Chemical Communications,
Journal Year:
2024,
Volume and Issue:
60(33), P. 4395 - 4418
Published: Jan. 1, 2024
This
review
summarizes
in
detail
the
state-of-the-art
research
on
design,
synthesis,
regulation,
and
persulfate-based
advanced
oxidation
process
application
of
MOF-derived
porous
nano-
macromaterials.
Water Environment Research,
Journal Year:
2025,
Volume and Issue:
97(5)
Published: April 28, 2025
Abstract
The
widespread
use
of
tetracycline
has
made
the
efficient
and
environmentally
friendly
treatment
tetracycline‐contaminated
wastewater
a
pressing
issue
in
environmental
management.
This
study
synthesized
high‐purity
uniformly
mixed
Cu
0
/CuFeO
2
composite
materials
using
one‐step
hydrothermal
method,
aiming
to
enhance
catalytic
activation
peroxymonosulfate
(PMS)
through
synergistic
effect
zero‐valent
metal
bimetallic
compounds.
demonstrated
exceptional
PMS
performance,
achieving
84%
hydrochloride
(TCH)
degradation
within
1
min
91%
20
min.
process
involved
action
•OH,
SO
4
•−
,
O
electron
transfer.
intermediates
TCH
were
identified
high‐performance
liquid
chromatography–mass
spectrometry
(HPLC‐MS),
four
potential
pathways
proposed.
Furthermore,
exhibited
robust
performance
across
wide
pH
range
maintained
high
efficiency
complex
aqueous
environments.
Even
after
five
cycles,
retained
78%
its
efficiency,
demonstrating
excellent
stability
reproducibility
/PMS
system.
Practitioner
Points
A
was
synthesized.
Robust
activity
observed
for
catalyst.
Synergistic
contributions
from
e
−
resulted
degradation.
Four
derived.
