Co single-atom catalyst on ordered macro–microporous structure as separator for Li-S battery

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 684, P. 189 - 196

Published: Jan. 11, 2025

Language: Английский

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Black phosphorous nanosheets@CNTs hybrid composite for boosting conversion of polysulfides in lithium sulfur batteries

Electrochimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 145762 - 145762

Published: Jan. 1, 2025

Language: Английский

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Zwitterionic covalent organic framework as a multifunctional separators for high performance lithium-sulfur batteries

Journal of Power Sources, Journal Year: 2025, Volume and Issue: 632, P. 236325 - 236325

Published: Jan. 27, 2025

Language: Английский

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Enhancing Li-S Battery Performance by Harnessing the Power of Single Atoms on 2D Borophene

Electrochimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 145831 - 145831

Published: Feb. 1, 2025

Language: Английский

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Enhancing Li-S Battery Performance by Harnessing the Power of Single Atoms on 2d Borophene

Published: Jan. 1, 2025

Li-S batteries are potentially interesting alternatives for green energy applications due to their high density and low cost. Nonetheless, present practical application falls short of theoretical predictions, despite efforts address volumetric expansion enhance electrical conductance through porous sulfur-hosting scaffolds. The performance is mainly restricted by the poor electrochemical reaction kinetics lithium polysulfides (LiPS), which convert into sulfide (Li2S) elemental sulfur (S) during charge-discharge cycles. Single-atom catalysts (SACs) offer novel opportunities addressing complex challenges effective in atomic-resolution characterization intermediates as well precise atomic-level engineering. Inspired single-atom catalysis approach, we designed an innovative electrocatalyst including FeN4 active sites anchored 2D borophene nanosheets. significant electronic coupling between Fe 3d S 2p orbitals promotes charge transfer improves redox dynamics polysulfide intermediates. Moreover, unique properties borophene, its mass density, superior conductivity, rapid Li-ion transport, robust binding with polysulfides, render it a promising choice battery materials. synergistic effect adsorption improved kinetics, enabled configuration three-dimensional architecture FeN4/borophene (Fe@BNS), results outstanding batteries. fabricated cells exhibit exceptional long-term cycle life (1180 mAh g−1 at 1 C 1000 cycles) high-rate (790.3 C) loading 6.5 mg cm−2.

Language: Английский

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Polyvinylimidazolium/polyacrylonitrile nanofiber separator with enhanced polysulfide adsorption toward durable lithium–sulfur batteries

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159329 - 159329

Published: Jan. 1, 2025

Language: Английский

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Mxene/Zif-67-Based Janus Separator for High-Performance Lithium-Sulphur Batteries

Published: Jan. 1, 2025

Language: Английский

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Recent Advances in In Situ Characterization of the Electrochemical Processes at the Alloy Anode-Electrolyte Interfaces

Langmuir, Journal Year: 2025, Volume and Issue: unknown

Published: March 6, 2025

Lithium-metal batteries (LMBs) have garnered widespread attention due to their high energy density. Alloy anodes are particularly notable for exceptional specific capacity used in LMBs. However, alloy encounter significant challenges interfacial issues, which include sluggish reaction kinetics and mechanical failures induced by force-electric coupling at the interface. In situ characterization of interface evolution is crucial gain a deeper understanding fundamental origins these issues. This review systematically examines associated with highlights role techniques elucidating kinetics, mechanisms, dendrite formation anode-electrolyte The future development this field proposed outlook.

Language: Английский

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Single Atomic Co Decorated Mesoporous Carbon/MXene Heterostructure as Redox Promoters for High-Stable Li-S Battery

Carbon, Journal Year: 2025, Volume and Issue: unknown, P. 120229 - 120229

Published: March 1, 2025

Language: Английский

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Hollow Multishelled High Entropy Oxide with Inert Aluminum Stabilizer for Boosted Electrochemical Lithium Storage

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 16, 2025

Abstract High entropy oxides (HEOs) have gained increasing attention as lithium‐ion battery anodes, owing to their multi‐principal synergistic effect and structural stability. However, the conversion type HEOs also suffer from low intrinsic conductivity, volume expansion, slow kinetics traditional metal oxide. Herein, a (FeCoNiCrMn) 2 O 3 HEO with hollow multishelled structure Al‐doping (Al‐HEO‐HoMS) is successfully prepared by thermal diffusion‐assisted template method. The effectively accommodates changes mitigates strains, resulting in excellent electrochemical Most importantly, inserted Al dopant Al‐HEO‐HoMS serves pegging points, securely fastening other metallic elements Al─O bonds maintain stability of anodes during repeated lithiation/delithiation. Additionally, abundant oxygen vacancies optimized electronic brought doping been validated accelerate lithiation kinetics. Consequently, anode exhibits high reversible capacity 1540 mAh g −1 after 500 cycles at 1 A . combination inert regulation expected alleviate expansion problem, offering universal strategy for designing advanced batteries.

Language: Английский

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