Advanced Materials,
Journal Year:
2023,
Volume and Issue:
35(51)
Published: May 16, 2023
Lithium
(Li)-based
batteries
are
gradually
evolving
from
the
liquid
to
solid
state
in
terms
of
safety
and
energy
density,
where
all
solid-state
Li-metal
(ASSLMBs)
considered
most
promising
candidates.
This
is
demonstrated
by
Bluecar
electric
vehicle
produced
Bolloré
Group,
which
utilized
car-sharing
services
several
cities
worldwide.
Despite
impressive
progress
development
ASSLMBs,
their
avenues
for
recycling
them
remain
underexplored,
combined
with
current
explosion
spent
Li-ion
batteries,
they
should
attract
widespread
interest
academia
industry.
Here,
potential
challenges
ASSLMBs
as
compared
analyzed
prospects
summarized
analyzed.
Drawing
on
lessons
learned
battery
recycling,
it
important
design
sustainable
technologies
before
gain
market
adoption.
A
battery-recycling-oriented
also
highlighted
promote
rate
maximize
profitability.
Finally,
future
research
directions,
challenges,
outlined
provide
strategies
achieving
ASSLMBs.
Global Challenges,
Journal Year:
2023,
Volume and Issue:
7(3)
Published: Feb. 5, 2023
Abstract
In
the
recycling
of
retired
lithium‐ion
batteries
(LIBs),
cathode
materials
containing
valuable
metals
should
be
first
separated
from
current
collector
aluminum
foil
to
decrease
difficulty
and
complexity
in
subsequent
metal
extraction.
However,
strong
binding
force
organic
binder
polyvinylidene
fluoride
(PVDF)
prevents
effective
separation
Al
foil,
thus
affecting
recycling.
This
paper
reviews
composition,
property,
function,
mechanism
PVDF,
elaborates
on
technologies
material
(e.g.,
physical
separation,
solid‐phase
thermochemistry,
solution
chemistry,
solvent
chemistry)
as
well
corresponding
reaction
behavior
transformation
mechanisms
PVDF.
Due
characteristic
variation
systems,
dissolution,
swelling,
melting,
degradation
processes
PVDF
exhibit
considerable
differences,
posing
new
challenges
efficient
spent
LIBs
worldwide.
It
is
critical
separate
recycle
reduce
environmental
risks
recovery
resources.
Developing
fluorine‐free
alternative
solid‐state
electrolytes
a
potential
way
mitigate
pollution
EV
era.
Green Chemistry,
Journal Year:
2023,
Volume and Issue:
25(8), P. 2992 - 3015
Published: Jan. 1, 2023
The
state-of-the-art
salt-thermal
method
to
recycle
spent
LIBs
enables
preferential
Li
recovery,
recovery
of
anode/cathode
material,
direct
regeneration
degraded
and
one-step
re-synthesis
advanced
functional
materials.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(23)
Published: March 27, 2024
Abstract
The
rapid
growth
of
electric
vehicle
use
is
expected
to
cause
a
significant
environmental
problem
in
the
next
few
years
due
large
number
spent
lithium‐ion
batteries
(LIBs).
Recycling
LIBs
will
not
only
alleviate
problems
but
also
address
challenge
limited
natural
resources
shortages.
While
several
hydro‐
and
pyrometallurgical
processes
are
developed
for
recycling
different
components
batteries,
direct
regeneration
presents
clear
environmental,
economic
advantages.
principle
approach
restoring
electrochemical
performance
by
healing
defective
structure
materials.
Thus,
development
technology
largely
depends
on
formation
mechanism
defects
LIBs.
This
review
systematically
details
degradation
mechanisms
types
found
diverse
cathode
materials,
graphite
anodes,
current
collectors
during
battery's
lifecycle.
Building
this
understanding,
principles
methodologies
directly
rejuvenating
materials
within
outlined.
Also
main
challenges
solutions
large‐scale
proposed.
Furthermore,
aims
pave
way
discarded
offering
theoretical
foundation
practical
guidance.
Advanced Materials,
Journal Year:
2023,
Volume and Issue:
35(51)
Published: May 16, 2023
Lithium
(Li)-based
batteries
are
gradually
evolving
from
the
liquid
to
solid
state
in
terms
of
safety
and
energy
density,
where
all
solid-state
Li-metal
(ASSLMBs)
considered
most
promising
candidates.
This
is
demonstrated
by
Bluecar
electric
vehicle
produced
Bolloré
Group,
which
utilized
car-sharing
services
several
cities
worldwide.
Despite
impressive
progress
development
ASSLMBs,
their
avenues
for
recycling
them
remain
underexplored,
combined
with
current
explosion
spent
Li-ion
batteries,
they
should
attract
widespread
interest
academia
industry.
Here,
potential
challenges
ASSLMBs
as
compared
analyzed
prospects
summarized
analyzed.
Drawing
on
lessons
learned
battery
recycling,
it
important
design
sustainable
technologies
before
gain
market
adoption.
A
battery-recycling-oriented
also
highlighted
promote
rate
maximize
profitability.
Finally,
future
research
directions,
challenges,
outlined
provide
strategies
achieving
ASSLMBs.
