Interface Modulation of Metal Sulfide Anodes for Long‐Cycle‐Life Sodium‐Ion Batteries

Advanced Materials, Journal Year: 2023, Volume and Issue: 35(13)

Published: Jan. 20, 2023

Although studies of transition metal sulfides (TMS) as anode materials for sodium-ion batteries are extensively reported, the short cycle life is still a thorny problem that impedes their practical application. In this work, new capacity fading mechanism TMS electrodes demonstrated; is, parasitic reaction between electrolyte anions (i.e., ClO4- ) and yields non-conductive unstable solid-electrolyte interphase (SEI) meanwhile, corrosively turns into less-active oxides. This knowledge guides development an electrochemical strategy to manipulate anion decomposition construct stable interface prevents extensive reactions. It shown introducing sodium nitrate radically changes Na+ solvation structure by populating ions in first sheath, generating conductive SEI layer containing both Na3 N NaF. The optimized enables iron sulfide stably over 2000 cycles with negligible loss, similar enhancement performance demonstrated on number other sulfides. work discloses sulfides' cycling failure from unique perspective highlights critical importance manipulating chemistry batteries.

Language: Английский

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Recent Progress in the Emerging Modification Strategies for Layered Oxide Cathodes toward Practicable Sodium Ion Batteries

Advanced Energy Materials, Journal Year: 2023, Volume and Issue: 13(27)

Published: May 16, 2023

Abstract Low‐cost sodium‐ion batteries (SIBs) have been extensively considered as a supplement or even replacement for successful lithium‐ion batteries. However, the practical application of SIBs is limited by their energy density and cyclic performance, which are mainly constrained cathode side. Therefore, development advanced materials essential SIBs. Among various materials, layered transition metal oxides (LTMOs) highly promising candidates due to compact crystal structure, low‐cost, ease preparation, similarities Li‐based LTMOs. Unfortunately, bottleneck issues faced Na‐based LTMOs, such severe phase transitions, sluggish diffusion kinetics, interface deterioration, pose significant challenges in achieving high‐performance cathodes. In this review, comprehensive overview summary recently reported modification strategies provided structure–function–performance relationship refined. A perspective on outlook direction LTMOs cathodes also provided. This review comprehensively explores providing new horizon future research

Language: Английский

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Developing High‐Performance Metal Selenides for Sodium‐Ion Batteries

Advanced Functional Materials, Journal Year: 2022, Volume and Issue: 32(51)

Published: Oct. 9, 2022

Abstract Sodium‐ion batteries (SIBs) show tremendous potential for large‐scale energy storage systems due to the high abundance of sodium resources and potentially low cost. Among discovered anode materials SIBs, metal selenides with large theoretical capacities are considered as a promising candidate. Nevertheless, selenide‐based anodes trapped by poor ionic/electronic conductivity, initial Coulombic efficiency, drastic volume changes during (de)sodiation process. Herein, differences in sodium‐storage mechanisms different first analyzed. Subsequently, specific challenges corresponding modification strategies (such nanostructure design, carbon modification, window regulation, electrolyte optimization, constructing heterostructures) SIB discussed detail, recent advances also presented. Finally, research directions SIBs comprehensively reviewed. It is believed that this review can provide constructive comments on optimization application high‐performance SIBs.

Language: Английский

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Low‐Cost Zinc Substitution of Iron‐Based Prussian Blue Analogs as Long Lifespan Cathode Materials for Fast Charging Sodium‐Ion Batteries

Advanced Functional Materials, Journal Year: 2022, Volume and Issue: 33(2)

Published: Nov. 20, 2022

Abstract Iron‐based Prussian blue analogs (Fe‐PBAs) are extensively studied as promising cathode materials for rechargeable sodium‐ion batteries owing to their high theoretical capacity, low‐cost and facile synthesis method. However, Fe‐PBAs suffer poor cycle stability low specific capacity due the crystallinity irreversible phase transition during excess storage. Herein, a modified co‐precipitation method prepare highly crystallized PBAs is reported. By introducing an electrochemical inert element (Zn) substitute high‐spin Fe in (ZnFeHCF‐2), depth of charge/discharge rationally controlled form reversible process sustainable Minor lattice distortion ZnFeHCF‐2 sodium‐ions insertion extraction proved by in‐situ tests, which have significantly impacted cycling stability. The shows remarkably enhanced performance with retention 58.5% over 2000 cycles at 150 mA g −1 well superior rate up 6000 (fast kinetics). Furthermore, successful fabrication full cell on as‐prepared commercial hard carbon anode demonstrates potential high‐performance electrode large‐scale energy storage systems.

