Dual-Template Molecularly Imprinted Polymers for Dispersive Solid-Phase Extraction Combined with High Performance Liquid Chromatography for the Determination of Sulfonamide Antibiotics in Environmental Water Samples DOI Open Access
Yuhao Wen,

Mingyang Hou,

Xingkai Hao

et al.

Polymers, Journal Year: 2024, Volume and Issue: 16(21), P. 3095 - 3095

Published: Nov. 1, 2024

In this study, we designed a molecularly imprinted polymers-dispersive solid-phase extraction-high-performance liquid chromatography (MIPs-DSPE-HPLC) method, as simple and efficient platform for the sensitive detection of two sulfonamide antibiotics (SAs) sulfamethoxine (SMM) sulfamethoxazole (SMZ) in environmental water samples. Using SMM SMZ templates, methacrylic acid functional monomer, ethylene glycol dimethacrylate crosslinking agent, azodiisobutyronitrile catalyst, dual-template polymers (dt-MIPs) were successfully synthesized via surface imprinting technology multi-template strategy. The adsorption properties prepared MIPs characterized, capacities towards 27.35 mg/g 30.92 mg/g, respectively. limits method three samples range 0.23–1.74 μg/L, recoveries between 82.7 110.3%, with relative standard deviations less than 5.93%. construction process MIPs-DSPE-HPLC is straightforward, exhibits high sensitivity selectivity, thus provides versatile quantification SAs complex matrices.

Language: Английский

The metal- and covalent-organic frameworks-based molecularly imprinted polymer composites for sample pretreatment DOI
Yuhao Wen,

Dani Sun,

Jinhua Li

et al.

TrAC Trends in Analytical Chemistry, Journal Year: 2024, Volume and Issue: 178, P. 117830 - 117830

Published: June 24, 2024

Language: Английский

Citations

15
Solid-phase extraction coupled with high performance liquid chromatography-triple quadrupole mass spectrometry for simultaneous determination of seven coumarins in water samples from drinking water treatment plants DOI

Wenmei Jiao,

Jingming Yang, Ce Xu

et al.

Chinese Journal of Chromatography, Journal Year: 2025, Volume and Issue: 43(1), P. 78 - 86

Published: Jan. 1, 2025

Chlorinated coumarins, which are as cytotoxic highly toxic halobenzoquinones toward CHO-K1 cells, have recently been identified disinfection byproducts in drinking water processes. Therefore, detecting coumarins samples collected at various stages from treatment plants helps assess the formation of chlorinated water. Hence, a simple, rapid, accurate, and sensitive method for quantifying is required. In this study, was developed based on solid-phase extraction coupled with high performance liquid chromatography-triple-quadrupole mass spectrometry analyzing seven plants, including 6,7-dihydroxycoumarin, 7-hydroxycoumarin, 6-hydroxy-4-methylcoumarin, 8-chloro-7-hydroxycoumarin, coumarin, 7-chloro-6-hydroxy-4-methylcoumarin, 3,8-dichloro-7-hydroxycoumarin. Sample pretreatment involved using HLB columns, followed by elution methanol, each containing 0.25% formic acid. The extracted solution separated via gradient Phenomenex Luna C18 column (100 mm×2.0 mm, 3 mm) 0.1% acid aqueous methanol mobile phases, analytes detected triple-quadrupole equipped electrospray ionization source multiple reaction monitoring mode. matrix effect, precision, accuracy were investigated raw treated matrices. Matrix effects 0.84-1.12 recorded detection coumarin water, while values 0.67-0.70 3,8-dichloro-7-hydroxycoumarin finished three exhibited above 0.80 after had diluted four times. These results suggest that only simple or sample dilution required to accurately determine plants. addition, these good linear relationships their respective concentrations. precision evaluated linearities certain range, correlation coefficients (r) greater than 0.99 limits (MDLs) 0.67-1.12 ng/L. recoveries 61.4%-91.5% spiked levels (20, 50, 100 ng/L) relative standard deviations (RSDs, n=6)≤11.2%. can be used analyze drinking-water plant. 7-Hydroxycoumarin, 0.21-27.9 ng/L 100% samples, 6-hydroxy-4-methylcoumarin not post-coagulated post-carbon-filtered but found sand-filtered higher latter (4.69 former (1.79 ng/L). 8-Chloro-7-hydroxycoumarin (0.07 This precise provides short analysis times, effectively monitor real removal during treatment.

