Applied Catalysis A General, Journal Year: 2024, Volume and Issue: unknown, P. 119982 - 119982
Published: Oct. 1, 2024
Language: Английский
Applied Catalysis A General, Journal Year: 2024, Volume and Issue: unknown, P. 119982 - 119982
Published: Oct. 1, 2024
Language: Английский
Device, Journal Year: 2024, Volume and Issue: 2(3), P. 100283 - 100283
Published: Feb. 7, 2024
The formation of interfacial electric fields using semiconductors/co-catalysts can effectively improve the carrier migration efficiency photocatalytic devices. Herein, an ultrathin 2D/2D/2D black phosphorus/MXene/MBene (denoted as BP/Ti3C2/MoB) ternary heterojunction with enhanced charge transfer is designed dual fields. formed by BP/Ti3C2 and Ti3C2/MoB accelerate photogenerated transfer, change position d-band center Ti atoms, lower energy level antibonding state, enhance adsorption effect H∗ active species, which ultimately leads to significant enhancement activity. results show that optimum visible-light-induced H2 evolution rate BP/Ti3C2/MoB 8,624 μmol g−1 h−1, has a very high factor (∼1,563%) compared pure BP. charge-transfer pathways mechanism are further elucidated some state-of-the-art spectroscopic characterizations theoretical calculations.
Language: Английский
Citations
56Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(15), P. 5311 - 5335
Published: Jan. 1, 2024
The panorama of the latest developments emerging porphyrin-based MOFs for photo(electro)catalytic CO 2 reduction is shown.
Language: Английский
Citations
38EcoEnergy, Journal Year: 2024, Volume and Issue: 2(1), P. 22 - 44
Published: Feb. 14, 2024
Abstract Layered double hydroxides (LDHs)‐based photocatalysts have generated widespread interest owing to their great potential for solving both energy and environmental issues through directly converting nonconsumable solar energy. Numerous methods been investigated analyzed in recent years promote the photocatalytic efficiency of LDHs. Z‐scheme heterojunction that mimics artificial photosynthesis is employed photocatalysis outstanding advantages, such as high quantum efficiency, separation redox sites, low recombination photocarriers. Herein, various LDHs‐based are briefly reviewed. associated with materials exhibit performance, these types hybrids applied H 2 O splitting, CO reduction, pollution degradation, which introduced summarized detail. In end, a brief conclusion focused on future challenges expectations LDH‐based system presented. We expect more advances photocatalyst can be achieved field coming days.
Language: Английский
Citations
32Precision Chemistry, Journal Year: 2024, Volume and Issue: 2(2), P. 49 - 56
Published: Jan. 17, 2024
An energy crisis and significant anthropogenic CO
Language: Английский
Citations
30Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 350, P. 127742 - 127742
Published: April 29, 2024
Language: Английский
Citations
24Journal of Cleaner Production, Journal Year: 2024, Volume and Issue: 458, P. 142416 - 142416
Published: May 6, 2024
Language: Английский
Citations
19CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Journal Year: 2024, Volume and Issue: 65, P. 174 - 184
Published: Oct. 1, 2024
Language: Английский
Citations
18Carbon Neutralization, Journal Year: 2025, Volume and Issue: 4(1)
Published: Jan. 1, 2025
ABSTRACT The Ni/CeO 2 catalyst stands out among various solid metal oxide catalysts for its exceptional catalytic proficiency, positioning it as a prime candidate the industrialization of methanation processes. This review thoroughly examines prevalent challenges associated with in reactions, compiles current strategies to overcome these hurdles, and presents novel perspectives. elucidates structural characteristics applications discusses synthesis methods their respective merits demerits, explores reaction systems at both laboratory industrial scales, clarifies underlying mechanisms. Furthermore, underscores mainstream approaches enhance low‐temperature activity mitigate decrement due Ni agglomeration. concludes by proposing future directions improving preventing deactivation, encompassing development innovative architectures, integrating in‐situ characterization theoretical calculations, investigating photothermal systems. Undoubtedly, scientific researchers will persistently strive develop high across broad temperature range robust stability, driving CO technology foreseeable future.
Language: Английский
Citations
3Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 7, 2025
Abstract Photocatalytic CO 2 reduction into high‐value C 2+ products such as H 6 is of great importance but challenging due to their multi‐electron steps and high energy barrier C─C coupling. Moreover, improving its solar‐to‐chemical (STC) conversion efficiency in pure water beyond the current 1% empirical value also a significant challenge. Herein, graphite carbon nitride (g‐C 3 N 4 ) nanosheets with controllable (C) doping nitrogen (N) vacancies (PCCN‐x) are designed through biochar‐tailored protocol for efficiently selectively photo‐converting . The optimal PCCN‐10 photocatalyst enables achievement an exceptional activity 99.14 µmol g −1 h selectivity 80.33% over 20 water. A record STC ≈1.13% solar fuel production from O vapor achieved without any other inputs. Outdoor tests demonstrated impressive ‐to‐C photo‐conversion rate 43.17 water, stable 50 period. Critically, experimental theoretical calculations further confirm pivotal role bridged sites activating molecules promoting formation coupling intermediate ( * OCCO), which very beneficial performance this work photocatalytic fuels paves way large‐scale broader sustainable applications.
Language: Английский
Citations
3Carbon, Journal Year: 2024, Volume and Issue: 222, P. 118977 - 118977
Published: Feb. 29, 2024
Language: Английский
Citations
12