Zinc oxides by thermal decomposition synthesis and parameters affecting electrocatalyst activity for CO2 reduction reaction DOI Creative Commons

Elías Rodríguez-Jara,

Margherita Cavallo, Ryosuke Nakazato

et al.

Open Ceramics, Journal Year: 2024, Volume and Issue: unknown, P. 100733 - 100733

Published: Dec. 1, 2024

Language: Английский

Development of catalytic systems for reduction of electrochemically inert inorganic molecules: carbon dioxide and nitrogen DOI Creative Commons
Paweł J. Kulesza, Iwona A. Rutkowska, Anna Chmielnicka

et al.

Current Opinion in Electrochemistry, Journal Year: 2025, Volume and Issue: unknown, P. 101657 - 101657

Published: Jan. 1, 2025

Language: Английский

Citations

0
Cambered Bipyridyl Ligand with Extended Aryl System Enables Electrochemical Reduction of Carbon Dioxide and Bicarbonate by Mn(bpy)(CO)3Br-type Catalyst Immobilized on Carbon Nanotubes DOI Creative Commons

Adam Lee,

Emile E. DeLuca,

Emma B. Kelly

et al.

Journal of the American Chemical Society, Journal Year: 2025, Volume and Issue: 147(9), P. 7411 - 7422

Published: Feb. 24, 2025

Heterogeneous materials containing molecular catalytic sites show promise for electrocatalytic reduction of CO2 to energy-enriched carbon products. Interactions between the catalyst and heterogeneous support increasingly are recognized as important in governing product selectivity rate. Recent work on Mn(R-bpy)(CO)3Br type catalysts immobilized multiwalled nanotubes (MWCNT) demonstrated control behavior with steric modification catalyst. Phenyl groups installed 4,4' positions bipyridine ligand (ph-bpy) maximized performance through π-π interactions MWCNT support. Herein we report outcome extending π system Mn(nap-bpy)(CO)3Br (nap-bpy = 4,4'-di(naphthalen-1-yl)-2,2'-bipyridine) Mn(pyr-bpy)(CO)3Br (pyr-bpy 4,4'-di(pyren-1-yl)-2,2'-bipyridine) MWCNT. We demonstrate exceptional electrocatalysis Mn(nap-bpy)(CO)3Br/MWCNT (FECO > 92%; JCO 16.5 mA/cm2) find that this electrochemically reduces bicarbonate absence deliberately added at a remarkable overall >80% products (FEHCOO- 52% FECO 29%). diminishing returns simply adding aromatic character bipyridyl Mn(pyr-bpy)(CO)3Br/MWCNT observe unique cambering believe enables selective catalysis. Mechanistic studies were carried out using novel thin-film infrared spectroelectrochemical (IR-SEC) technique. These experiments undergo single electron Mn-centered radical binds reduction-coupled process.

Language: Английский

Citations

0
Electrocatalysis: Prospects and Role to Enable an E‐Chemistry Future DOI Creative Commons
Gabriele Centi, Siglinda Perathoner

The Chemical Record, Journal Year: 2025, Volume and Issue: unknown

Published: March 3, 2025

Abstract Electrocatalysis is a crucial technology that will enable future low‐carbon chemical production and energy beyond fossil fuels. Notwithstanding the intense growing research in area, potentialities of field are largely unexplored. We provide case examples discuss emerging possibilities have still not been investigated enough but necessary to exploit this potential e‐chemistry. Starting from defining trends setting scene, as well clarifying difference between electrochemistry electrocatalysis, some elements vision foster innovation discussed. The aim stimulate discussion reflection rather than review state‐of‐the‐art. Aspects discussed regard i) passing electro photoelectrocatalytic approaches, ii) making chemicals air, iii) exploitation both anodic cathodic reactions, tandem/paired electrocatalytic iv) for selective oxidation mediated synthesis. Priorities strategies an e‐chemistry Intensifying these directions extending still‐too‐limited current including modelling design, effort accelerate realisation distributed

Language: Английский

Citations

0
Identification of catalyst optimization trends for electrocatalytic CO(2) reduction to ethylene DOI Creative Commons
Stefan J. Raaijman, Maarten P. Schellekens, Yoon Jun Son

et al.

EES Catalysis, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

In this perspective we analyze copper and copper-based electrocatalysts with high ethylene selectivities from the literature to identify global catalyst formulation trends that allow for making catalysts improved performance.

Language: Английский

Citations

0
Recent Advancements Related to Silver-based Electrocatalysts for Carbon Dioxide Reduction Reaction to Carbon Monoxide DOI Creative Commons

Cristina Tricella,

Mohsin Muhyuddin, Roberto Nisticò

et al.

Current Opinion in Electrochemistry, Journal Year: 2025, Volume and Issue: unknown, P. 101696 - 101696

Published: April 1, 2025

Language: Английский

Citations

0
Synthesis of various Pb catalysts and their examination in the study of electrochemical CO2 reduction (ECR) using a quartz crystal microbalance with a Mn3O4 anode DOI

V. S. K. Yadav,

Mohammed A. H. S. Saad,

Mohammed J. Al‐Marri

et al.

Catalysis Science & Technology, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Graphical representation of the QCM-ECR reactor setup.

Language: Английский

Citations

0
Recent advances in the measurement of thermochemical, electrochemical and photochemical efficiency of CO2 conversion to value-added products - its challenges and future directions DOI Creative Commons
Subodh Chaudhari,

Harish Pawar,

Kajal Pawar

et al.

Deleted Journal, Journal Year: 2025, Volume and Issue: unknown, P. 100049 - 100049

Published: April 1, 2025

Language: Английский

Citations

0
Multi-response optimization for a waste heat recovery rotary drum with flights: Focusing on enhancement and homogenization of heat exchange DOI
Yucong He, Lei Rao,

E Dianyu

et al.

Process Safety and Environmental Protection, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Language: Английский

Citations

0
Dynamic protonation of ligand sites in molecular catalysts enhances electrochemical CO 2 reduction DOI Creative Commons
Libo Sun, Tan Su, A.C. Fisher

et al.

Science Advances, Journal Year: 2025, Volume and Issue: 11(17)

Published: April 25, 2025

Molecular catalysts with functional group decorations are promising for electrocatalytic CO 2 reduction to produce valuable chemicals and fuels. Using nickel phthalocyanine derivatives cyano, methoxy, dimethylamino groups, this study unveils why decorating molecular either electron-donating or electron-withdrawing groups can enhance their activity. Notably, the group–decorated catalyst demonstrated stable nearly 100% -to-CO selectivity over a wide potential range high partial current densities up 300 milliamperes per square centimeter. Theoretical in situ spectroscopic analyses revealed critical role of dynamic protonation ligand sites activating metal center, which be facilitated by decoration groups. Conversely, although requiring higher energy protonation, synergy between centers protonated sites, favoring formation key *COOH intermediates improving at bias. This underscores importance optimizing functionalized enhanced RR

Language: Английский

Citations

0
Energy-carbon pricing-guided collaborative optimization for local integrated energy communities with multi-vector electrification consumers DOI Creative Commons
Yufei Xi, Lujie Zuo,

Meng Chen

et al.

Applied Energy, Journal Year: 2025, Volume and Issue: 392, P. 125946 - 125946

Published: April 29, 2025

Language: Английский

Citations

0