The European Physical Journal D, Journal Year: 2024, Volume and Issue: 78(11)
Published: Nov. 1, 2024
Language: Английский
The European Physical Journal D, Journal Year: 2024, Volume and Issue: 78(11)
Published: Nov. 1, 2024
Language: Английский
Applied Physics Reviews, Journal Year: 2025, Volume and Issue: 12(2)
Published: April 2, 2025
Carbon dioxide (CO2) reduction to value-added chemicals for sustainable and clean energy is hindered by its considerable ionization potential (IP) negative adiabatic electron affinity (EA), which makes CO2 a chemically inert molecule, leading challenging unfavorable conversion under ambient conditions. To cope with this challenge, novel catalysts have been developed lower the activation reactions. However, low activity, selectivity, deactivation of limit their industrial applications. This scenario demands development next-generation, highly active, selective, long-term stable based on reaction mechanism microkinetics. review summarizes unifies current catalyst design concepts thermochemical C1 products via heterogenous catalysis. In addition, recommendations are made leverage thermal-catalysis knowledge plasma-activated catalysts. Four reactions were reviewed analyzed producing single-carbon (C1) organic products, including reverse water gas shift (RWGS) reaction, dry reforming methane (DRM), methanation, hydrogenation. Each section focuses one elaborate status experimental computational-based catalysts, unsupported mono-metals, supported mono- bimetallic catalysis, transition carbide depending followed causes deactivation. Finally, directions future outlined translate thermal catalysis at specific level rational catalyze non-thermal plasma (NTP) catalytic system.
Language: Английский
Citations
0Materials Today Sustainability, Journal Year: 2024, Volume and Issue: 27, P. 100817 - 100817
Published: May 9, 2024
Language: Английский
Citations
2ChemSusChem, Journal Year: 2024, Volume and Issue: 17(21)
Published: June 24, 2024
Abstract Transitioning from both the direct and indirect use of fossil fuels to renewable sustainable resources near future demands a focal shift in catalysis research – investigating catalytic reactions isolation developing coupled for modern chemical value chains. In this Perspective, we discuss status emerging prospects across various scales provide key examples. Besides being essential alternative current fossil‐based processes, coupling offers novel scalable pathways value‐added chemicals. By emphasizing specific requirements challenges arising reactions, aim identify underscore needs that are critical expedite their development fully unlock potential fuel production.
Language: Английский
Citations
2ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 7, 2024
Language: Английский
Citations
2Journal of Polymer Science, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 13, 2024
ABSTRACT Pressure‐sensitive adhesives (PSAs) are widely used in daily life, but their poor degradability poses significant challenges to sustainable development. To address this, we synthesized a polycarbonate, PPCB, using carbon dioxide and propylene oxide as raw materials, incorporating rigid benzene rings ester functional groups. PPCB exhibited T d,−5% , d,max that were 58.5% 30.7% higher than those of polypropylene carbonate (PPC), respectively. Its highest tensile strength was 55% PPC, while its elongation at break decreased from 421% 165%. The 180° peel reached 5.2 ± 0.56 N /cm, surpassing some commercial products such Duct‐tape. demonstrated high stable adhesion (~52 ) on various substrates. skin tissue 26.6 1.6 kPa, significantly commercially available fibrin glue. Rheological studies indicated maintained viscosity throughout the testing process, with lap shear close 4.56 MPa. Additionally, showed excellent degradability, water absorption rate weight loss. also good biocompatibility, cell viability greater 90%. has potential become novel degradable PSA, providing new solution for environmental sustainability.
Language: Английский
Citations
0The European Physical Journal D, Journal Year: 2024, Volume and Issue: 78(11)
Published: Nov. 1, 2024
Language: Английский
Citations
0