Hydrated Metal Vanadate Heterostructures as Cathode Materials for Stable Aqueous Zinc-Ion Batteries DOI Creative Commons

Siqi Zhang,

Yan Wang, Yunyu Wu

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(16), P. 3848 - 3848

Published: Aug. 14, 2024

Aqueous zinc ion batteries (AZIBs) have received a lot of attention in electrochemical energy storage systems for their low cost, environmental compatibility, and good safety. However, cathode materials still face poor material stability conductivity, which cause reversibility rate performance AZIBs. Herein, heterogeneous structure combined with cation pre-intercalation strategies was used to prepare novel CaV6O16·[email protected]·nH2O (CaNiVO) high-performance Zn storage. Excellent achieved via the wide interlayer conductive network originating from interlayer-embedded metal ions heterointerfaces two-phase CaNiVO. Furthermore, this unique further showed excellent structural led fast electron/ion transport dynamics. Benefiting strategies, CaNiVO electrodes an impressive specific capacity 334.7 mAh g−1 at 0.1 A 110.3 2 g−1. Therefore, paper provides feasible strategy designing optimizing superior performance.

Language: Английский

Future Long Cycling Life Cathodes for Aqueous Zinc‐Ion Batteries in Grid‐Scale Energy Storage DOI Creative Commons
Divyani Gupta, Sailin Liu, Ruizhi Zhang

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 21, 2025

Abstract Developing sustainable energy storage systems is crucial for integrating renewable sources into the power grid. Aqueous zinc‐ion batteries (ZIBs) are becoming increasingly popular due to their safety, eco‐friendliness, and cost‐effectiveness. However, challenges remain in achieving realistic time per charge, long cycling life, high capacity practical conditions. Despite advancements cathode materials, issues such as dissolution side reactions limit performance. Optimizing architecture electrolyte composition essential address these challenges. Tailored formulations can stabilize electrode‐electrolyte interface (EEI enhance stability. This perspective reviews cathodes from past decades compares performance under different current densities. Emphasizing low density extended stability widespread adoption of ZIBs grid‐scale applications. By focusing on aspects, this aims bridge gap between research applications, offering insights optimizing material structure selecting matching electrolytes storage. work guides future developments ZIB technology, facilitating transition lab real‐world deployment.

Language: Английский

Citations

1

Regulating the zinc ion transport kinetics of Mn3O4 through copper doping towards high-capacity aqueous Zn-ion battery DOI
Yafei Guo,

Zhen-Hao Luo,

Nan Zhang

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 677, P. 459 - 469

Published: July 31, 2024

Language: Английский

Citations

5

Operando pH measurements revealing the promoted Zn2+ intercalation kinetics of pre-intercalated V2O5 cathode in aqueous zinc metal batteries DOI Creative Commons
Xu Liu,

Dong Xu,

Stefano Passerini

et al.

Journal of Power Sources, Journal Year: 2024, Volume and Issue: 623, P. 235401 - 235401

Published: Sept. 8, 2024

Language: Английский

Citations

5

Asymmetric supercapacitor with Mn-Ni-Co vanadate and carbon black incorporated FeMoO4 electrodes DOI
Vikas Sharma,

Rishabh Jaiswal,

Garima Chaturvedi

et al.

Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 93, P. 112311 - 112311

Published: May 30, 2024

Language: Английский

Citations

4

Zincophilic and hydrophobic group grafting vanadyl phosphate cathode for high performance zinc ion batteries DOI
Binglin Zhang, Yu Jiang, Shiyao Deng

et al.

Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 114, P. 115873 - 115873

Published: Feb. 22, 2025

Language: Английский

Citations

0

Synergistically Electronic and Structural Regulation of VO2 by Ce Doping Toward High-Performance Zinc-Ion Batteries DOI
Haozhen Li, Xiaocheng Li, Juan Liu

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: March 18, 2025

Language: Английский

Citations

0

Engineering of VOx structure integrating oxygen vacancies for improved zinc ions storage based on cations doping regulation with electric density DOI
Juan Xu,

Nengneng Han,

Sihao Chen

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(34), P. 14182 - 14192

Published: Jan. 1, 2024

Cation-embedding and oxygen-vacancy co-modified VO x thin-sheet-microspheres assembled with nanoparticles were designed for zinc-ion batteries a high rate capacity.

Language: Английский

Citations

3

Cerium-doped Mn2O3 microspheres: a high-performance cathode material for aqueous zinc-ion batteries DOI
Xin Li, Wenyu Wang, Linwen Li

et al.

New Journal of Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Aqueous zinc-ion batteries (AZIBs) have received considerable attention due to their advantages of being safe, environmentally friendly, and cost-effective.

Language: Английский

Citations

0

Electronic Conductive Metal–Organic Frameworks for Aqueous Rechargeable Zinc‐Ion Battery Cathodes: Design, Progress, and Prospects DOI Creative Commons
Chuntao Yang,

Youlin Xiang,

Yingjian Yu

et al.

Carbon Energy, Journal Year: 2025, Volume and Issue: unknown

Published: April 25, 2025

ABSTRACT Zinc‐ion batteries (ZIBs) have significant potential for advancements in energy storage systems owing to their high level of safety and theoretical capacity. However, ZIBs face several challenges, such as cathode capacity degradation short cycle life. Ordinary metal–organic frameworks (MOFs) are characterized by specific surface areas, large pore channels, controllable structures functions, making them suitable use ZIB cathodes with good performance. the insulating properties MOFs hinder further development. In contrast, electronic conductive (EC‐MOFs) show conductivity, which facilitates rapid electron transport ameliorates charging discharging efficiency ZIBs. This paper introduces unique conduction mechanism EC‐MOFs elaborates various strategies constructing conductivity stability. Additionally, synthesis methods EC‐MOF‐based materials elucidated. Finally, this presents a summary outlook on cathodes. review provides guidance designing applying other devices.

Language: Английский

Citations

0

Sodium-Intercalated Vanadium Oxide Coated on Carbon Cloth for Electrode Materials in High-Performance Aqueous Zinc-Ion Batteries DOI Creative Commons
Chen Chen,

Baoxuan Hou,

Ting Cheng

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(9), P. 2074 - 2074

Published: May 7, 2025

In this work, novel sodium-intercalated vanadium oxide nanowire electrode materials (NaXV@CC) were successfully designed as cathode for Aqueous Zinc-Ion Batteries (AZIBs) through a two-step electrochemical process. The optimized material, Na30V@CC, exhibited superior capacity, excellent rate capability, and outstanding stability. intercalation of sodium ions into the lattice induced significant transformation in overall nanostructure, leading to altered morphology. This unique structural design provided abundant active sites efficient ion transport pathways, thereby enhancing performance. charging discharging capacities 343.3 330.4 mAh·g−1 at 0.2 A·g−1, respectively, capacity was maintained 90 8 A·g−1. battery demonstrated exceptional retention over 3000 cycles 5 highlighting its long-term Moreover, reaction governed by combination diffusion surface processes. Na30V@CC system reduced impedance improved zinc rates. study offers valuable insights performance vanadium-based cathodes AZIBs.

Language: Английский

Citations

0