Stability of the Au/electrolyte interface during hydrogen evolution: A Cyclic Plasmo-Voltammetry study DOI Creative Commons
Moritz J. Feil,

Simon Leisibach,

Markus Becherer

et al.

Electrochimica Acta, Journal Year: 2024, Volume and Issue: unknown, P. 145509 - 145509

Published: Dec. 1, 2024

Language: Английский

Exploring alkaline electrolytes for enhanced hydrogen generation using CuO/TiO2/PPy photocatalyst under diffused light DOI

A. Rami,

Paramsinh Zala,

Brijesh Tripathi

et al.

Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 114532 - 114532

Published: April 1, 2025

Language: Английский

Citations

0
Electrocatalysis, diverse and forever young DOI
Tristan Asset, Alexandr G. Oshchepkov, Frédéric Maillard

et al.

Electrochimica Acta, Journal Year: 2024, Volume and Issue: unknown, P. 145174 - 145174

Published: Sept. 1, 2024

Language: Английский

Citations

3
Grand-Canonical Variational Theory of Oscillatory Fields at Electrified Metal-Solution Interfaces DOI Creative Commons

M. Zhang,

Yanxia Chen, Michael Eikerling

et al.

Published: Aug. 16, 2024

The oscillatory fields near the electrode surface are not considered in classical models of electrical double layer (EDL), while holding immense importance for stability, activity, and selectivity interfacial reactions. Here, we develop a unified theoretical framework EDL under constant potential conditions, combining an orbital-free DFT treatment electrons on metal side statistical field theory charged fluids electrolyte side. resulting grand is hybrid functional electron density, electric potential, solvent polarization, referred to as density-potential-polarization (DPPFT). Built DPPFT, model Ag(110)-KPF6 aqueous interface parameterized with experimental capacitance (Cdl) data. calibrated then employed study influence electronic, ion, properties structure capacitance. Cdl profiles at different crystal faces various solutions rationalized coherently. We reveal that intensified ion layering leads elevated capacitances zero charge (PZC) narrowed ionic peaks profile. Contrary models, DPPFT allows co-ions have appreciable density surface, opening avenue decipher origin anomalous anion effects electrochemical CO2 reduction. presented adds much-needed realism modelling EDLs.

Language: Английский

Citations

2
Stability of the Au/electrolyte interface during hydrogen evolution: A Cyclic Plasmo-Voltammetry study DOI Creative Commons
Moritz J. Feil,

Simon Leisibach,

Markus Becherer

et al.

Electrochimica Acta, Journal Year: 2024, Volume and Issue: unknown, P. 145509 - 145509

Published: Dec. 1, 2024

Language: Английский

Citations

0