Nitrogen-Doped Calcite Derived from Ca-MOFs as an Efficient Adsorbent for Sr(II) Removal from Water: The Role of Nitrogen and Calcium DOI Creative Commons
Xinran Xie, Guoce Yu,

Jiang-Bo Huo

et al.

Clean Technologies, Journal Year: 2024, Volume and Issue: 7(1), P. 2 - 2

Published: Dec. 27, 2024

Strontium (90Sr) is a typical radionuclide, which can act as contaminant and poses big problem for the eco-environment if left untreated. In this study, an original nitrogen-doped calcite (N-CaCO3) was synthesized using solvothermal calcination method used to remove Sr(II) from simulated water. XRD, SEM, XPS analyses proved that N successfully doped into CaCO3, resulting in porous CaCO3 with regular morphology. The specific surface area of N-CaCO3 (136.53 m2/g) reach 2.19-fold greater than CaCO3. results based on batch adsorption data indicated pseudo-second-order kinetic model (R2 = 0.9964) ion exchange 0.9859) fitted well. as-synthesized exhibited better performance regard low concentrations (below 64.5 mg/L) compared commercial structural analysis suggested Ca played pivotal roles process mechanism dominated by complexation. This study fabricated cleanup, presenting efficient strategy modulate microstructure or other materials, enhance its performance.

Language: Английский

Tetracycline in the environment: Toxicity, uses, occurrence, detection, and removal by covalent organic frameworks − Recent advances and challenges DOI

Kawan F. Kayani

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132418 - 132418

Published: March 1, 2025

Language: Английский

Citations

4

Unique sandwich-cookie-like nanosheet array heterojunction bifunctional electrocatalyst towards efficient overall water/seawater splitting DOI
Qian Long, Yao Zhu, Huiting Hu

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 669, P. 935 - 943

Published: May 11, 2024

Language: Английский

Citations

10

Designing MOF-COF hybrid materials for energy, biomedical and environment applications DOI
Muhammad Altaf Nazir,

Mamoona Naseer,

Sami Ullah

et al.

Inorganic Chemistry Communications, Journal Year: 2024, Volume and Issue: unknown, P. 113262 - 113262

Published: Oct. 1, 2024

Language: Английский

Citations

10

Hydrothermal Carbonization Technology for Wastewater Treatment under the “Dual Carbon” Goals: Current Status, Trends, and Challenges DOI Open Access
Guoqing Liu,

Qing Xu,

Salah Fatouh Abou‐Elwafa

et al.

Water, Journal Year: 2024, Volume and Issue: 16(12), P. 1749 - 1749

Published: June 20, 2024

Hydrothermal carbonization (HTC) technology transforms organic biomass components, such as cellulose and lignin, into valuable carbon materials, gases inorganic salts through hydrolysis, degradation polymerization, with significant advantages over traditional methods by reducing energy consumption, lowering pollutant emissions enhancing efficiency. In the context of global climate change, HTC plays a critical role in water environment management addressing industrial, agricultural, domestic wastewater challenges. The application extends to treatment, where hydrochar effectively adsorbs heavy metals, compounds, anions, thereby improving quality. However, challenges remain, optimizing process for diverse raw managing economic costs, environmental social impacts. Future research policy support are essential advancing technology. By reaction mechanisms, developing catalysts, promoting international cooperation, can significantly contribute towards achieving neutrality goals fostering sustainable development.

Language: Английский

Citations

9

Two-dimensional MBene combined with cobalt nanoparticles enabling highly efficient peroxymonosulfate activation for ornidazole degradation DOI
Xinyu Zheng, Lunhong Ai, Ran Jia

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 354, P. 128647 - 128647

Published: July 2, 2024

Language: Английский

Citations

9

Green preparation of metal–organic frameworks in deep eutectic systems with boosted photocatalytic activity DOI Open Access
Wenqian Jiang, Yumei Chen,

Xinru Ding

et al.

Journal of Chemical Technology & Biotechnology, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 29, 2025

Abstract Background Metal–organic frameworks (MOFs) are known for their extensive specific surface area, robust stability, and diverse active sites, which make them highly effective applications in photocatalysis. The deep eutectic system (DESys) offers a green alternative to traditional toxic organic solvents can impart novel, eco‐friendly properties synthesized materials. This study investigates DESys/MIL‐100(Fe), MOF within DESys, its application the photocatalytic decomposition of tetracycline hydrochloride (TC‐HCl). Compared conventional synthesis methods, DESys‐based approach avoids use hydrofluoric acid high‐pressure reaction equipment, making it more environmentally friendly potentially suitable large‐scale industrial production MOFs. Results results showed that DESys/MIL‐100(Fe) demonstrated significantly better performance TC‐HCl degradation than MIL‐100(Fe) by methods. After 2 h visible‐light exposure, efficiency reached 91.20% with while was only 38.74% under identical conditions. improved be attributed enhanced adsorption capabilities, increased number greater absorption visible light, higher carrier density. These factors contribute superior catalytic efficiency. Conclusion findings demonstrate not exhibits outstanding stability pollutants but also highlights potential using DESys high‐performance sustainable pathway MOFs environmental applications. © 2025 Society Chemical Industry (SCI).

Language: Английский

Citations

1

Integrated Heterogeneous Engineering with the Vacancy Defect of Porous CoPv-MoxPv Nanosheets for an Accelerated Hydrogen Evolution Reaction DOI
Qian Long, Yao Zhu, Huiting Hu

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(20), P. 9346 - 9354

Published: May 8, 2024

Electrochemical water splitting is a possible way of realizing sustainable and clean hydrogen production but challenging, because highly active durable electrocatalyst essential. In this work, we integrated heterogeneous engineering vacancy defect strategies to design fabricate heterostructure (CoPv-MoxPv/CNT) with abundant phosphorus vacancies attached carbon nanotubes (CNTs). The defects enabled the optimization electronic structure; thereby, electron-rich low-valent metal sites enhanced ability nonmetallic P capture proton H. Meanwhile, interface between bimetallic phosphides CNTs realized rapid electron transfer. addition, Co, Mo, species in electrocatalytic process exposed increased amounts featuring porous nanosheet structures, which facilitated adsorption reaction intermediates thus evolution performance. particular, optimized CoPv-MoxPv/CNT catalyst possesses an overpotential 138 mV at current density 10 mA cm–2 long-term stability for 24 h. This work offers insights possibilities exploration transition metal-based electrocatalysts through combining multiple synergistic strategies.

Language: Английский

Citations

4

Self-assembled perylene diimide decorated g-C3N4 heterojunction catalyst with strong interfacial charge transfer through π-π interaction for efficient boosted photocatalytic degradation of tetracycline DOI
Guangyu Wu,

Guoyu Tai,

Geng Li

et al.

Surfaces and Interfaces, Journal Year: 2024, Volume and Issue: 53, P. 105008 - 105008

Published: Aug. 25, 2024

Language: Английский

Citations

3

Modulation of metal-organic frameworks by anionic surfactants for rapid adsorption of organic pollutants bisphenol A and chrome black T DOI
Wenwen Li, Jihui Li, Jian Han

et al.

Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2024, Volume and Issue: 697, P. 134323 - 134323

Published: May 22, 2024

Language: Английский

Citations

1

Integrated doped-Ru electrocatalyst with excellent H adsorption–desorption and active site on hollow tubular structures for boosting efficient hydrogen evolution DOI

Yuhao Yin,

Yao Zhu, Qian Long

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 677, P. 1005 - 1013

Published: Aug. 22, 2024

Language: Английский

Citations

1