Treatability of diclofenac and triclosan solutions by catalytic and photocatalytic oxidation processes DOI
Eylem Topkaya, Ayla Arslan

Journal of Chemical Technology & Biotechnology, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 29, 2024

Abstract BACKGROUND In recent years, advanced oxidation processes (AOP) have gained importance as highly effective methods in the treatment of organic substances with toxic and permanent properties. Diclofenac (DCF) Triclosan (TCS) pollutants, which are from endocrine disrupting chemicals (EDCs) that were encountered various aquatic environments such inlet outlet waters plants, surface waters, drinking water, groundwater sediments reported literature. this study, mineralisation DCF TCS EDCs, investigated by AOPs. The applied O 3 , /UV, /ZnO, UV/ZnO, /UV/ZnO. studies carried out at two different initial concentrations (5 10 mg/L), 5 ppm ozone dose, 2 × 8 W UVC light, 0.1 g ZnO, original pH, 30 min reaction time. RESULTS highest COD TOC removal efficiencies determined /UV/ZnO process 82% COD, 71% mg/L concentration for pollutant 72% 75% pollutant. For these conditions, consumptions 0.13 mgO /mgCOD removed 0.31 /mgTOC 0.69 0.98 respectively. electrical energy per order values found range 12.33–20.88 kWh/m processes. Treatment costs calculated 0.002 to 44.823 €/m . CONCLUSION treatability ozone‐based processes, especially photocatalytic a feasible process. © 2024 Society Chemical Industry (SCI).

Language: Английский

Kinetic modeling and optimization of triclosan adsorption onto coconut shell activated carbon DOI Creative Commons

Liane Carmen Ruszczyk,

Gabriel André Tochetto, Adriana Dervanoski

et al.

Journal of Hazardous Materials Letters, Journal Year: 2024, Volume and Issue: unknown, P. 100131 - 100131

Published: Oct. 1, 2024

Language: Английский

Citations

4

Emerging antibiotic pollution and its remedy by waste based biochar adsorbents: a review DOI

Injila Hamid,

Mohsen Ahmadipour, Muthanna J. Ahmed

et al.

Environmental Science and Pollution Research, Journal Year: 2025, Volume and Issue: unknown

Published: March 14, 2025

Language: Английский

Citations

0

Expression of nanobodies in Arabidopsis thaliana strengthens the absorption capacity of triclosan from growth media DOI

Weixia Liu,

Mengya Li, Xiangyu Zhang

et al.

Physiologia Plantarum, Journal Year: 2025, Volume and Issue: 177(2)

Published: March 1, 2025

Triclosan (TCS) is a broad-spectrum antimicrobial disinfectant widely used in pharmaceuticals and personal care products (PPCPs). Due to the extensive usage of PPCPs, TCS inevitably entered environment pose harmful effects on ecosystem. Phytoremediation an attractive approach remove from environment. In this study, gene encoding anti-TCS nanobody was transformed into Arabidopsis thaliana (A. thaliana) enhance absorption capacity TCS. Nanobodies are small antibody fragments (ca. 15 kDa) derived variable domain camelid heavy-chain-only antibodies. We constructed two transgenic lines, T-S-C line with expression throughout plant T-S-P dominant roots, were constructed. The nanobodies A. alleviated phytotoxicity exhibited significantly stronger tolerance toxicity than wild type (WT), either solid medium system or hydroponics system. Under stress TCS, seedlings both plants increase root length fresh weight compared those WT. Moreover, presence activities superoxide dismutase, peroxidase, catalase, glutathione higher concentration absorbed increased by 50.0% 24.1%, 55.6% 38.0%, respectively, This study provides proof principle that transforming represents novel technology improve efficiency phytoremediation for environmental pollutants.

Language: Английский

Citations

0

Triclosan removal from synthetic solution using corn cobs and their magnetic composites: Insights from batch adsorption and fixed-bed column studies DOI Creative Commons
Cristina E. Almeida‐Naranjo, Fabián Santana-Romo,

Elvia Gallegos-Castro

et al.

Industrial Crops and Products, Journal Year: 2025, Volume and Issue: 228, P. 120917 - 120917

Published: March 31, 2025

Language: Английский

Citations

0

Evaluation of the Pathway of Contaminants in the Environment: A Case Study of Different Aquatic Environmental Compartments DOI Open Access
Jonathan C. Espíndola, Nazareno Scaccia, Inalmar D. Barbosa Segundo

et al.

