Food and Chemical Toxicology, Journal Year: 2024, Volume and Issue: 194, P. 115103 - 115103
Published: Nov. 8, 2024
Language: Английский
Food and Chemical Toxicology, Journal Year: 2024, Volume and Issue: 194, P. 115103 - 115103
Published: Nov. 8, 2024
Language: Английский
Journal of Hazardous Materials, Journal Year: 2025, Volume and Issue: 487, P. 137250 - 137250
Published: Jan. 17, 2025
Language: Английский
Citations
0Journal of Hazardous Materials, Journal Year: 2025, Volume and Issue: 489, P. 137491 - 137491
Published: Feb. 7, 2025
Language: Английский
Citations
0Ecotoxicology and Environmental Safety, Journal Year: 2025, Volume and Issue: 292, P. 117979 - 117979
Published: March 1, 2025
With the widespread application of biochar, biochar-mineral complexes are formed in large quantities environment. However, there few reports on their adsorption and desorption mechanisms for organophosphate esters (OPEs). In this study, (MBC@FH MBC@F) were prepared through co-ball-milling with biochar minerals (α-FeO(OH) Fe2O3). The properties pristine MBC@FH/F compared, adsorption-desorption OPEs all materials analyzed. results showed that have a larger specific surface area, more oxygen-containing functional groups, stronger aromaticity, pore structures, but less persistent free radicals than biochar. exhibited lower secondary kinetic rate constant (k2), higher intraparticle diffusion (k1p) capacity Hydrophobic interactions controlled TPhP TPPO complexes, π-π interactions, filling, hydrogen bonding also participated process. MBC@F had aromaticity MBC@FH, thus having MBC@FH. spatial volume inhibited its materials, demonstrating smaller amounts TPhP. was only observed TPhP, while no occurred TPPO. retention amount represented by subtracting from amount, which increased 1.22-6.98 times, reaching 4.48-41.07 mg/g. addition, hysteresis decreases increasing diameter MBC@FH/F. This study illustrated formation may be conducive to OPEs.
Language: Английский
Citations
0Environmental Science & Technology, Journal Year: 2025, Volume and Issue: unknown
Published: March 10, 2025
Large-scale oceanic assessments are key for determining the persistence and long-range transport potential of organic pollutants, but there is a dearth these organophosphate esters (OPEs), widely used as flame retardants plasticizers. This work reports latitudinal distribution (42°N–70°S) vertical profiles (from surface to 2000 m depth) OPEs in Atlantic Southern Oceans explores their biogeochemical controls. The gradient shows higher OPE concentrations near equator than at latitudes, consistent with prevailing atmospheric circulation, measured wet deposition events. At deep chlorophyll maximum depth, was an inverse correlation between phytoplankton biomass, lowest Ocean, role biological pump depleting levels from photic zone. trends ocean (2000 resembled those intertropical concentrations. Analysis derived bottom zone minimum oxygen layer suggested complex dynamic cycling driven by transport, degradation, redissolution depth. persistent enough reach all compartments, quantitative resolution sources, sinks, seasonality, cycles will require future research.
Language: Английский
Citations
0Journal of Hazardous Materials, Journal Year: 2025, Volume and Issue: unknown, P. 138039 - 138039
Published: March 1, 2025
Language: Английский
Citations
0The Science of The Total Environment, Journal Year: 2024, Volume and Issue: 953, P. 176096 - 176096
Published: Sept. 10, 2024
Language: Английский
Citations
3Environment International, Journal Year: 2024, Volume and Issue: 195, P. 109205 - 109205
Published: Dec. 11, 2024
Language: Английский
Citations
1Chemosphere, Journal Year: 2024, Volume and Issue: unknown, P. 143579 - 143579
Published: Oct. 1, 2024
Language: Английский
Citations
0Food and Chemical Toxicology, Journal Year: 2024, Volume and Issue: 194, P. 115103 - 115103
Published: Nov. 8, 2024
Language: Английский
Citations
0