Constructing self-standing Fe2O3-Pt/NF nanoflowers with synergistic active sites for efficient electrocatalytic overall (sea) water splitting DOI
Weiping Xiao, Yue Zhang,

Changwang Ke

et al.

Nanoscale, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

The corrosion engineering strategy is used to synthesize self-standing Fe 2 O 3 -Pt/NF heterostructures for efficient water splitting in alkaline solution, attributed abundant active sites, fast electron transfer, and strong electronic interaction.

Language: Английский

Enhancing the Electrocatalytic Oxidation of 5-Hydroxymethylfurfural Through Cascade Structure Tuning for Highly Stable Biomass Upgrading DOI Creative Commons
Xiaoli Jiang,

Xianhui Ma,

Yuanteng Yang

et al.

Nano-Micro Letters, Journal Year: 2024, Volume and Issue: 16(1)

Published: Aug. 22, 2024

Abstract Electrocatalytic 5-hydroxymethylfurfural oxidation reaction (HMFOR) provides a promising strategy to convert biomass derivative high-value-added chemicals. Herein, cascade is proposed construct Pd–NiCo 2 O 4 electrocatalyst by Pd loading on Ni-doped Co 3 and for highly active stable synergistic HMF oxidation. An elevated current density of 800 mA cm –2 can be achieved at 1.5 V, both Faradaic efficiency yield 2,5-furandicarboxylic acid remained close 100% over 10 consecutive electrolysis. Experimental theoretical results unveil that the introduction atoms modulate local electronic structure Ni/Co, which not only balances competitive adsorption OH – species, but also promote Ni 3+ species formation, inducing high indirect activity. We have discovered incorporation facilitates 2+ pre-oxidation electrophilic OH* generation contribute direct process. This work new approach design advanced upgrading.

Language: Английский

Citations

13
FeP nanoparticles anchored on N-doped carbon as ORR/OER bifunctional catalyst and its application in Zn-air batteries DOI

Yifei Su,

Hongmei Du, Jingjing Xu

et al.

Fuel, Journal Year: 2025, Volume and Issue: 387, P. 134349 - 134349

Published: Jan. 11, 2025

Language: Английский

Citations

1
External field-assisted catalysis DOI Creative Commons
Linbo Jiang,

Lintao Jiang,

Xu Luo

et al.

eScience, Journal Year: 2025, Volume and Issue: unknown, P. 100398 - 100398

Published: March 1, 2025

Language: Английский

Citations

1
General design of self-supported Co-Ni/nitrogen-doped carbon nanotubes array for efficient oxygen evolution reaction DOI

Mengfei Mou,

Yameng Wang,

Wenjie Yu

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Language: Английский

Citations

0
Single-atom Tungsten Doping Induced Chemical-electrochemical Coupled Pathway on Ni(OH)2 Enables Efficient Urea Electrooxidation DOI

Lebin Cai,

Haoyun Bai, Jilong Li

et al.

Energy & Environmental Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

A chemical–electrochemical coupled pathway on Ni(OH) 2 surface has been proposed for high-selectivity urea electrooxidation reaction (UOR) as the alternative of conventional oxygen evolution (OER).

Language: Английский

Citations

0
In Situ Construction of IrOx Nanofilm on TiOx for Boosting Low‐Ir Catalysis in Practical PEM Electrolyze DOI Open Access
Yufeng Qin, Yixuan Huang, Qingqing Ye

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 10, 2025

Abstract Exploring low‐iridium (Ir) electrocatalysts for oxygen evolution reaction (OER) is exigent to promote the commercialization of proton electrolyte membrane water electrolyzers (PEMWEs). Herein, study presents a scalable and facile strategy in situ construct an IrO x nanofilm continuously coated on TiO support as efficient durable OER catalyst through one‐step annealing Ir‐salt‐adsorbed titanium‐based metal–organic frameworks (MOFs) precursor. The unique structure forms continuous p‐n junction interface, endowing strong interfacial electron transfer from also ensuring well‐connected conductive network anodic catalytic layer due dispersion . optimal requires low overpotential 233 mV at 10 mA cm −2 with 40‐fold com. 2 mass activity. assembled PEMWE shows cell voltage 1.762 V 1 A ≈220 h operation under start/shut‐down operation. Operando characterizations theoretical calculation reveal that not only reduces energy barrier dissociation deprotonation step *OOH boosting kinetics but prevents oxidation Ir sites form soluble species improves durability. This work offers new avenue rationally design synthesize low‐Ir application.

Language: Английский

Citations

0
Carbon in situ supported Ni/CeO2 heterogeneous catalyst with rich interfaces for efficient electrocatalysis DOI
Xiaodan Yang, Yuan Zhang, Shimin Zhang

et al.

Journal of Rare Earths, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 1, 2025

Language: Английский

Citations

0
Enabling Unconventional “Alternating‐Distal” N2 Reduction Pathway for Efficient Ammonia Electrosynthesis DOI Open Access
Chu Zhang, Qing Wang, Zeyu Li

et al.

Angewandte Chemie International Edition, Journal Year: 2025, Volume and Issue: unknown

Published: March 10, 2025

The general understanding on the reaction path is that electrocatalytic N2 reduction follows either individual associative alternating or distal pathways, where efficient activation and selective NH3 production are very challenging. Herein, an unconventional "alternating-distal" pathway was achieved by shifting "*NHNH2→*NH2NH2" to "*NHNH2→*NH + NH3" step boost synthesis with amorphous CeMnOx electrocatalyst. In this process, realized through π back donation Mn site, while Mn/Ce dual active sites could regulate intermediate configurations avoid nitrogen-containing by-product formation. Such affirmed in situ spectroscopic analyses theoretical calculations. a neutral media, average ammonia rate of 82.8 µg h-1 mg-1 outstanding Faradaic efficiency 37.3% were attained. This work validated mechanism synthesis, which might be extended other catalytic process multiple possible paths.

Language: Английский

Citations

0
Dual atom coordinated nickel-cobalt selenide Nanoflowers with superior OER performance synthesized via one-step hydrothermal approach DOI
Yiyang Chen, Chaofan Liu, Huanan Wang

et al.

Journal of Electroanalytical Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 119053 - 119053

Published: March 1, 2025

Language: Английский

Citations

0
Anode Alchemy on Multiscale: Engineering from Intrinsic Activity to Impedance Optimization for Efficient Water Electrolysis DOI Creative Commons

Xiaotong Wu,

Faiza Meharban, Jingsan Xu

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: March 5, 2025

The past decade has seen significant progress in proton exchange membrane water electrolyzers (PEMWE), but the growing demand for cost-effective electrolytic hydrogen pushes higher efficiency at lower costs. As a complex system, performance of PEMWE is governed by combination multiscale factors. This review summarizes latest from quantum to macroscopic scales. At level, electron spin configurations can be optimized enhance catalytic activity. nano and meso scales, advancements atomic structure optimization, crystal phase engineering, heterostructure design improve mass transport. macro scale, innovative techniques gas bubble management internal resistance reduction drive further gains under ampere-level operating conditions. These modifications level cascade through meso- macro-scales, affecting charge transfer, reaction kinetics, evolution management. Unlike conventional approaches that focus solely on one scale-either catalyst (e.g., atomic, or modifications) device porous transport layers design)-combining optimizations unlocks greater improvements. Finally, perspective future opportunities engineering anode toward commercial viability offered.

Language: Английский

Citations

0