Holistic optimization strategies for advanced aqueous zinc iodine batteries DOI Creative Commons
Junwei Xu, Zhongyuan Huang,

Haihui Zhou

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 72, P. 103596 - 103596

Published: June 25, 2024

Zinc-based batteries are gaining prominence as promising alternatives to lithium-ion (LIBs) in the pursuit of Net-Zero goals, owing their cost-effectiveness, scalability, and reduced resource dependency. Aqueous rechargeable zinc-iodine (Zn-I2) batteries, particular, emerging an enticing choice for future energy storage systems, thanks eco-friendly nature, impressive theoretical capacity, energy/power density. Nevertheless, several challenges, including well-known polyiodide shuttling phenomenon, suboptimal thermodynamic stability, issues like corrosion dendrite formation on Zn metal anodes, impede practical implementation. Tremendous progress has been achieved circumvent these recent years, though a comprehensive review article both entry-level experienced researchers is still lacking up date. This aims at discussing fundamentals, solutions enable understanding electrochemistry mechanisms, systematically summarizing past, present, technologies strategies involving iodine cathode design modification, interlayer construction/separator electrolytes optimization, anodes protection. Additionally, based achievements, some directions efforts developing high-performance Zn−I2 proposed accelerate commercial applications.

Language: Английский

Optimization strategies toward advanced aqueous zinc-ion batteries: From facing key issues to viable solutions DOI
Xiangye Li, Lu Wang,

Yihan Fu

et al.

Nano Energy, Journal Year: 2023, Volume and Issue: 116, P. 108858 - 108858

Published: Sept. 2, 2023

Language: Английский

Citations

115
Comprehensive Review of Electrolyte Modification Strategies for Stabilizing Zn Metal Anodes DOI Open Access
Yuxuan Liang,

Meijia Qiu,

Peng Sun

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(51)

Published: Aug. 24, 2023

Abstract In response to the need of sustainable development, there is an increasing demand for electrical energy storage, leading a stimulated pursuit advanced batteries. Aqueous zinc ion batteries (AZIBs) have attracted much attention due their low cost, high safety, and environmental friendliness. Despite great efforts made by researchers in designing developing high‐performance AZIBs, several challenges remain. Particularly Zn anode, growth dendrites occurance various side reactions significantly hinder advancement AZIBs. This review article aims discuss principles electrolyte's structure properties, faced AZIBs anodesm strategies improve battery performance through electrolyte modification systematic manner. conclusion, potential future directions aimed at enhancing stability anodes cathodes are proposed ensure that research geared toward achieving realistic targets commercializing

Language: Английский

Citations

93
Ionogels: Preparation, Properties and Applications DOI
Chang‐Cun Yan, Weizheng Li, Ziyang Liu

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: unknown

Published: Dec. 31, 2023

Abstract Ionogels, composed of ionic liquids and supporting networks, possess a plethora exceptional properties, including nonvolatility, remarkable thermal electrochemical stability, elevated mechanical strength, as well outstanding conductivity. Based on these extraordinary characteristics, ionogels have found extensive applications in diverse fields encompassing functional materials, sensors, soft electronics, solid electrolytes, biomedicine. In recent years, witnessed significant advancements emerged highly popular subject matter. Consequently, this review provides comprehensive overview the latest progress made realm ionogels. The preparation methods are initially introduced following concise introduction. Subsequently, properties ionogels, high low temperature resistance, conductivity, stimuli‐response self‐healing recyclability their structure‐property relationships, comprehensively discussed. Moreover, utilization skins, adhesions other domains also elaborated upon extensively. Finally, after succinct summary, challenges prospects regarding future development thoroughly deliberated.

Language: Английский

Citations

90
Hetero‐Polyionic Hydrogels Enable Dendrites‐Free Aqueous Zn‐I2 Batteries with Fast Kinetics DOI
Jin‐Lin Yang, Zehua Yu, Jiawen Wu

et al.

Advanced Materials, Journal Year: 2023, Volume and Issue: 35(44)

Published: Aug. 23, 2023

Rechargeable aqueous Zn-I2 batteries (ZIB) are regarded as a promising energy storage candidate. However, soluble polyiodide shuttling and rampant Zn dendrite growth hamper its commercial implementation. Herein, hetero-polyionic hydrogel is designed the electrolyte for ZIBs. On cathode side, iodophilic polycationic (PCH) effectively alleviates shuttle effect facilitates redox kinetics of iodine species. Meanwhile, polyanionic (PAH) toward metal anode uniformizes Zn2+ flux prevents surface corrosion by electrostatic repulsion polyiodides. Consequently, symmetric cells with PAH demonstrate remarkable cycling stability over 3000 h at 1 mA cm-2 (1 mAh ) 800 10 (5 ). Moreover, full PAH-PCH deliver low-capacity decay 0.008 ‰ per cycle during 18 000 cycles 8 C. This work sheds light on electrolytes design long-life conversion-type batteries.