Sustainability, Journal Year: 2024, Volume and Issue: 16(10), P. 3927 - 3927

Published: May 8, 2024

The occurrence of contaminants emerging concern (CECs) in several environmental compartments has raised significant given the extensive array compounds and their consistent detection across various matrices. Monitoring all potentially harmful identifying sources is nearly impossible. However, providing data on crucial lays groundwork for decision makers to craft mitigation strategies toward a more sustainable water policy. Hence, primary aim this study was conduct an evaluation CECs environment. main novelty relies understanding specific pathway three different aquatic compartments. For that, combined systematic review systemic analysis performed. Initially, five most common types found ecosystems (groundwater surface water) wastewater were considered. each group CECs, identified. A bibliographic portfolio generated through application review. Finally, conducted. All classes studied identified evaluated. Except pesticides, degree contamination by followed sequence based compartment (i.e., WW–SW–GW).

Language: Английский

Citations

3

Synthesis, mechanism and environmental applications of g-C3N4 composites: A synergistic approach to adsorption and photocatalysis DOI

Ibrahim Khan,

Yangshuo Sun,

Fawad Khan

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 359, P. 130472 - 130472

Published: Nov. 26, 2024

Language: Английский

Citations

3

Triclosan Adsorption on Chitosan: Computational Study of Molecular Interactions and Potential for Environmental Remediation DOI Open Access
Cleidiane Cardoso Teixeira, Anna Karla dos Santos Pereira, Grasiele Soares Cavallini

et al.

Polymers, Journal Year: 2025, Volume and Issue: 17(4), P. 487 - 487

Published: Feb. 13, 2025

The compound triclosan (TCS) is widely found in personal hygiene products, and when present effluents, it can cause problems to human health, such as endocrine disruption, intestinal problems, liver tumors. A sustainable alternative for the removal of TCS use adsorbent biopolymers, which are low-cost, renewable, biodegradable. One most used biopolymers chitosan (CHT), has excellent adsorptive properties due its functional groups. In this context, work evaluated, through computational simulations, interaction molecule with CHT. frontier molecular orbitals electrostatic potential show that different forms interactions occur, thus, five complexes were shown be stable after optimization interactions. bond lengths ranged from 1.839 Å 3.606 formed mainly by hydrogen bonds H...Cl binding energy (∆EBind) allowed us infer adsorption occurred, ∆EBind < 0, values -4.14 kcal mol-1 -17.74 mol-1. thermodynamic demonstrated process was exothermic two spontaneous: TCS...CHTiii ΔG= -3.14 TCS...CHTiv -2.82 topological parameters revealed almost all between CHT electrostatic, non-covalent analysis confirmed presence van der Waals complexes. Thus, study showed efficient treatment effluents containing emerging contaminant triclosan.

Language: Английский

Citations

0

Comparative Kinetic Analysis of Triclosan Degradation under UV-C and Simulated Solar Irradiation DOI Creative Commons
Lázaro Adrián González-Fernández, Myriam Chems, Nahúm Andrés Medellín-Castillo

et al.

Separations, Journal Year: 2024, Volume and Issue: 11(5), P. 131 - 131

Published: April 25, 2024

This research delves deeply into the intricate degradation kinetics of triclosan, employing two distinct methodologies: UV and simulated solar irradiation. Through a comprehensive comparative analysis, study endeavors to elucidate efficacy these techniques, aiming shed light on their respective methodological strengths limitations. The compares irradiation techniques for triclosan degradation, revealing that both methods exhibit effectiveness in degrading with variations observed rates byproduct formation. detailed examination reveals pathways mechanisms involved photodegradation process. Results highlight influence irradiance levels residence times efficiency. identifies optimal conditions emphasizing importance time levels. show 4 h an level 450 W m−2 maximize Analysis byproducts provides insights transformation under irradiation, indicating formation 2,4-dichlorophenol, quinone, hydroquinone as primary byproducts.

Language: Английский

Citations

2

Tradeoffs between hygiene behaviors and triclosan loads from rivers to coastal seas in the post COVID-19 era DOI
Xian Sun, Yongwei Guo,

Dingyu Luo

et al.

Marine Pollution Bulletin, Journal Year: 2024, Volume and Issue: 203, P. 116507 - 116507

Published: May 23, 2024

Language: Английский

Citations

2

Cyanuric chloride as a linker towards the synthesis of covalent triazine polymers: a review DOI Creative Commons

Silpa Elizabeth Peter,

Paul G. Thomas, P. Vairavel

et al.

Materials Advances, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Covalent triazine polymers, comprised of aromatic electron-deficient 1,3,5-triazine units, exhibit distinctive structural properties, rendering them an emerging porous material across diverse applications.

Language: Английский

Citations

2