Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 19, 2024
Abstract The development and application of solid‐state electrolytes (SSEs) play a crucial role in advancing lithium metal batteries (LMBs). Consequently, the search for high‐performance, economic, easily fabricated SSEs has become prevailing trend. In this work, we explore an alternative approach to design traditional commercial lithium‐ion cathode material, spinel‐type LiMn 2 O 4 (LMO) as SSE. By blending LMO with poly(vinylidene difluoride) combining two layers polyethylene (PE) film on top bottom, effectively reduce its high electronic conductivity, thereby creating PE/LMO/PE SSE demonstrates ionic conductivity (3.15 × 10 −4 S cm −1 at 35°C), low (7.31 −11 ), good interfacial contact stability both anode, LiFePO nickel‐rich Li[Ni 0.8 Co 0.1 Mn ]O cathodes. This study offers new direction electrochemically active material LMO, while providing simple feasible solution SSEs. Additionally, it opens up perspectives selecting high‐performance use LMBs, paving economic path toward commercialization batteries.
Language: Английский