Polymer Chemistry,
Journal Year:
2024,
Volume and Issue:
16(4), P. 422 - 432
Published: Nov. 14, 2024
We
offer
a
rational
study
of
simple
synthesis
porous
organic
polymers
which
impregnate
their
own
reducing
sites
Ag
+
into
nanoparticles
at
the
meantime
we
utilized
these
nanocomposites
for
hazardous
pollutants.
ACS Applied Energy Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 6, 2025
The
rising
interest
in
conjugated
microporous
polymers
(CMPs)
as
prospective
electrode
materials
for
supercapacitors
(SCs)
has
been
dampened
by
numerous
obstacles.
Many
CMPs
exhibit
poor
conductivity
and
substandard
electrochemical
properties,
limiting
their
practical
applications.
In
response
to
these
issues,
we
successfully
synthesized
Fe-
N-doped
carbon-based
from
Py-BZFC-CMP
Py-PHFC-CMP
through
calcination
potassium
hydroxide
(KOH)
activation
at
800
°C.
resulting
carbons,
designated
Py-BZFC-CMP-800
Py-PHFC-CMP-800,
demonstrated
excellent
attributes,
including
outstanding
thermal
stability
with
a
Td10
up
732
°C,
impressive
char
yields
reaching
87
wt
%.
Furthermore,
exhibited
large
surface
areas,
peaking
376
m2
g–1,
significant
total
pore
volume
(PVtotal)
of
0.36
cm3
g–1.
One
remarkable
material,
produced
KOH
exceptional
performance.
It
achieved
specific
capacitance
324
F
g–1
0.5
A
rivaling
some
the
highest
performing
porous
carbon
reported
date.
Py-PHFC-CMP-800
cycling
stability,
retaining
86%
its
after
5000
charge–discharge
cycles
10
This
project
offers
advancement
field
CMP-based
showcasing
how
rational
precursor
design
pyrolysis
can
lead
creation
high-performance
carbons.
Fe
heteroatom
doping
approach
enhances
functionality
opens
possibilities
owing
use
valuable
application,
efficient
energy
storage
systems.