Language: Английский

Citations

0
A dummy template molecularly imprinted polymer-coated fiber array extraction for simultaneous HPLC analysis of eight biogenic amines in fermented horse milk DOI

Adila Muhtar,

Pengli Jian,

Turghun Muhammad

et al.

Analytica Chimica Acta, Journal Year: 2025, Volume and Issue: 1352, P. 343901 - 343901

Published: March 6, 2025

Language: Английский

Citations

0
Recent advances in synthesis and applications of hyper-crosslinked porous organic polymers for sample pretreatment: A review DOI
Ashraf Ali,

Tongtong Qin,

Wenfen Zhang

et al.

Analytica Chimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 343934 - 343934

Published: March 1, 2025

Language: Английский

Citations

0
Advanced Photocatalytic Treatment of Aqueous Disinfection By-products with Sodium Alginate Hydrogel-Encapsulated Titanium dioxide and Luminous Powder; A synergistic mechanism DOI

Pengfei Zhang,

Umuhoza Claudine,

Saleem Raza

et al.

Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 116317 - 116317

Published: March 1, 2025

Language: Английский

Citations

0
A label-free electrochemical aptasensor combined Au/Ag@ZIF-8 and dual amplification strategy for sensitive detection of β-lactoglobulin DOI
Tao Lü, Zhiguang Suo, Min Wei

et al.

Food Bioscience, Journal Year: 2025, Volume and Issue: unknown, P. 106118 - 106118

Published: Feb. 1, 2025

Language: Английский

Citations

0
Epitope-imprinted biomaterials with tailor-made molecular targeting for biomedical applications DOI

Youlu Diao,

Jia Gao,

Yue Ma

et al.

Bioactive Materials, Journal Year: 2024, Volume and Issue: 45, P. 162 - 180

Published: Nov. 21, 2024

Language: Английский

Citations

3
Chameleon-inspired molecular imprinted polymer with bicolored states for visual and stable detection of diethylstilbestrol in water and food samples DOI

Dongmei Li,

Jiayue Zhou,

Zhuxin Chang

et al.

Food Chemistry, Journal Year: 2024, Volume and Issue: 469, P. 142531 - 142531

Published: Dec. 18, 2024

Language: Английский

Citations

0
Dual-Template Molecularly Imprinted Polymers for Dispersive Solid-Phase Extraction Combined with High Performance Liquid Chromatography for the Determination of Sulfonamide Antibiotics in Environmental Water Samples DOI Open Access
Yuhao Wen,

Mingyang Hou,

Xingkai Hao

et al.

Polymers, Journal Year: 2024, Volume and Issue: 16(21), P. 3095 - 3095

Published: Nov. 1, 2024

In this study, we designed a molecularly imprinted polymers-dispersive solid-phase extraction-high-performance liquid chromatography (MIPs-DSPE-HPLC) method, as simple and efficient platform for the sensitive detection of two sulfonamide antibiotics (SAs) sulfamethoxine (SMM) sulfamethoxazole (SMZ) in environmental water samples. Using SMM SMZ templates, methacrylic acid functional monomer, ethylene glycol dimethacrylate crosslinking agent, azodiisobutyronitrile catalyst, dual-template polymers (dt-MIPs) were successfully synthesized via surface imprinting technology multi-template strategy. The adsorption properties prepared MIPs characterized, capacities towards 27.35 mg/g 30.92 mg/g, respectively. limits method three samples range 0.23–1.74 μg/L, recoveries between 82.7 110.3%, with relative standard deviations less than 5.93%. construction process MIPs-DSPE-HPLC is straightforward, exhibits high sensitivity selectivity, thus provides versatile quantification SAs complex matrices.

Language: Английский

Citations

0