Synergy of Cu-Doping and In Situ Reconstruction on Bi2O2CO3 for Promoting CO2 Electroreduction Over Wide pH Range DOI
Shengnan Zhang, Xiaoyan Zhang, J. C. Yang

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 13, 2024

Doping Cu and in situ electrochemical reconstruction on Bi 2 O CO 3 optimize the hybridization between 6p of 2p *OCHO, leading to high HCOO − faradaic efficiency >96% all-pH range satisfactory durability.

Language: Английский

Advancements in Amorphous Oxides for Electrocatalytic Carbon Dioxide Reduction DOI Creative Commons

Youcai Meng,

Junyang Ding,

Yifan Liu

et al.

Materials Today Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 100065 - 100065

Published: Sept. 1, 2024

Language: Английский

Citations

6

Construction of Zinc-Bismuth Composite Oxide Interface Helps Electrochemical Reduction of CO2 to Produce Formic Acid Efficiently and Stably DOI

Shuxiu Yu,

Shixiong Yuan,

Liang Li

et al.

Catalysis Letters, Journal Year: 2025, Volume and Issue: 155(3)

Published: Feb. 17, 2025

Language: Английский

Citations

0

Electrocatalytic Bipolar Synthesis of Valuable Chemicals DOI

Wenqi Gao,

Chen Wang,

Lin Lv

et al.

ChemCatChem, Journal Year: 2024, Volume and Issue: 16(21)

Published: July 29, 2024

Abstract Electrocatalysis can synthesize kinds of valuable chemicals and plays vital role in developing clean renewable energy storage conversion devices. In the traditional electrocatalytic systems, researchers try to one type chemical at cathode or anode independently. Recently, bipolar synthesis both simultaneously becomes popular attracts much attention. this minireview, we summarize latest processes on innovative strategies for various chemicals. We will discuss findings according categories products, including hydrogen production, formate production hydrogenation. And associated catalysts optimization, reaction mechanism, design principles are well introduced. Moreover, challenges prospects highlighted future developments. This review is timely guide others pay more attention novel systems.

Language: Английский

Citations

1

Spin Regulation of Nickel Single Atom Catalyst via Axial Phosphor‐Coordination Achieves Near Unity CO Selectivity in Electrochemical CO2 Reduction DOI

Kanghua Miao,

Jundi Qin,

Siyuan Lai

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 26, 2024

Abstract The engineering of the spin state and axial coordination metal center single‐atom catalyst (SAC) represents an effective strategy for regulating catalytic activity, selectivity, stability toward electrocatalytic reduction CO 2 (ECO R). However, rational design deliberate fabrication SACs with specified atoms remain challenging. Herein, Ni single phosphorus (NiP−N 4 −C) four planar nitrogen are fabricated, which induces reorientation 3d orbitals atom shift from low (S = 0) to high 2). enhanced d−p orbital coupling between adsorbents enhances activation reduces energy barrier formation * COOH, a key intermediate in ECO R produce CO, enabling activity near unity selectivity broad potential range 600 mV (−0.4–−1.0 V vs reversible hydrogen electrode RHE), achieving turnover frequency 37.2 s −1 at −1.0 versus RHE. As bifunctional cathode electrocatalyst, NiP−N −C demonstrates peak power density 18.5 mW cm −2 maintains cycling durability over 70 h rechargeable Zn−CO batteries.

Language: Английский

Citations

1

Optimizing Cu doping on carbon nitrogen holly shell for enhanced selectivity towards formate in CO2 reduction DOI
Yurui Xu, Xiao Liu, Minghui Jiang

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 683, P. 347 - 357

Published: Dec. 12, 2024

Language: Английский

Citations

1

Synergy of Cu-Doping and In Situ Reconstruction on Bi2O2CO3 for Promoting CO2 Electroreduction Over Wide pH Range DOI
Shengnan Zhang, Xiaoyan Zhang, J. C. Yang

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 13, 2024

Doping Cu and in situ electrochemical reconstruction on Bi 2 O CO 3 optimize the hybridization between 6p of 2p *OCHO, leading to high HCOO − faradaic efficiency >96% all-pH range satisfactory durability.

Language: Английский

Citations

0