Abstract
High-resolution
three-dimensional
micro-CT
imaging
is
used
to
investigate
nitrogen,
carbon
dioxide,
and
hydrogen
injection
in
reservoir
carbonate
rocks.
The
images
were
analysed
ascertain
gas
saturation,
pore
occupancy,
ganglia
size
connectivity
across
the
sample.
experiment
studies
a
water-wet
rock
that
filled
with
synthetic
brine
before
between
each
injection.
experimental
conditions
involve
unsteady-state
at
pressure
of
9
MPa,
temperature
60°C,
rate
0.005
mL/min,
0.1
mL/min
remove
all
sample
firstly
saturated
brine,
followed
by
N2
injection,
then
Images
are
taken
throughout
phase
after
waiting
24
hours
This
procedure
replicated
for
CO2
H2
cycles.
saturation
gases
as
follows:
around
25%,
approximately
21%,
18%.
While
slightly
decreased
hours,
remained
relatively
stable
over
time.
profile
reveals
experience
more
significant
changes
during
period
caused
Ostwald
ripening
compared
propagate
centre
Capillary
measurements
based
on
interfacial
curvature
80%
indicate
decline
N2,
from
1.46
kPa
1.18
hours.
experiences
decrease
1.17
1.05
while
shows
minimal
capillary
time
remaining
1.04
kPa.
Pore
occupancy
analysis
occupying
pores
mostly
above
25
µm
radius,
increase
larger
Throat
radii
than
18
show
an
indicating
improved
connectivity,
supported
normalized
Euler
number.
predominantly
occupies
30
40
change.
19
throats
8
increased
suggests
enhanced
connectivity.
Overall,
this
study
provides
useful
reference
comparing
displacement
trapping
behaviour
waterflooding
which
have
been
studied
extensively,
those
H2,
applicable
storage
projects
within
reservoirs.
Journal of Energy Storage,
Journal Year:
2024,
Volume and Issue:
97, P. 112766 - 112766
Published: June 29, 2024
In
this
study,
we
investigate
the
dynamics
of
interfacial
tension
(IFT)
between
residual
pore
water
and
gas
mixtures
containing
H2,
CH4,
H2S
within
subsurface
porous
media,
essential
for
underground
hydrogen
storage
(UHS)
systems.
Utilizing
molecular
simulations,
established
specific
IFT
correlations
across
a
spectrum
concentrations,
ranging
from
5
%
to
80
%,
under
conditions
14.5
MPa
343
K.
Our
results
demonstrate
marked
decrease
in
IFT,
with
notable
12
reduction
observed
even
at
minimal
concentration
H2S-H2
mixtures,
contrasting
6
H2S-CH4
reaching
saturation
point
concentrations
exceeding
%.
The
presence
CH4
interface
mitigates
caused
by
H2S,
underscoring
complexity
interactions
storage.
These
insights
into
gas-water
carry
significant
implications
optimization
UHS
operations,
informed
substantial
variations
different
concentrations.
International Journal of Hydrogen Energy,
Journal Year:
2024,
Volume and Issue:
86, P. 261 - 274
Published: Aug. 30, 2024
Using
high-resolution
micro-CT
imaging
at
2.98
μm/voxel,
we
compared
the
percolation
of
hydrogen
in
gas
injection
with
expansion
for
a
hydrogen-brine
system
Bentheimer
sandstone
1
MPa
and
20
°C,
representing
storage
an
aquifer.
We
introduced
dimensionless
numbers
to
quantify
contribution
advection
displacement.
analysed
3D
spatial
distribution
its
displacement
both
cases
demonstrated
that
injection,
can
only
advance
from
connected
cluster
invasion-percolation
type
process,
while
expansion,
access
more
pore
space
even
disconnected
clusters.
The
average
saturation
sample
increased
30%
50%
by
estimated
10%
expanded
volume
is
attributed
exsolution
brine.
This
work
emphasises
importance
studying
combined
effects
pressure
decline
withdrawal
assess
influence
on
remobilising
trapped
gases.
•
High-resolution
X-ray
studied
sandstone.
Disconnected
clusters
expand
reconnect
during
decline.
Gas
as
declined.
Hydrogen
brine
10%.
accessed
larger
pores
than
injection.