Protons Selectively Regulate the Asymmetric Activation of the C─H Bonds of Methanol Molecules DOI Open Access
Kun Jia, Peng Jia

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(7)

Published: Feb. 1, 2025

Abstract The activation of C─H bonds under mild conditions is a crucial step in the conversion organic molecules. However, simultaneous methanol can result excessive oxidation, thereby diminishing selectivity for formaldehyde production. We achieved selective by adjusting proton concentration an anhydrous solution, which significantly enhanced dehydrogenation rate methanol. Additionally, we constructed related molecular models to identify sites asymmetric providing new insights further studies on bond activation.

Language: Английский

Protons Selectively Regulate the Asymmetric Activation of the C─H Bonds of Methanol Molecules DOI Open Access
Kun Jia, Peng Jia

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(7)

Published: Feb. 1, 2025

Abstract The activation of C─H bonds under mild conditions is a crucial step in the conversion organic molecules. However, simultaneous methanol can result excessive oxidation, thereby diminishing selectivity for formaldehyde production. We achieved selective by adjusting proton concentration an anhydrous solution, which significantly enhanced dehydrogenation rate methanol. Additionally, we constructed related molecular models to identify sites asymmetric providing new insights further studies on bond activation.

Language: Английский

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