Language: Английский

Citations

84
Tough, Anti‐Fatigue, Self‐Adhesive, and Anti‐Freezing Hydrogel Electrolytes for Dendrite‐Free Flexible Zinc Ion Batteries and Strain Sensors DOI
Zong‐Ju Chen, Tianyu Shen,

Min‐Hao Zhang

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(26)

Published: Feb. 27, 2024

Abstract Quasi‐solid aqueous zinc ion batteries (AZIBs) based on flexible hydrogel electrolytes are promising substitutions of lithium‐ion owing to their intrinsic safety, low cost, eco‐friendliness and wearability. However, it remains a challenge lower the freezing point without sacrificing fundamental advantages such as conductivity mechanical properties. Herein, an all‐around electrolyte is constructed through convenient energy dissipation strategy via rapid reversible intramolecular/intermolecular ligand exchanges between Zn 2+ alterdentate ligands. The as‐obtained exhibits excellent properties, fatigue resistance, high Zn‐ion (38.2 mS cm −1 ), good adhesion (19.1 kPa), ultra‐low (−97 °C). Due ligands help improve solvation structure guide uniform deposition, Zn||Zn symmetric cells show stable plating/stripping behavior long‐term cycle stability. Zn||V 2 O 5 full exhibit large capacity 230.6 mAh g retention 75.2% after 1000 cycles. Furthermore, AZIBs operate stably even under extreme conditions including temperature (−40 °C) bending angle (180°). mechanically damage‐resistant can also be utilized in strain sensors. This work offers facile for developing deformation‐resistant, dendrite‐free, environmentally adaptable AZIBs.

Language: Английский

Citations

53
Rapidly Synthesized Single‐Ion Conductive Hydrogel Electrolyte for High‐Performance Quasi‐Solid‐State Zinc‐ion Batteries DOI
Tianyu Qiu, Tonghui Wang, Wensi Tang

et al.

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 62(45)

Published: Sept. 20, 2023

Single-ion conductive electrolytes can largely eliminate electrode polarization, reduce the proportion of anion migration and inhibit side reactions in batteries. However, they usually suffer from insufficient ion conductivity due to strong interaction between cations cationic receptors. Here we report an ultrafast light-responsive covalent organic frameworks (COF) with sulfonic acid groups modification as acrylamide polymerization initiator. Benefiting reduced electrostatic Zn2+ through solvation effects, as-prepared COF-based hydrogel electrolyte (TCOF-S-Gel) receives up 27.2 mS/cm transference number 0.89. In addition, sufficient hydrogen bonds endow single-ion TCOF-S-Gel have good water retention superb mechanical properties. The assembled Zn||TCOF-S-Gel||MnO2 full zinc-ion battery exhibits high discharge capacity (248 mAh/g at 1C), excellent rate capability (90 10C) superior cycling performance. These enviable results enlist instantaneously photocured be qualified large-scaled flexible high-performance quasi-solid-state

Language: Английский

Citations

47
Hydrogel Electrolyte Enabled High‐Performance Flexible Aqueous Zinc Ion Energy Storage Systems toward Wearable Electronics DOI Open Access

Gao Weng,

Xianzhong Yang, Zhiqi Wang

et al.

Small, Journal Year: 2023, Volume and Issue: 19(48)

Published: Aug. 2, 2023

To cater to the swift advance of flexible wearable electronics, there is growing demand for energy storage system (ESS). Aqueous zinc ion systems (AZIESSs), characterizing safety and low cost, are competitive candidates storage. Hydrogels, as quasi-solid substances, appropriate burgeoning electrolytes that enable high-performance AZIESSs. However, challenges still remain in designing suitable comprehensive hydrogel electrolyte, which provides AZIESSs with high reversibility versatility. Hence, application electrolyte-based electronics restricted. A thorough review required electrolyte design pave way This delves into engineering desirable from perspective designers. Detailed descriptions basic characteristics, Zn anode, cathode stabilization effects well their functional properties provided. Moreover, discussed, expecting accelerate strides toward lives. Finally, corresponding future development trends also presented, hope inspiring readers.

Language: Английский

Citations

42
A Sustainable Dual Cross-Linked Cellulose Hydrogel Electrolyte for High-Performance Zinc-Metal Batteries DOI Creative Commons
Haodong Zhang, Xiaotang Gan, Yuyang Yan

et al.

Nano-Micro Letters, Journal Year: 2024, Volume and Issue: 16(1)

Published: Feb. 2, 2024

Aqueous rechargeable Zn-metal batteries (ARZBs) are considered one of the most promising candidates for grid-scale energy storage. However, their widespread commercial application is largely plagued by three major challenges: The uncontrollable Zn dendrites, notorious parasitic side reactions, and sluggish

Language: Английский

Citations

42
Hydrogel-stabilized zinc ion batteries: progress and outlook DOI
Le Li,

Shaofeng Jia,

Yue Shi

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(11), P. 6404 - 6422

Published: Jan. 1, 2024

We explored effective solutions for enhancing the operational stability of ZIBs by designing hydrogel electrolytes that protect zinc anodes, cathodes, and electrolytes.

Language: Английский

Citations

42
Advanced electrolytes for high-performance aqueous zinc-ion batteries DOI

Jie Wei,

Pengbo Zhang,

Jingjie Sun

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

This review presents an comprehensive overview of various advanced aqueous electrolytes for zinc-ion batteries, including “water-in-salt” electrolytes, eutectic molecular crowding and hydrogel electrolytes.

Language: Английский

Citations

38