Language: Английский

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Formulating High‐Rate and Long‐Cycle Heterostructured Layered Oxide Cathodes by Local Chemistry and Orbital Hybridization Modulation for Sodium‐Ion Batteries

Advanced Materials, Journal Year: 2022, Volume and Issue: 34(33)

Published: June 24, 2022

Abstract It is still very urgent and challenging to simultaneously develop high‐rate long‐cycle oxide cathodes for sodium‐ion batteries (SIBs) because of the sluggish kinetics complex multiphase evolution during cycling. Here, concept accurately manipulating structural formulating high‐performance heterostructured biphasic layered by local chemistry orbital hybridization modulation reported. The P2‐structure stoichiometric composition cathode material shows a P2‐ O3‐type heterostructure that explicitly evidenced various macroscale atomic‐scale techniques. Surprisingly, displays excellent rate performance, remarkable cycling stability (capacity retention 82.16% after 600 cycles at 2 C), outstanding compatibility with hard carbon anode integrated advantages intergrowth structure environment regulation. Meanwhile, formation process from precursors calcination highly reversible dynamic Na + intercalation/deintercalation are clearly articulated series in situ characterization Also, intrinsic properties corresponding electrochemical behavior further elucidated density states electron localization function functional theory calculations. Overall, this strategy, which finely tunes orbitals SIBs, will open up new field other materials.

Language: Английский

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Toward Smart Sensing by MXene

Small, Journal Year: 2022, Volume and Issue: 19(14)

Published: Dec. 14, 2022

Abstract The Internet of Things era has promoted enormous research on sensors, communications, data fusion, and actuators. Among them, sensors are a prerequisite for acquiring the environmental information delivering to an artificial center make decisions. MXene‐based have aroused tremendous interest because their extraordinary performances. In this review, electrical, electronic, optical properties MXenes first introduced. Next, discussed according sensing mechanisms such as electrochemical, methods. Initially, biosensors introduced based chemiresistors field‐effect transistors. Besides, wearable pressure sensor is demonstrated with piezoresistive devices. Third, electrochemical methods include amperometry electrochemiluminescence examples. addition, approaches refer surface plasmonic resonance fluorescence energy transfer. Moreover, prospects delivered multimodal fusion toward complicated human‐like senses. Eventually, future opportunities MXene conveyed in new material discovery, structure design, proof‐of‐concept

Language: Английский

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Structure evolution of layered transition metal oxide cathode materials for Na-ion batteries: Issues, mechanism and strategies

Materials Today, Journal Year: 2022, Volume and Issue: 62, P. 271 - 295

Published: Dec. 16, 2022

Language: Английский

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Low-cost layered oxide cathode involving cationic and anionic redox with a complete solid-solution sodium-storage behavior

Energy storage materials, Journal Year: 2022, Volume and Issue: 47, P. 44 - 50

Published: Jan. 28, 2022

Language: Английский

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Advanced MOF-derived carbon-based non-noble metal oxygen electrocatalyst for next-generation rechargeable Zn-air batteries

Coordination Chemistry Reviews, Journal Year: 2022, Volume and Issue: 473, P. 214839 - 214839

Published: Sept. 20, 2022

Language: Английский

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Construction of ZnS/Sb₂S₃ Heterojunction as an Ion‐Transport Booster toward High‐Performance Sodium Storage

Advanced Functional Materials, Journal Year: 2022, Volume and Issue: 33(9)

Published: Dec. 26, 2022

Abstract Metal sulfides have shown great promise for sodium‐ion batteries due to their excellent redox reversibility and relatively high capacity. However, metal generally suffer from sluggish charge transport serious volume change during the charge–discharge process. Herein, potato chip‐like nitrogen‐doped carbon‐coated ZnS/Sb 2 S 3 heterojunction (ZnS/Sb @NC) is precisely synthesized through a sulfurization reaction, subsequent cation exchange process between Zn 2+ Sb 3+ . The theoretical calculations experimental studies reveal boosted transfer in @NC composites. Therefore, electrode exhibits cycling stability (a reversible capacity of 511.4 mAh g ‐1 after 450 cycles) superior rate performance (400.4 at 10 A ). In addition, based on conversion‐alloy reaction mechanism store Na + , which disclosed by X‐ray diffraction resolution transmission electron microscopy analysis. This effective synthesis method can provide reference design other high‐performance materials batteries.

Language: Английский

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