Coatings,
Journal Year:
2023,
Volume and Issue:
13(8), P. 1457 - 1457
Published: Aug. 18, 2023
Aqueous
zinc
ion
batteries
(AZIBs)
are
considered
as
one
of
the
most
promising
energy
storage
technologies
due
to
their
advantages
being
low
in
cost,
high
safety,
and
environmental
friendliness.
However,
dendrite
growth
parasitic
side
reactions
on
metal
anode
during
cycling
lead
a
coulombic
efficiency
an
unsatisfactory
lifespan,
which
seriously
hinders
further
development
AZIBs.
In
this
regard,
metal–organic
frameworks
(MOFs)
deemed
suitable
surface
modification
materials
for
Zn
deal
with
abovementioned
problems
because
characteristics
large
specific
area,
porosity,
excellent
tunability.
Considering
rapidly
growing
research
enthusiasm
topic
recent
years,
herein,
we
summarize
advances
design,
fabrication,
application
MOFs
derivatives
anode.
The
relationships
between
nano/microstructures,
synthetic
methods
MOF-based
materials,
enhanced
electrochemical
performance
via
MOF
systematically
summarized
discussed.
Finally,
existing
future
area
proposed.
Batteries & Supercaps,
Journal Year:
2023,
Volume and Issue:
6(10)
Published: Aug. 14, 2023
Abstract
Aqueous
zinc‐ion
batteries
(ZIBs)
stand
out
as
promising
next‐generation
energy
storage
systems.
However,
the
Zn
anode
failure
caused
by
unstable
Zn/electrolyte
interface
hinders
their
practical
applications.
Constructing
artificial
layer
on
surface
provides
an
effective
method
to
optimize
interfacial
stability
and
mitigate
issues,
while
most
of
current
investigations
put
emphasis
discussion
2+
H
2
O
regulation,
we
notice
that
anions
hydrogen
evolution
reaction
(HER)
intermediates
also
play
a
crucial
role
in
occurrence
side
reactions,
thus
comprehensive
evaluation
modulation
strategies
regarding
all
different
ion
species
ZIBs
system
is
helpful
for
developing
advanced
interface.
Herein,
this
work
systematically
reviews
achievements
about
cation
anion
stabilizing
emphasizes
relationship
between
material
properties
ionic
regulation
mechanisms
first
time,
aiming
provide
unprecedented
design
reference.
Furthermore,
some
noteworthy
points
perspectives
are
proposed,
which
has
guiding
significance
realization
high‐performance
multi‐level
regulated
anode.
Chem & Bio Engineering,
Journal Year:
2024,
Volume and Issue:
1(5), P. 381 - 413
Published: June 13, 2024
Aqueous
zinc
ion
batteries
(AZIBs)
have
emerged
as
promising
candidates
for
large-scale
energy
storage
systems
during
post
lithium-ion
era,
drawing
attention
their
environmental-friendliness,
cost-effectiveness,
high
safety,
and
minimal
manufacturing
constraints.
However,
the
long-standing
roadblock
to
commercialization
lies
in
dendrite
growth
parasitic
reactions
(hydrogen
evolution
reaction
water-induced
corrosion)
of
metallic
anode,
which
strongly
depends
on
complicated
interphasial
chemistries.
This
review,
with
a
focus
optimizing
anode/electrolyte
interphase,
begins
by
elucidating
intrinsic
factor
ions'
migration,
diffusion,
nucleation,
electro-crystallization,
nucleus
AZIBs,
along
underlying
scientific
principles.
Then
electrochemical
theories
pertinent
plating
behavior
interphase
is
systematically
clarified,
thereby
enriching
understanding
how
anode
structure
electrolyte
design
principles
relate
electrode
interphase.
Accordingly,
rational
strategies
emphasizing
structural
engineering
been
summarized
discussed
detail.
The
mechanisms,
advances,
drawbacks,
future
outlook
these
are
analyzed
purpose
fabricating
chemically
electrochemically
stable
Finally,
challenging
perspectives
major
directions
proposed.
review
expected
shed
light
developing
high-performance
Zn
anodes
use
sustainable
AZIBs.
Coatings,
Journal Year:
2023,
Volume and Issue:
13(8), P. 1457 - 1457
Published: Aug. 18, 2023
Aqueous
zinc
ion
batteries
(AZIBs)
are
considered
as
one
of
the
most
promising
energy
storage
technologies
due
to
their
advantages
being
low
in
cost,
high
safety,
and
environmental
friendliness.
However,
dendrite
growth
parasitic
side
reactions
on
metal
anode
during
cycling
lead
a
coulombic
efficiency
an
unsatisfactory
lifespan,
which
seriously
hinders
further
development
AZIBs.
In
this
regard,
metal–organic
frameworks
(MOFs)
deemed
suitable
surface
modification
materials
for
Zn
deal
with
abovementioned
problems
because
characteristics
large
specific
area,
porosity,
excellent
tunability.
Considering
rapidly
growing
research
enthusiasm
topic
recent
years,
herein,
we
summarize
advances
design,
fabrication,
application
MOFs
derivatives
anode.
The
relationships
between
nano/microstructures,
synthetic
methods
MOF-based
materials,
enhanced
electrochemical
performance
via
MOF
systematically
summarized
discussed.
Finally,
existing
future
area
proposed.
