S-doped amorphous multi-metal borophosphates for efficient alkaline seawater oxidation with a high corrosion resistance DOI

Min Gi Kim,

Ashish Gaur, Min Su Cho

et al.

Applied Surface Science, Journal Year: 2024, Volume and Issue: unknown, P. 161222 - 161222

Published: Sept. 1, 2024

Language: Английский

Coupling Co-Ni phosphides for energy-saving alkaline seawater splitting DOI
Weijia Liu, Wenxian Liu, Tong Hou

et al.

Nano Research, Journal Year: 2024, Volume and Issue: 17(6), P. 4797 - 4806

Published: Feb. 7, 2024

Language: Английский

Citations

76
Phosphorus–tungsten dual-doping boosts acidic overall seawater splitting performance over RuOx nanocrystals DOI

Junyang Ding,

Zimo Peng,

Zhiwei Wang

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(41), P. 28023 - 28031

Published: Jan. 1, 2024

Dual-doped ruthenium-based nanocrystals were developed as efficient and stable electrocatalysts for acidic overall seawater splitting with superior activity durability.

Language: Английский

Citations

35
Recent achievements in selenium-based transition metal electrocatalysts for pH-universal water splitting DOI
Y.‐B. Jiang,

Sanshuang Gao,

Xijun Liu

et al.

Nano Research, Journal Year: 2024, Volume and Issue: 17(7), P. 5763 - 5785

Published: May 16, 2024

Language: Английский

Citations

15
Amorphous Ni(OH)2 Coated Cu Dendrites with Superaerophobic Interface for Bipolar Hydrogen Production Assisted with Formaldehyde Oxidation DOI Open Access

Shaojian Jiang,

Yuhang Liu, Ruidong Yang

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 13, 2025

Abstract Since formaldehyde oxidation reaction (FOR) can release H 2 , it is attractive to construct a bipolar hydrogen production system consisting of FOR and evolution (HER). Although copper‐based catalysts have attracted much attention due their low cost high activity, the performance enhancement mechanism lacks in‐depth investigation. Here, an amorphous‐crystalline catalyst amorphous nickel hydroxide‐coated copper dendrites on foam (Cu@Ni(OH) /CF) prepared. The modification Ni(OH) resulted in hydrophilic aerophobic states Cu@Ni(OH) /CF surface, facilitating transport liquid‐phase species electrode surface accelerating . Open circuit potential (OCP) density functional theory (DFT) calculations indicate that this core–shell structure facilitates adsorption HCHO OH − In addition, catalytic pathway are investigated through situ FTIR DFT calculations, results showed lowered energy barrier for C─H bond breaking H─H formation. HER//FOR system, Pt/C//Cu@Ni(OH) provide current 0.5 A cm −2 at 0.36 V achieve efficient stable production. This work offers new ideas designing electrocatalysts assisted with oxidation.

Language: Английский

Citations

1
Accelerating the Discovery of Efficient High-Entropy Alloy Electrocatalysts: High-Throughput Experimentation and Data-Driven Strategies DOI

Xiangyi Shan,

Yiyang Pan,

Furong Cai

et al.

Nano Letters, Journal Year: 2024, Volume and Issue: 24(37), P. 11632 - 11640

Published: Sept. 3, 2024

High-entropy alloys (HEAs) present both significant potential and challenges for developing efficient electrocatalysts due to their diverse combinations compositions. Here, we propose a procedural approach that combines high-throughput experimentation with data-driven strategies accelerate the discovery of HEA hydrogen evolution reaction (HER). This enables rapid preparation arrays various element composition ratios within model system. The intrinsic activity is swiftly screened using scanning electrochemical cell microscopy (SECCM), providing precise composition-activity data sets An ensemble machine learning (EML) then used predict database subspace Based on these results, two groups promising catalysts are recommended validated through actual electrocatalytic evaluations. approach, which strategies, provides new pathway electrocatalysts.

Language: Английский

Citations

8
C3N5-based nanomaterials and their applications in heterogeneous catalysts, energy harvesting, and environmental remediation DOI
Linfeng Xiao,

Sanshuang Gao,

Runhua Liao

et al.

Materials Horizons, Journal Year: 2024, Volume and Issue: 11(11), P. 2545 - 2571

Published: Jan. 1, 2024

The semiconductor material C 3 N 5 , due to its unique physicochemical properties and excellent performance, has been widely researched applied in the fields of energy, catalysis environmental remediation.

Language: Английский

Citations

7
Interfacial coupling of Ce-CoSe2 nanoneedle arrays with MXene for efficient overall water splitting DOI
Ao Zhou, Wenwen Cai,

Weijian Guo

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 678, P. 970 - 978

Published: Aug. 28, 2024

Language: Английский

Citations

6
In situ capturing site-to-site reactive species in CO2-laser-patterned high-entropy alloy nanoflowers for robust alkaline seawater electrolysis DOI

Chae Eun Park,

Gyoung Hwa Jeong,

V. Maheskumar

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(33), P. 21744 - 21757

Published: Jan. 1, 2024

CO 2 -laser method to synthesize AuRuIrPdPt high-entropy alloys (HEAs) for hydrogen evolution in alkaline and seawater splitting. Optimized HEA-60 exhibits remarkable HER activity stability, surpassing those of commercial Pt/C.

Language: Английский

Citations

4
“Similar stacking”‐inspired compressive strain of heterogeneous phosphide for efficient hydrogen evolution DOI Creative Commons
Tianyi Xu,

Dongxu Jiao,

Jinchang Fan

et al.

Carbon Energy, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 3, 2025

Abstract Strain effects have garnered significant attention in catalytic applications due to their ability modulate the electronic structure and surface adsorption properties of catalysts. In this study, we propose a novel approach called “similar stacking” for stress modulation, achieved through loading Co 2 P on Ni (Ni P/Co P). Theoretical simulations reveal that compressive strain induced by influences orbital overlap electron transfer with hydrogen atoms. Furthermore, number stacked layers can be adjusted varying precursor soaking time, which further modulates range adsorption. Under 2‐h condition, effect proves favorable efficient production. Experimental characterizations using X‐ray diffraction, high‐angel annular dark‐field scanning transmission election microscope (HAADF‐STEM), absorption near‐edge spectroscopy successfully demonstrate lattice contraction bond length shortening Co–P. Remarkably, our catalyst shows an ultrahigh current density 1 A cm −2 at overpotential only 388 mV, surpassing commercial Pt/C, while maintaining long‐term stability. This material design strategy similar stacking opens up new avenues modulation deeper development electrocatalysts.

Language: Английский

Citations

0
Recent advances in core–shell structured noble metal-based catalysts for electrocatalysis DOI
Chenchen Wang,

Zengsheng Guo,

Qi Shen

et al.

Rare Metals, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 13, 2025

Language: Английский

Citations

0