Adsorption-type aluminium-based direct lithium extraction: The effect of heat, salinity and lithium content

Desalination, Journal Year: 2024, Volume and Issue: 577, P. 117406 - 117406

Published: Feb. 2, 2024

Conventional lithium production through solar evaporation is considered a time-consuming procedure, taking substantial 12 to 18 months with significant environmental impacts such as aquifer depletion and damaging the basin's complex hydrological system. Direct Lithium Extraction (DLE) has emerged promising alternative for extraction from brines, offering reduced impact. Although adsorption-type DLE aluminium-based adsorbents sole commercial technology of DLE, debate persists concerning its Technology Readiness Level (TRL), which challenges prevailing notion that undeniably reaches TRL 9. Within this narrative, we propose adsorption capable attaining highest potential in recovery brines when three critical conditions are met: presence certain level salinity, minimum content brine, heat source up brine. In account, an attempt been made elucidate role these criteria during DLE.

Language: Английский

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Challenges and opportunities of recovering lithium from seawater, produced water, geothermal brines, and salt lakes using conventional and emerging technologies

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 498, P. 155349 - 155349

Published: Aug. 30, 2024

Energy storage plays a crucial role in the modern energy landscape, with its applications spanning from renewable integration to electrification of transportation and microgrids. Lithium is key component lithium-ion batteries at core technologies. Increasing demand for lithium has challenged supply chains required rethinking how we source it. This comprehensive review presents critical holistic assessment opportunities challenges sourcing diverse feedstocks, such as seawater, geothermal, produced water (oilfield), salt lake brines. We assess various extraction technologies (precipitation, extraction, electrochemical techniques, membrane processes) considering these three feedstocks. A quantitative comparative analysis conducted across all technologies, factors cost, commercial maturity, operation duration, other relevant parameters determine most promising each feedstock while identifying remaining research technological gaps. Our reveals that Direct Extraction (DLE) characterized by higher selectivity lower environmental impact, demonstrate significant promise enhancing yields geothermal In contrast, processes are identified more suited seawater brines, offering cost-effective scalability despite fouling. Ultimately, efficient illustrated harvesting unconventional resource. The shows adsorption chemical precipitation recovery lake, oilfield brine.

Language: Английский

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Advanced computational strategies for lithium chemical and electrochemical adsorption: A comprehensive state-of-the-art review

Desalination, Journal Year: 2025, Volume and Issue: unknown, P. 118524 - 118524

Published: Jan. 1, 2025

Language: Английский

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Freeze-dried low-curvature porous structure iron phosphate electrodes for efficient lithium extraction from brine

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132021 - 132021

Published: Feb. 1, 2025

Language: Английский

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The sustainable supply of lithium resources from the Qinghai-Tibet plateau salt lakes group: The selection of extraction methods and the assessment of adsorbent application prospects

Desalination, Journal Year: 2024, Volume and Issue: 583, P. 117659 - 117659

Published: April 26, 2024

Language: Английский

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Composite flat-sheet membrane adsorbent of Li2TiO3-Ethylene-co-vinyl alcohol (LTO-EVAL) for lithium extraction

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 496, P. 154122 - 154122

Published: July 20, 2024

Language: Английский

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Enhanced lithium separation from brines using nanofiltration (NF) technology: A review

Desalination, Journal Year: 2024, Volume and Issue: unknown, P. 118148 - 118148

Published: Sept. 1, 2024

Language: Английский

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Critical Review of Lithium Recovery Methods: Advancements, Challenges, and Future Directions

Processes, Journal Year: 2024, Volume and Issue: 12(10), P. 2203 - 2203

Published: Oct. 10, 2024

The integration of lithium into technological applications has profoundly influenced human development, particularly in energy storage systems like lithium-ion batteries. With global demand for surging alongside advancements, the sustainable extraction and recovery this critical material have become increasingly vital. This paper explores lithium’s role, its chemical properties, environmental economic considerations associated with recovery. We examine various methods, including conventional techniques such as hydrometallurgy, pyrometallurgy, direct physical recycling, well emerging technologies mechanochemistry, ion pumping, bioleaching while emphasizing need practices to address challenges. review also discusses challenges future directions Advances technology streamlined processes spurred development innovative techniques. concludes an emphasis on further research essential deepen our understanding their strengths limitations, explore new strategies meet growing indispensable resource.

Language: Английский

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Electrochemical extraction technologies of lithium: Development and challenges

Desalination, Journal Year: 2024, Volume and Issue: 598, P. 118419 - 118419

Published: Dec. 7, 2024

Language: Английский

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Electrochemical Direct Lithium Extraction: A Review of Electrodialysis and Capacitive Deionization Technologies

Resources, Journal Year: 2025, Volume and Issue: 14(2), P. 27 - 27

Published: Feb. 3, 2025

The rapid expansion of lithium-ion battery (LIB) markets for electric vehicles and renewable energy storage has exponentially increased lithium demand, driving research into sustainable extraction methods. Traditional recovery from brine using evaporation ponds is resource intensive, consuming vast amounts water causing severe environmental issues. In response, Direct Lithium Extraction (DLE) technologies have emerged as more efficient, eco-friendly alternatives. This review explores two promising electrochemical DLE methods: Electrodialysis (ED) Capacitive Deionization (CDI). ED employs ion-exchange membranes (IEMs), such cation exchange membranes, to selectively transport ions sources like seawater achieves high rates. IEMs utilize chemical structural properties enhance the selectivity Li+ over competing Mg2+ Na+. However, faces challenges consumption, membrane fouling, reduced efficiency in ion-rich solutions. CDI uses electrostatic forces adsorb onto electrodes, offering low consumption adaptability varying concentrations. Advanced variants, Membrane (MCDI) Flow (FCDI), ion enable continuous operation. MCDI incorporates reduce co-ion interference effects, while FCDI utilizes liquid electrodes scalability operational flexibility. Advancements electrode materials remain crucial efficiency. Validating these methods at pilot scale assessing performance, scalability, economic feasibility under real-world conditions. Future should focus on reducing costs, developing durable selective creating integrated systems overall By addressing challenges, can provide solutions management, minimize impact, support a low-carbon future.

Language: Английский

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