The Out‐of‐Plane C─S Bonds Boosting Reversible Redox in Copper Sulfide Cathodes for Ultradurable Magnesium Battery DOI Open Access
Qin Su, Weixiao Wang, Jiajun Chen

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 21, 2024

Abstract As a typical conversion‐type cathode material, CuS has shown great potential in the field of rechargeable magnesium batteries (RMBs) due to its excellent energy density, stable voltage platforms, and low cost. However, poor phase conversion reversibility cathodes resulted Coulombic efficiency short cycling life, impeding further development. Herein, an abundance CS heterointerfaces is meticulously crafted by nanoparticles anchored on rGO nanosheets (CuS@G). The out‐of‐plane C─S bonds effectively reduce activation sulfur atoms within Cu‐S tetrahedrons, facilitating formation S─S Cu₂S crystal structure driving reversible between during charge/discharge process. Furthermore, more could diminish copper ion dissolution induced volume expansion. Consequently, CuS@G exhibits one most remarkable rate performances date (160.5 mAh g −1 at 1 A ), retaining 64.7% capacity after 1000 cycles. Additionally, durable CuS@G||Mg pouch cell successfully assembled, delivering high 9.5 mAh. These fundamental insights provide valuable guidance for design high‐performance materials next‐generation RMBs.

Language: Английский

The Role of Ion-Polaron Electrostatic Attraction on Zn2+ Migration in α-V2O5 for Zinc Ion Battery: Insights from First-Principles Calculations DOI

Yiming Guo,

Dan Wu, Zhuo Sun

et al.

The Journal of Physical Chemistry Letters, Journal Year: 2025, Volume and Issue: 16(6), P. 1415 - 1423

Published: Jan. 30, 2025

The migration of Zn2+ ions is significantly more challenging compared to that Li+ within the same crystalline framework, leading poor rate performance zinc-ion batteries (ZIBs). Compared Li+, slower vaguely attributed stronger electrostatic interaction induced by Zn2+. Herein, rule how size channel and affect in α-V2O5 has been systematically investigated first-principle calculations. It found expanding layer spacing can facilitate migration. Once surpasses a certain threshold, further expansion does not lead continued reduction barrier. local structure distortions caused electron small polarons would decrease size, which should have increased energy barrier for However, interestingly, barriers, be ion-polaron attraction. higher activation barriers those rationalized specific attraction Moreover, comparative strength polaron-ion alkali alkaline earth metal unveiled. Overall, this study provides theoretical insights into role on ion

Language: Английский

Citations

1
Kinetics-Boosted and Dissolution-Suppressed Molybdenum-Doped vanadium dioxide for Long-Life Zinc-Ion batteries DOI
Dongdong Zhang, Yilei Yue,

Chengwu Yang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160160 - 160160

Published: Feb. 1, 2025

Language: Английский

Citations

1
A high-entropy zero-strain V-based cathode for high performance aqueous zinc-ion batteries DOI
Xiang Ding, Jiabo Le,

Yibing Yang

et al.

Energy storage materials, Journal Year: 2025, Volume and Issue: 76, P. 104098 - 104098

Published: Feb. 7, 2025

Language: Английский

Citations

1
Biopolymer‐Based Gel Electrolytes for Advanced Zinc Ion Batteries: Progress and Perspectives DOI

Renjie Jia,

Chuanliang Wei, Benhua Ma

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 1, 2024

Abstract In recent years, aqueous zinc ion batteries (ZIBs) with ultra‐high safety and environmental friendliness have emerged as a promising candidates for energy storage conversion devices. However, the severe side reactions dendrites issues discourage practical application of ZIBs. Recently, biopolymer‐based gel electrolytes disclosed large potential in tackling these challenges ZIBs, numerous advancements reported. Their advantages lie suppressing including hydrogen evolution Zn metal anode corrosion, well inhibiting growth dendrites. This review comprehensively examines classification, structures properties electrolytes, focus on hydrogel derived from various natural macromolecular biopolymers, along brief discussion non‐hydrogel using ionic liquids or organic solutions solvents. Subsequently, preparation physical chemical methods are summarized. Furthermore, applications ZIBs diverse cathodes materials introduced. Finally, it highlights benefits excellent electrochemical performance outlining their prospects next generation proposing future perspectives.

