Published: Jan. 1, 2024
Language: Английский
Published: Jan. 1, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159779 - 159779
Published: Jan. 1, 2025
Language: Английский
Citations
5Water Research, Journal Year: 2025, Volume and Issue: 276, P. 123291 - 123291
Published: Feb. 13, 2025
Language: Английский
Citations
1Desalination, Journal Year: 2024, Volume and Issue: unknown, P. 118461 - 118461
Published: Dec. 1, 2024
Language: Английский
Citations
4Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 131599 - 131599
Published: Jan. 1, 2025
Language: Английский
Citations
0Advanced Science, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 20, 2025
Abstract Covalent organic frameworks (COFs) have emerged as prominent membrane materials for efficiently fractionating molecules and ions due to their unique pore structure. However, the fabrication of free‐standing COF nanofilms with high crystallinity remains an arduous undertaking, feasible methods that can enable precise control over film microstructure are barely reported. This work conceives exquisite interface‐confined catalytic strategy prepare Tp‐BD(OH) 2 nanofilm anisotropic structure analogously conventional polymeric membranes. Experimental data molecular simulations reveal hydroxyl groups on framework substantially capture anchor acid catalyst through hydrogen bonding interactions at incipient stage interfacial polycondensation, instigating confined catalysis self‐termination reaction interface. The distinctive asymmetric endows a record‐breaking pure water permeance 525.3 L m −2 h −1 bar unprecedented dye/salt selectivity 648.6, surpassing other reported films state‐of‐the‐art nanofiltration membranes, well enduring structural durability chemical stability. implemented opens up new avenue regulating holds broad prospects rational design high‐performance membranes sustainable purification treatment.
Language: Английский
Citations
0Elsevier eBooks, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132301 - 132301
Published: Feb. 1, 2025
Language: Английский
Citations
0Journal of Membrane Science, Journal Year: 2025, Volume and Issue: unknown, P. 123927 - 123927
Published: March 1, 2025
Language: Английский
Citations
0Small, Journal Year: 2025, Volume and Issue: unknown
Published: April 3, 2025
Vapor-driven smart materials show significant advantages in areas such as intelligent control, gas detection, and information transmission. However, their typically singular response mechanisms pose challenges for achieving binary behaviors within a single system. Drawing inspiration from bimetallic strips, dual-layer covalent organic framework (DL-COF) membrane is developed with hierarchical pore structure. This exhibits asymmetric expansion or contraction on either side when exposed to morpholine 1,4-dioxane vapors, enabling behaviors. The driving forces underlying these responses are the shifts hydrogen bond equilibrium caused by chain-like bonding swelling effects two layers, which have different degrees of crystallinity. structure further enhances rapid mass transfer, DL-COF achieve an impressive time just 0.6 s. By leveraging its distinct responsiveness can be effectively utilized visual translation encrypted information, reliable decoding gas-encrypted Morse code continuous programmatic vapor inputs.
Language: Английский
Citations
0Journal of Membrane Science, Journal Year: 2025, Volume and Issue: unknown, P. 124061 - 124061
Published: April 1, 2025
Language: Английский
Citations
0