Desalination, Journal Year: 2024, Volume and Issue: unknown, P. 118450 - 118450
Published: Dec. 1, 2024
Language: Английский
Desalination, Journal Year: 2024, Volume and Issue: unknown, P. 118450 - 118450
Published: Dec. 1, 2024
Language: Английский
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Nov. 12, 2024
Abstract Hybrid capacitive deionization (HCDI) emerges as a burgeoning electrochemical desalination technology due to the utilization of profitable pseudocapacitive reactions. Although tunable organic compounds are potential faradaic electrode materials, their insufficient active sites and high water‐solubility restrict practical HCDI applications. Herein, polymer (PNDS) is proposed with diverse redox‐active for deionization. The pronounced molecular aromaticity strong π‐electron delocalization not only endow PNDS framework rigidity, but refine its electronic structure bolster redox activity electron affinity. As an material, demonstrates substantial capacitance 390 F g −1 sustains long‐term stability at 96.3% after 5000 cycles, surpassing reported Na + ‐capturing electrodes. In‐operando monitoring techniques theoretical calculations reveal efficient capture C═N C═O within during repeated electrosorption processes. conceptual demonstration, high‐performance device equipped exhibits impressive salt removal capacity (66.4 mg ), rapid rate (2.2 min ) stable regeneration property. More importantly, integrated system engineered rapidly repeatedly treat saltwater resources human consumption agricultural irrigation, highlighting promising prospects high‐efficiency
Language: Английский
Citations
16Desalination, Journal Year: 2025, Volume and Issue: unknown, P. 118591 - 118591
Published: Jan. 1, 2025
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161124 - 161124
Published: Feb. 1, 2025
Language: Английский
Citations
0Langmuir, Journal Year: 2025, Volume and Issue: unknown
Published: April 2, 2025
Electrode materials are crucial for the performance of redox-flow desalination (RFD), a promising technology addressing increasing global demand freshwater. However, lack efficient and stable electrode options has hindered its widespread application. To overcome this limitation, we developed polyaniline (PANI)-modified graphite foil electrodes, achieving significant reduction in energy consumption RFD (up to 78.8%). Electrochemically deposited onto surface foil, PANI film improves redox behavior enhances performance. At current density 3 mA cm-2, decreased from 125.44 39.26 KJ mol-1 with modification 207.73 40.11 at 6 cm-2. The modified electrodes also achieved salt removal rates 1.60 3.17 μmol cm-2 min-1 respective densities In addition, demonstrated excellent multicycle long-term stability. These findings pave way development high-performance systems have implications other electrochemical technologies.
Language: Английский
Citations
0Water Research, Journal Year: 2025, Volume and Issue: unknown, P. 123646 - 123646
Published: April 1, 2025
Language: Английский
Citations
0ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(44), P. 16434 - 16443
Published: Oct. 21, 2024
Access to freshwater is crucial for a sustainable environment and human ecosystems. Hybrid capacitive deionization (HCDI) based on attractive pseudocapacitive reactions considered promising environmentally friendly energy-saving electrochemical desalination technology. However, the application of HCDI technology still limited, mainly due unsatisfactory ion adsorption ability electrode. Herein, we unveil an innovative redox-active organic molecule (PATD) that showcases outstanding properties desalination. Notably, integration C═O C═N groups in PATD promotes stable efficient reactions. Additionally, rigid molecular structure, combined with minimal HOMO–LUMO energy gap, ensures exceptional redox characteristics superior electron transfer capability molecule, which are substantiated by experimental evidence theoretical studies. As electrode, exhibits significant along excellent long-term stability, retaining 89.0% its capacitance after 5000 cycles NaCl aqueous solution. In practical applications, developed device incorporating electrode demonstrates remarkably high salt removal capacity 56.9 mg g–1, swift average rate 1.9 g–1 min–1, consistent regeneration performance while attaining reliable recovery, highlights prospects technologies.
Language: Английский
Citations
3Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 157769 - 157769
Published: Nov. 1, 2024
Language: Английский
Citations
3Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(6), P. 114324 - 114324
Published: Oct. 2, 2024
Language: Английский
Citations
1Small, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 29, 2024
Battery-type faradaic materials are considered a class of promising electrodes for capacitive deionization (CDI) due to their superior ability store ions through redox reactions. However, the desalination potential such electrode has not been fully explored subject accessibility, conductivity, stability, etc. Herein, embedded battery material Ag nanoparticles is designed in capsule-structural units composed graphene and constructed freestanding composite CDI. Particularly, these confined interconnected capsules can be both efficiently accessed by electrolyte rationally protected capsule networks, significantly unlocking as materials. Impressively, optimized Ag-involved anodes achieve an ultrahigh NaCl capacity ≈360 mg g
Language: Английский
Citations
0Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: unknown, P. 114626 - 114626
Published: Oct. 1, 2024
Language: Английский
Citations
0