Bio-Based Oligomers: Progress, Applications, and Future Perspectives DOI Creative Commons
Tahereh Hayeri

Sustainable Chemical Engineering, Journal Year: 2024, Volume and Issue: unknown, P. 471 - 480

Published: Aug. 1, 2024

In response to escalating environmental concerns, the coatings industry is experiencing a profound shift towards sustainability. Central this transformation are advanced technologies such as water-borne coatings, radiation-curable solutions, and high-solid powder coatings. These innovations complemented by increasing use of bio-based materials derived from biomass or biomass-dependent processes, which serve eco-friendly alternatives traditional fossil fuel-based materials. not only provide versatility through chemical modifications but also facilitate curing techniques, significantly enhancing sustainability profile Recent research has made notable strides in developing with high bio-renewable content, highlighting sector's commitment reducing impact. This review comprehensively examines recent advancements field, focusing on integration oligomers into various coating formulations. It discusses progress creating durable explores diverse applications, provides insights emerging trends future directions. Key areas exploration include essential oils, vegetable polymers wood flame-retardant materials, development solvent-free solid using deep eutectic solvents. Additionally, covers innovative applications electrochromic devices biomass-derived functional for enzyme immobilization, challenges breakthroughs lignin depolymerization. The UV-curable technology aqueous two-phase extraction processes monomers further underscore sustainable practices. By synthesizing analyzing these advancements, study contributes ongoing discourse surrounding opportunities innovation providing roadmap environmentally friendly solutions.

Language: Английский

A review on molecularly imprinted magnetic solid phase extraction emphasizing the analysis of antibiotics in complex matrices:Design, preparation, and application DOI
Youfang Huang, Cui Ma, Xiaojia Huang

et al.

Journal of Chromatography A, Journal Year: 2025, Volume and Issue: 1742, P. 465653 - 465653

Published: Jan. 5, 2025

Language: Английский

Citations

2
Solubility measurement of Ceftriaxone sodium in SC-CO2 and thermodynamic modeling using PR-KM EoS and vdW mixing rules with semi-empirical models DOI Creative Commons
Gholamhossein Sodeifian, Hamidreza Bagheri, Mohsen Ashjari

et al.

Case Studies in Thermal Engineering, Journal Year: 2024, Volume and Issue: 61, P. 105074 - 105074

Published: Sept. 1, 2024

The complete investigation of the solubility Ceftriaxone sodium drug has not yet been conducted. This communication investigates in supercritical CO2 (SC-CO2) for first time. measurements were performed using utilizing UV-vis analysis under different operation conditions (at P (bar) = 120-270 and T (K) 308-338). results demonstrated that ranged from 0.90 × 10-6 to 8.01 10-6. mole fraction increases proportionally with an increase pressure, while maintaining a constant temperature. However, crossover was noted. behavior SC-CO2 modeled by Peng-Robinson equation state (PR EoS) Kwak-Mansoori van der Waals mixing rules seven semi-empirical correlations (Bian et al., Kumar-Johnston, Chrastil, Garlapati-Madras, Bartle Sung-Shim Sodeifian al.,). vaporization, total solvation enthalpies sodium/SC-carbon dioxide system obtained KJ, al. correlations. evaluation two methods absolute average relative deviation (AARD%). Both models exhibited satisfactory level agreement experimental data. Finally, PR/KM EoS Chrastil models, AARD% values 8.70% 8.10% respectively, showed superior precision accurately fitting

Language: Английский

Citations

8
Highly selective magnetic molecularly imprinted polymer for preconcentration and determination of atorvastatin in human urine samples DOI

Shadi Oshaghi

Microchemical Journal, Journal Year: 2024, Volume and Issue: 206, P. 111465 - 111465

Published: Aug. 17, 2024

Language: Английский

Citations

5
Nanomaterial-based magnetic solid-phase extraction in pharmaceutical and biomedical analysis DOI
Jingxin Hou,

Cong Hu,

Hanyin Li

et al.

Journal of Pharmaceutical and Biomedical Analysis, Journal Year: 2024, Volume and Issue: 253, P. 116543 - 116543

Published: Oct. 28, 2024

Language: Английский

Citations

5
Assembly of Silicate–Phenolic Network Coatings with Tunable Properties for Controlled Release of Small Molecules DOI
Omid Mazaheri, Zhixing Lin, Wanjun Xu

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 13, 2024

Engineered coatings are pivotal for tailoring the surface properties and release profiles of materials applications across diverse areas. However, developing robust that can both encapsulate controllably cargo is challenging. Herein, a dynamic covalent coordination assembly strategy used to engineer silicate-based coatings, termed silicate-phenolic networks (SPNs), using sodium metasilicate phenolic ligands (tannic acid, gallic pyrogallol). The pH-responsive (owing bonding), their hydrophobicity be tuned upon post-functionalization with hydrophobic gallates (propyl, octyl, lauryl gallates). potential SPN controlled small molecules, such as urea (a widely fertilizer), demonstrated-controlled in soil achieved response different pHs (up 7 days) 14 days). Furthermore, leveraging presence silicon (within coating) metal ions (Fe

