Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 503, P. 158274 - 158274
Published: Dec. 5, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 503, P. 158274 - 158274
Published: Dec. 5, 2024
Language: Английский
Frontiers of Chemical Science and Engineering, Journal Year: 2025, Volume and Issue: 19(4)
Published: March 3, 2025
Language: Английский
Citations
0Advanced Sustainable Systems, Journal Year: 2025, Volume and Issue: unknown
Published: April 1, 2025
Abstract The development of technologies for replacing formaldehyde‐based adhesives and disposing sewage sludge (SS) are two standing issues high interest to the academy industry. This study reports production formaldehyde‐free wood bio‐adhesive using hydrochar from hydrothermal carbonization SS aided by sodium periodate (NaIO4) oxidation. performance bio‐adhesives can meet requirements Chinese National Standard GB/T 9846‐2015 (≥0.7 MPa). aldehyde group forms after NaIO4 treatment hydrochar, which should benefit adhesion performance. However, oxidation process also breaks some polysaccharides' carbon chains, disrupting extracellular polymeric substances (EPS) structure in forming small molecular compounds. As a result, wet shear strength value decreases, but water resistance increases. Nevertheless, interaction between active functional groups (e.g., amine groups) during hot‐pressing promotes In addition, doping polyethyleneimine, cross‐linked network be further enhanced, improving resistance. Hence, introducing is key step bio‐adhesives, proving as novel practical approach valorize producing adhesives.
Language: Английский
Citations
0Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(3), P. 112701 - 112701
Published: April 5, 2024
Language: Английский
Citations
3Environmental Research, Journal Year: 2024, Volume and Issue: 259, P. 119576 - 119576
Published: July 10, 2024
Language: Английский
Citations
3Biofuels Bioproducts and Biorefining, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 17, 2024
Abstract This study reports the use of deep‐eutectic‐solvent‐ (DES‐) assisted hydrothermal carbonization (HTC) to disrupt floc structure sewage sludge (SS) for deep carbonization, with resulting hydrochars employed in preparation formaldehyde‐free plywood bioadhesives. Sewage‐sludge‐based bioadhesive exhibits an excellent wet shear strength, complying requirements Chinese national standard GB/T 9846–2015 (≥0.7 MPa). The molecular weight proteins and formation covalent bonds via dehydration have a notable role improving adhesive performance (wet strength). Maillard reaction is key during HTC destroy secondary proteins, release more OH NH 2 . main hot‐press treatment dehydration. High ash content bioadhesives improves flame resistance potential, particularly on addition DES. A plausible mechanism proposed this. work provides new method valorization SS‐derived contributes development greener wood
Language: Английский
Citations
3Frontiers in Microbiology, Journal Year: 2024, Volume and Issue: 15
Published: Feb. 26, 2024
Currently, there is a growing interest in transforming wastewater treatment plants (WWTPs) into resource recovery plants. Microorganisms aerobic granular sludge produce extracellular polymeric substances (EPS), which are considered sustainable resources to be extracted and can used diverse applications. Exploring applications other high-value materials, such as adhesives, will not only enhance the valorization potential of EPS but also promote recovery. This study aimed characterize water-soluble fraction from collected at demonstration plant Netherlands based on its chemical composition (amino acids, sugar, fatty acids) propose proof-of-concept for use an adhesive. comprises mixture biomolecules, proteins (26.6 ± 0.3%), sugars (21.8 0.2%), acids (0.9%). The exhibited shear strength reaching 36–51 kPa across pH range 2–10 without additional treatment, suggesting application findings this provide insights concept excess WWTPs.
Language: Английский
Citations
2Current Opinion in Biotechnology, Journal Year: 2024, Volume and Issue: 89, P. 103192 - 103192
Published: Aug. 30, 2024
Biofilms play important roles in water technologies such as membrane treatments and activated sludge. The extracellular polymeric substances (EPS) are key components of biofilms. However, the precise nature these how they influence biofilm formation behavior remain critical knowledge gaps. EPS produced by many different microorganisms span multiple biopolymer classes, which each require distinct strategies for characterization. biopolymers additionally associate with other to form insoluble complexes. Here, we explore recent progress toward resolving structures functions EPS, where a shift towards direct functional assessments advanced characterization techniques is necessary. This will enable integration better microbial community omics analyses understand biosynthesis pathways create further opportunities control valorization.
Language: Английский
Citations
2Journal of Hazardous Materials, Journal Year: 2024, Volume and Issue: 476, P. 134973 - 134973
Published: June 19, 2024
Language: Английский
Citations
0Water, Journal Year: 2024, Volume and Issue: 16(22), P. 3235 - 3235
Published: Nov. 11, 2024
This work evaluated the alterations in levels and types of polycyclic aromatic hydrocarbons (PAHs) within both liquid solid products throughout process catalytic supercritical water gasification dewatered sewage sludge to examine effect various catalysts inhibit reaction pathways. The addition Ni, NaOH, Na2CO3, H2O2, KMnO4 reduced concentrations PAHs, with Ni H2O2 showing best performance. especially higher-molecular-weight compounds residues, decreased sharply as amount increased. At a 10 wt% addition, PAHs were by 91% 88%, respectively. High-ring not detected residues increased an 8 wt%. evidently inhibits PAH formation promoting ring-opening reactions initial raw inhibiting polymerization open-chain intermediate products. NaOH + or combined significantly lowered while increasing H2 yield. 5 70% 44%, respectively, yield escalated from 0.13 mol/kg OM 3.88 OM. Possible mechanisms associated pathways these are proposed.
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 503, P. 158274 - 158274
Published: Dec. 5, 2024
Language: Английский
Citations
0