shweta Priya, S A Salmataj,

B Anusha

et al.

Materials Research Express, Journal Year: 2024, Volume and Issue: 12(1), P. 012001 - 012001

Published: Dec. 20, 2024

Abstract As the world moves toward greener energy generation methods and cleaner environments, activated carbon produced from ligninocellulosic resources has attracted unexpected interest due to its easy availability, economic, renewable, biodegradable properties, which makes it a viable alternative exhaustible coal. This review paper provides comprehensive overview of systematic procedure develop plant biomass, characterization by simple techniques, versatile applications carbon. includes role in environmental remediation, emphasizing efficacy removing wide array pollutants, sustainable hydrogen capture storage supercapacitors. A brief comparison key aspects optimal toxicant adsorption, like batch conditions, best-fit model, isotherms, maximum are also made. To ascertain efficiency supercapacitors, their strategy designing it, output terms specific capacitance, power, density compared.

Language: Английский

Citations

0