An Investigation on Effect of Organic Additives for Stable Performance Vanadium – Cerium Redox Flow Batteries DOI Creative Commons

Viet Dung Trinh,

Chinh Dang Huynh, Hoang Vinh Tran

et al.

ChemElectroChem, Journal Year: 2024, Volume and Issue: 12(3)

Published: Dec. 27, 2024

Abstract In an era where renewable energy resources are pivotal yet plagued by variability, vanadium‐cerium (V‐Ce) redox flow batteries (RFBs) present a sophisticated solution to storage and grid stability. This study focuses into the electrochemical integration of cerium with vanadium enhance traditional batteries′ density cost‐effectiveness. Through innovative design that allows scalability addresses challenges lower inherent in RFBs, V‐Ce RFBs demonstrate potential for more compact efficient systems. this work, we provide open‐source mono cell research. Herein, research spotlights characterization Ce‐based electrolytes, employing mixed acid electrolytes improve solubility. For improving performance including diffusion coefficients electron transfer rates, L–Leucine L–Lysine have been used as organic additives. Obtained results revealed these additives not only influence stability efficiency but also significantly affect charge‐discharge properties which, L‐leucine showing superior over L‐lysine. These findings propose new way optimizing large‐scale regarding efficiency, safety, environmental impact.

Language: Английский

Non-sacrificial additive regulated electrode–electrolyte interface enables long-life, deeply rechargeable aqueous Zn anodes DOI
Ang Li, Xinyu Zhang, Zeyu Xu

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 494, P. 153240 - 153240

Published: June 17, 2024

Language: Английский

Citations

7

Next‐Generation Ultrathin Lightweight Electrode for pH‐Universal Aqueous Flow Batteries DOI
Jiajun Wu, Rui Nie, Lihong Yu

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 23, 2024

Aqueous flow batteries (AFBs) are promising long-duration energy storage system owing to intrinsic safety, inherent scalability, and ultralong cycle life. However, due the thicker (3-5 mm) heavier (300-600 g m

Language: Английский

Citations

7

Coordinated Control of Proton Exchange Membrane Electrolyzers and Alkaline Electrolyzers for a Wind-to-Hydrogen Islanded Microgrid DOI Creative Commons

Zhanfei Li,

Zhenghong Tu, Zhongkai Yi

et al.

Energies, Journal Year: 2024, Volume and Issue: 17(10), P. 2317 - 2317

Published: May 11, 2024

In recent years, the development of hydrogen energy has been widely discussed, particularly in combination with renewable sources, enabling production “green” hydrogen. With significant increase wind power generation, a promising solution for obtaining green is wind-to-hydrogen (W2H) systems. However, high proportion and electrolyzers large-scale W2H system will bring about problem consumption frequency stability reduction. This paper analyzes operational characteristics economic feasibility mainstream electrolyzers, leading to proposal coordinated scheme involving both proton exchange membrane (PEM) electrolyzer an alkaline (ALK) electrolyzer. Subsequently, control based on Model Predictive Control (MPC) proposed regulation islanded microgrid. Finally, simulation results demonstrate that under PEM/ALK not only flexibly accommodates fluctuating but also maintains face large disturbances. Compared traditional all ALK deviation this reduced by 25%, time shortened 80%, demand storage (ESS) reduced. The result validates effectiveness MPC benefits scheme.

Language: Английский

Citations

6

Electrochemical Systems for Renewable Energy Conversion and Storage: Focus on Flow Batteries and Regenerative Fuel Cells DOI

Fengjia Xie,

Xuming Zhang, Zhefei Pan

et al.

Current Opinion in Electrochemistry, Journal Year: 2024, Volume and Issue: unknown, P. 101596 - 101596

Published: Oct. 1, 2024

Language: Английский

Citations

5

Short process for preparing high-purity vanadium electrolyte by efficient selective oxidation of vanadium from multi-impurity shale-hosted leachate via the synergistic effect of H2O2 and NaClO DOI

Hongru Qu,

Yimin Zhang, Hong Liu

et al.

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 131548 - 131548

Published: Jan. 1, 2025

Language: Английский

Citations

0

NiMoS-Modified Carbon Felt Electrode for Improved Efficiency and Stability in a Neutral S/Fe Redox Flow Battery DOI Creative Commons
Dan Mei, Bowen Liu, Haiqing Ma

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(6), P. 1219 - 1219

Published: March 8, 2025

Polysulfide-ferricyanide redox flow batteries (PFRFBs) are gaining significant attention in long-duration energy storage for their abundant availability and environmental benignity. However, the sluggish kinetics of polysulfide reactions have tremendously constrained performances. To address this issue, we developed a NiMoS catalyst-modified carbon felt (NiMoS-CF) electrode, which significantly accelerates electrochemical reaction rates enhances cycling stability PFRFB. Our PFRFB system, integrated with NiMoS-CF exhibited an efficiency 70% voltage 87%, remarkable doubling its cycle life as opposed to pristine (CF) electrode at current density 40 mA cm−2. Notably, during 2500 cycles charge–discharge testing, achieved average coulombic exceeding 99%. These improvements performance can be attributed electrode’s large surface area, low resistance, robust activity. This study offerings novel approach enhancing PFRFBs, laying scientific foundation applications practical PFRFBs next-generation storage.

Language: Английский

Citations

0

Performance evaluation of vanadium redox flow battery based on asymmetric flow rate design DOI
Zebo Huang, Kate Li, Jian Wu

et al.

Electrochimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 146046 - 146046

Published: March 1, 2025

Language: Английский

Citations

0

The Construction of Highly Conductive Framework in Mn3O4@C‐MWCNTs Slurry for Aqueous Zinc‐Based Semi‐Solid Flow Batteries DOI Open Access
Haoxuan Yan,

Bowen Yang,

Chao Chen

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: March 16, 2025

Abstract Aqueous zinc‐based semi‐solid flow batteries (AZSSFBs) are promising large‐scale energy storage devices due to their low cost and superior safety. The formation of a conductive network in the slurry plays an important role capacity active materials stability suspension. Meanwhile, suspension will determine cycle life AZSSFBs. Herein, metal‐organic‐framework‐derived carbon‐coated Mn 3 O 4 @C composites fabricated dispersed aqueous electrolyte construct stable 3D carbon framework by combining multi‐walled nanotubes (MWCNTs). can not only facilitate rapid electron transportation, but also enhance slurry, ensuring conduction for fluidic slurry. Based on @C‐MWCNTs AZSSFBs display enhanced electrochemical performance.

Language: Английский

Citations

0

The design of novel lithium salt additives: 4-benzonitrile-1,3-double (trimethylboric acid) lithium (LBTA) to endow inherent superior stability in high voltage lithium ion batteries DOI
Lucheng Li, Meiling Liu, Peng Yang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162078 - 162078

Published: April 1, 2025

Language: Английский

Citations

0

Microwave and NaCl driven synthesis of P-doped graphitic carbon at atmospheric pressure for long-life vanadium redox flow batteries DOI

Heeyeon An,

Sieun Jeon,

Junseo Park

et al.

Journal of Materials Chemistry A, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Phosphorus-doped graphitic carbon with enhanced performance for VRFBs synthesized via sustainable, scalable microwave and NaCl-driven process.

Language: Английский

Citations

0