Journal of Water Process Engineering, Journal Year: 2024, Volume and Issue: 68, P. 106329 - 106329
Published: Oct. 28, 2024
Language: Английский
Journal of Water Process Engineering, Journal Year: 2024, Volume and Issue: 68, P. 106329 - 106329
Published: Oct. 28, 2024
Language: Английский
Journal of Water Process Engineering, Journal Year: 2025, Volume and Issue: 72, P. 107432 - 107432
Published: March 10, 2025
Language: Английский
Citations
1Environmental Research, Journal Year: 2025, Volume and Issue: unknown, P. 120808 - 120808
Published: Feb. 1, 2025
Language: Английский
Citations
0Journal of Water Process Engineering, Journal Year: 2025, Volume and Issue: 72, P. 107515 - 107515
Published: March 23, 2025
Language: Английский
Citations
0Molecules, Journal Year: 2025, Volume and Issue: 30(7), P. 1544 - 1544
Published: March 31, 2025
In the field of sustainable energy conversion and storage technologies, copper-based complexes have become a research hotspot due to their efficient stable catalytic performance. The development bifunctional catalysts that can simplify steps, enhance efficiency, reduce catalyst usage has an important area. this study, we successfully synthesized two copper with different geometries utilizing di(2-pyridyl) ketone as ligand, [CuII2L2Cl2]·0.5H2O (1) [Cu4IIL4(OCH3)2](NO3)2 (2) (L = deprotonated methoxy-di-pyridin-2-yl-methanol), which serve homogeneous electrocatalysts for water oxidation CO2 reduction simultaneously. turnover frequency (TOF) 1 2 electrocatalytic are 7.23 s−1 0.31 under almost neutral condition (pH 8.22), respectively. Meanwhile, TOF CO 4.27 8.9 s−1, addition, both remain essentially unchanged during processes, demonstrating good stability. Structural analysis reveals distinct efficiencies originate from geometric configurations: binuclear structure complex facilitates proton-coupled electron transfer oxidation, whereas tetranuclear architecture enhances activation. Complexes represent first molecular capable catalyzing reduction. findings in work open up new avenues advancement artificial photosynthesis simulation
Language: Английский
Citations
0Journal of Water Process Engineering, Journal Year: 2024, Volume and Issue: 68, P. 106329 - 106329
Published: Oct. 28, 2024
Language: Английский
Citations
2