Language: Английский

Citations

5
Preconcentration and Determination of Copper(II) in Water and Tea Infusion Samples Using Hierarchical MnSb2O6@Fe3O4 Nanoparticles and Magnetic Solid Phase Extraction–FAAS DOI Creative Commons
Dılgeş Baskın

ACS Omega, Journal Year: 2025, Volume and Issue: 10(9), P. 9537 - 9546

Published: Feb. 26, 2025

Heavy metal pollution poses a significant threat to living organisms and requires continuous monitoring of the environmental samples. In this study, novel hierarchical MnSb2O6@Fe3O4 nanoparticles were synthesized used as adsorbents in magnetic solid-phase extraction (MSPE) Cu(II). The strong properties these enabled rapid efficient separation from complex matrices, simplifying preconcentration ensuring high adsorption efficiency. By integration MSPE with flame atomic absorption spectrometry (FAAS), matrix effects reduced, detection limits improved, cost-effectiveness simplicity FAAS leveraged for Cu(II) analysis optimized parameters MSPE-FAAS method included pH, stirring time type, eluent volume adsorbent amount, achieving correlation coefficient 0.9991, limit 2.1 ng·mL–1 linear range 10.0–200 ng·mL–1. developed enhanced sensitivity by 48-fold was successfully applied wastewater, tap water, apple tea samples, recoveries 93–102%. capacity determined be 15.2 mg·g–1, demonstrating its efficiency heavy removal. This methodology highlights robust approach preconcentrating trace metals diverse combining advantages practical, cost-effective system.

Language: Английский

Citations

0
A dummy template molecularly imprinted polymer-coated fiber array extraction for simultaneous HPLC analysis of eight biogenic amines in fermented horse milk DOI

Adila Muhtar,

Pengli Jian,

Turghun Muhammad

et al.

Analytica Chimica Acta, Journal Year: 2025, Volume and Issue: 1352, P. 343901 - 343901

Published: March 6, 2025

Language: Английский

Citations

0
Sensitive determination of chlorpromazine in pharmaceutical formulations and biological fluids using solid phase extraction followed by HPLC-UV and spectrophotometric analysis DOI Creative Commons

Raed F. Hassan,

Jalal N. Jeber,

Hussein Fares Abd‐Alrazack

et al.

RSC Advances, Journal Year: 2025, Volume and Issue: 15(15), P. 11478 - 11490

Published: Jan. 1, 2025

An environmentally friendly analytical method was developed to detect trace amounts of chlorpromazine in pharmaceutical formulations, urine, and serum samples. The integrates magnetic solid-phase extraction (MSPE) with UV detection (MSPE-UV), utilizing materials procedures. MSPE system employed 3-chloropropyltriethoxysilane-coated nanoparticles (Fe3O4@CPTES) as adsorbents, offering a sustainable efficient alternative conventional methods. proposed technique eliminates the need for toxic organic solvents commonly used pre-concentration steps, aligning principles green chemistry. Optimization parameters, including pH, ionic strength, adsorbent dosage, revealed high efficiencies (98% solutions, 52% 33% serum), corresponding enrichment factors 102, 52, 41, respectively, limits low 0.08 ng mL-1 solutions. demonstrates excellent linearity (R 2 > 0.9988) over wide range (0.15-400 mL-1) precision (RSD < 7%). Fe3O4@CPTES enable rapid, reusable, extraction, reducing both analysis time resource consumption. While tablet validates robustness, primary application lies CPZH biological matrices. This approach offers reliable, sensitive, eco-friendly protocol detection, highlighting its potential broader applications biomedical analysis.

Language: Английский

Citations

0
Novel phenazine-based microporous organic network for selective and sensitive determination of trace sulfonamides in milk samples DOI

Zhao-Jun Hu,

Xiao-Lin Luan,

Yuanyuan Cui

et al.

Analytica Chimica Acta, Journal Year: 2024, Volume and Issue: 1326, P. 343138 - 343138

Published: Aug. 23, 2024

Language: Английский

Citations

3
Determining the characteristics of representative volume elements in severely deformed aluminum-matrix composite DOI Creative Commons
Amir Hossein Assari,

Negar Shaghaghi,

Saeid Yaghoobi

et al.

Heliyon, Journal Year: 2024, Volume and Issue: 10(16), P. e36489 - e36489

Published: Aug. 1, 2024

The accurate evaluation of the effective mechanical properties composites mainly depends on characteristics representative volume elements (RVEs). This paper investigates RVE size. Additionally, effect fraction reinforcement, edge effect, and types critical size are discussed. First, Al/Ni multilayered were processed by nine cycles cross-accumulative roll bonding (CARB) method. Then, one type RVEs was created based cross-sectional micrographs to consider their inhomogeneities. Another generated using random sequential adsorption (RSA) procedure. Thereafter, homogenized elastic both microstructure-based RSA-based computed compared as a function Ni results showed that increasing fragments, indicated stiffer behavior. By from 0.2 Vf 0.8 Vf, Poisson ratio decreased 7 % modulus increased 83 for RVE. Regarding (0.8 Vf), largest (size 1) with length 575 μm width smallest 5) 287.5 μm, 16 decrease, respectively.

Language: Английский

Citations

2