Advanced Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Aug. 28, 2024
Protonic
ceramic
electrochemical
cells
(PCECs)
have
received
considerable
attention
as
they
can
directly
generate
electricity
and/or
produce
chemicals.
Development
of
the
electrodes
with
trifunctionalities
oxygen
reduction/evolution
and
nonoxidative
ethane
dehydrogenation
is
yet
challenging.
Here
these
findings
are
reported
in
design
trifunctional
for
PCECs
a
detailed
composition
Mn
Energy Materials,
Journal Year:
2024,
Volume and Issue:
4(1)
Published: Jan. 8, 2024
As
a
clean
and
efficient
energy
conversion
device,
solid
oxide
fuel
cells
have
been
garnering
attention
due
to
their
environmentally
friendly
adaptability.
Consequently,
they
become
one
of
the
current
research
directions
new
energy.
The
cathode,
as
electrochemical
reaction
site
an
oxidation
atmosphere
in
cells,
plays
key
role
determining
output
performance.
In
recent
years,
development
double
perovskite
cathode
materials
with
mixed
ionic
electronic
conductors
has
made
significant
progress
intermediate-temperature
(600-800
°C)
cells.
These
potential
deliver
higher
power
densities
improved
stability,
making
them
promising
candidates
for
future
cell
applications.
Fe-based
structure
material
gained
extensive
its
adjustable
crystal
performance,
it
A(A’)
or
B(B’)
positions
AA’BB’O6
structure.
This
several
advantages,
such
high
oxygen
catalytic
activity,
low
thermal
expansion
coefficient,
compatibility
electrolyte.
An
increasing
number
researchers
exploring
performance
mechanism
by
modifying
adjusting
microstructure,
structure,
this
paper,
LnBaFe2O5
Sr2Fe2-xMoxO6
is
reviewed
highlight
effects
various
modification
methods
developed
on
these
materials.
Furthermore,
are
prospected.
Energy Reviews,
Journal Year:
2024,
Volume and Issue:
3(4), P. 100085 - 100085
Published: March 30, 2024
Perovskite
oxides
with
high
oxygen
ionic
conductivity
have
played
major
roles
in
five
important
devices
of
significance
for
clean
energy
future
and
automated
manufacturing,
i.e.,
solid
oxide
fuel
cell,
electrolysis
permeable
membranes,
gas
sensors,
pumps,
all
which
exhibit
different
performance
requirements
challenges.
Although
improving
the
ion
transport
within
perovskite
lattice
serves
as
key
to
increasing
efficiencies
perovskites'
components
these
devices,
criteria,
structures,
and/or
physicochemical
properties
often
become
complicating
factors.
It
is
understood
that
mainly
determined
by
crystal
structure,
A/B-site
cations
their
content,
vacancies.
This
perspective
overviews
factors,
can
be
manipulated
adapt
needs
devices.
Brief
discussions
are
then
made
on
concepts,
status,
outlook
each
device
together
strategies
performance.
The
summaries
insights
provided
this
review
anticipated
promote
more
strategic
research
development
directions
activities
applications.
Advanced Energy Materials,
Journal Year:
2024,
Volume and Issue:
14(12)
Published: Feb. 6, 2024
Abstract
Discovering
new
materials
that
efficiently
catalyze
the
oxygen
reduction
and
evolution
reactions
is
critical
for
facilitating
widespread
adoption
of
solid
oxide
fuel
cell
electrolyzer
(SOFC/SOEC)
technologies.
Here,
machine
learning
(ML)
models
are
developed
to
predict
perovskite
catalytic
properties
SOFC/SOEC
applications,
including
surface
exchange,
diffusivity,
area
specific
resistance
(ASR).
The
based
on
trivial‐to‐calculate
elemental
features
more
accurate
dramatically
faster
than
best
ab
initio‐derived
features,
potentially
eliminating
need
initio
calculations
in
descriptor‐based
screening.
model
ASR
enables
temperature‐dependent
predictions,
has
well
calibrated
uncertainty
estimates
online
accessibility.
Use
temporal
cross‐validation
reveals
be
effective
at
discovering
promising
prior
their
initial
discovery,
demonstrating
can
make
meaningful
predictions.
Using
SHapley
Additive
ExPlanations
(SHAP)
approach,
detailed
discussion
different
approaches
featurization
provided
ML
property
prediction.
Finally,
used
screen
19
million
perovskites
develop
a
list
cheap,
earth‐abundant,
stable,
high
performing
materials,
find
some
top
contain
mixtures
less‐explored
elements
(e.g.,
K,
Bi,
Y,
Ni,
Cu)
worth
exploring
detail.
Advanced Science,
Journal Year:
2023,
Volume and Issue:
10(36)
Published: Oct. 28, 2023
Proton-conducting
solid
oxide
fuel
cells
(H-SOFCs)
have
the
potential
to
be
a
promising
technology
for
energy
conversion
and
storage.
To
achieve
high
chemical
compatibility
catalytic
activity,
nickel-doped
barium
ferrate
with
triple
conducting
ability
is
developed
as
cathodes
H-SOFCs,
presenting
an
impressive
electrochemical
performance
at
intermediate
temperatures.
The
cell
optimized
BaCe0.26
Ni0.1
Fe0.64
O3
-δ
(BCNF10)
composite
cathode
reaches
outstanding
of
1.04
W
cm-2
600
°C.
electrocatalytic
capacity
can
attributed
its
significant
proton
conductivity
which
confirmed
through
hydrogen
permeation
experiments.
Density
functional
theory
(DFT)
calculations
are
further
conducted
reveal
that
presence
nickel
enhance
processes
hydration
formation
migration,
leading
improve
electro-catalytic
activity.