Language: Английский

Citations

7
Unveiling Electrochemically Induced Phase Transition of Hierarchical ZnV2O4@C Superstructures Toward Advanced Aqueous Zinc Ion Batteries DOI Open Access

Shujia Zhang,

Xiaolong Jia, Fulu Chu

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: March 21, 2025

Aqueous zinc ion batteries (AZIBs) are promising candidates for large-scale energy storage systems due to their high safety and low cost. Among diverse cathodes, spinel ZnV2O4 (ZVO) becomes more prominent thanks its capacity long cycling life. However, the slow diffusion kinetics, vanadium dissolution, ambiguous zinc-storage mechanism restrict prospective applications. For this, herein, unique ZVO flower-shaped nano/micro-architectures with carbon coating (ZVO@C) designed enhance active electrode-electrolyte sur-/interfaces reduce distance, while nano-carbon shell improves electrical conductivity of cathodes inhibits dissolution. Furthermore, essential ZVO@C is first clarified that irreversible electrochemically-induced phase formation ZnV3O8 Zn3(OH)2V2O7·2H2O during cycle, rather than itself, which genuine electroactive phases following storage. Theoretical calculations reveal two newly-formed intrinsically endowed good boosted kinetics reversible co-(de)intercalation Zn2+ H+. The optimized shows superior stability 208.7 mAh g-1 after 5000 cycles even at 10 A g-1. Essentially, contribution provides in-depth insights intriguing transition involved promotes commercial applications vanadium-based long-lifespan AZIBs.

Language: Английский

Citations

0
Modulating the interlayer H+ migration in MnO2 via W and K co-doping engineering to high-capacity aqueous zinc-ion batteries DOI

Guodong Miao,

Zhen Wang, Feng Sun

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 693, P. 137636 - 137636

Published: April 17, 2025

Language: Английский

Citations

0
Towards ultra-stable aqueous zinc-ion batteries via electrochemical polymerization of phthalimido-anchored benzoquinone DOI
Dan Wang, Yuxuan Bai,

ZIQING zhou

et al.

Green Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Phthalimido anchored benzoquinone is selected as monomer for electropolymerization to fabricate the cathode of aqueous ZIBs with ultralong cycling stability.

Language: Английский

Citations

0
Construction of high-performance aqueous zinc-ion batteries by guest pre-intercalation MnO2-based cathodes DOI
Lulu Zhao, Junwei Yin,

Bingchen Liu

et al.

Advances in Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 103499 - 103499

Published: March 1, 2025

Language: Английский

Citations

0
The optimal integrating state of VOx with the synergistic effect of Cu2+ cation and polyaniline for high performance flexible fiber zinc-ion battery DOI
Juan Xu,

Nengneng Han,

Sihao Chen

et al.

Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 120, P. 116415 - 116415

Published: April 4, 2025

Language: Английский

Citations

0
Industrial Scalability of Zinc‐Ion Batteries: Enhanced Electrochemical Performance with High Mass Loading Electrodes on Graphene‐Coated Metal Current Collectors DOI

Heeyeon Heo,

Jaeyeon Lee, Yong‐Ryun Jo

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 2, 2025

Abstract Zinc‐ion batteries (ZIBs) have emerged as a promising energy storage solution due to their inherent safety, environmental sustainability, and cost‐effectiveness. Utilizing water‐based electrolytes, ZIBs eliminate fire risks thermal runaway concerns, making them ideal for large‐scale systems. The high theoretical capacity, low cost, abundance, toxicity of zinc further enhance its suitability grid‐scale applications. However, conventional current collectors such graphite foil exhibit limitations in scalability mechanical properties, which make unsuitable industrial roll‐to‐roll manufacturing processes. This study addresses these by exploring graphene‐coated stainless steel an alternative collector. Here, graphene coating followed heat treatment remove the surface oxides improves conductivity corrosion resistance material. As result, fabricated ZIB exhibits specific capacities 1.90 0.91 mAh cm −2 at densities 0.3 2.0 C, respectively, demonstrate remarkable long cycle life with capacity retention 88.7% up 1500 cycles density 1.0 despite electrode loading 13.27 mg . innovation enhances electrochemical performance cycling stability, thereby advancing safe, scalable, high‐performance solution.

Language: Английский

Citations

0