Journal of Materials Chemistry A,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
A
hydrogen-bond-guided
micellar
self-assembly
strategy
is
leveraged
to
construct
flower-like
carbon
superstructures,
which
employs
aggregated
micelles
serve
as
a
structural
guide
enable
attaining
superior
performance
in
ZHCs.
RSC Advances,
Journal Year:
2025,
Volume and Issue:
15(1), P. 323 - 330
Published: Jan. 1, 2025
Flower-like
g-C
3
N
4
/CuCo
2
O
structures
have
been
successfully
established
by
decorating
on
CuCo
nanostructures,
demonstrating
excellent
specific
capacity
and
cyclic
stability
as
a
pseudocapacitance
electrode.
RSC Advances,
Journal Year:
2025,
Volume and Issue:
15(4), P. 2582 - 2590
Published: Jan. 1, 2025
Heteroatom-doped
hierarchical
porous
carbon
(AF-MMTC)
was
prepared
with
hard
template
and
salt
dual
templating
agents,
the
synergistically
construct
pore
structures
at
different
scales.
Small Methods,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 5, 2025
Abstract
Understanding
how
to
tune
the
properties
of
electroactive
materials
is
a
key
parameter
for
their
applications
in
energy
storage
systems.
This
work
presents
comprehensive
study
tailoring
polyaniline
(PANI)
suspensions
by
acid‐assisted
polymerization
method
and
subsequent
deposition
on
boron‐doped
diamond
(BDD)
supports
with
low/high
B
concentrations.
The
porous
or
densely
packed
morphology
PANI
successfully
controlled
varying
monomer‐to‐initiator
ratio.
interaction
between
BDDs
leads
shift
oxidation
reduction
potentials,
high
doping
resulted
potentials.
Notably,
highest
specific
capacitance
958
F
g
−1
,
which
represents
90%
theoretical
capacitance,
recorded
support
relatively
low
content.
Moreover,
obtained
slow
kinetic
has
stronger
B‐doped
support,
confirmed
electrochemical
impedance
spectroscopy.
provides
valuable
insights
optimizing
suspension
preparation
methods
selecting
appropriate
boron
concentrations
nanodiamond
composite
electrodes
applications.
Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 11, 2025
Abstract
Activated
nanoporous
carbons
are
widely
used
in
various
applications,
where
their
efficiency
is
largely
determined
by
specific
surface
area
and
pore
structure.
Traditional
KOH‐assisted
chemical
activation
methods
primarily
produce
micropores,
limiting
the
performance
of
these
porous
applications
requiring
a
hierarchical
arrangement
micro,
meso,
macropores.
This
study
introduces
novel
integrated
strategy
using
3D
flower‐like
microsphere
(3DFM)
ZnO
KOH
to
synthesize
from
Sesbania
Grandiflora
side
shoots.
The
nanosheet
tips
bulk
3DFM‐ZnO
generate
mesopores
macropores,
while
induces
microporosity,
resulting
structure
with
an
ultrahigh
4114
m
2
g
−1
.
fabricated
activated
carbon
electrodes
combination
macro,
micropores
exhibit
high
capacitances
672
F
for
positive
electrode
756
negative
electrode.
optimized
proper
selection
electrolytic
ions
electrodes.
A
operating
potential
window
2.7
V
achieved
symmetric
device
through
charge‐balanced
mass
loading.
flexible
electric
double‐layer
capacitor
demonstrates
maximum
energy
128.2
W
h
kg
at
power
1.35
kW
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 17, 2025
Abstract
Zinc‐ion
hybrid
supercapacitors
(ZHSCs)
are
emerging
for
high‐efficiency
energy
storage.
However,
single‐layer
cathode
materials
often
suffer
from
low‐charge
storage
kinetics.
Herein,
an
innovative
gradient
porous
carbon
superstructure
with
enhanced
charge
kinetics
is
developed,
achieved
by
designing
a
concentration
to
facilitate
rapid,
directional
ion
transport
and
efficient
The
pore
design
optimized
micropore
sizes
(0.88
0.96
nm)
mesopore
size
(≈4
enhances
the
hydrated
zinc
([Zn(H
2
O)
6
]
2+
)
diffusion,
facilitating
desolvation
Zn
Furthermore,
N/O
co‐doping
provides
pseudo‐capacitance
lowering
barrier
C‐O‐Zn
bond
formation,
increasing
defect
density
conductivity
of
material.
Further
graphitization
improves
wettability,
while
high
specific
surface
area
(SSA)
offers
abundant
active
sites.
ZHSCs
fabricated
this
exhibit
remarkably
101.8
Wh
kg
−1
at
substantial
power
503.6
W
,
outperforming
reported
benchmark
materials.
exceptional
charge–discharge
cycling
stability
also
demonstrated
over
10
000
cycles.
This
work
presents
effective
strategy
enhancing
in
supercapacitors.
RSC Advances,
Journal Year:
2025,
Volume and Issue:
15(12), P. 9055 - 9080
Published: Jan. 1, 2025
As
the
demand
for
efficient
and
high-performance
energy
storage
devices
continues
to
rise,
supercapacitors
have
emerged
as
a
promising
technology
due
their
rapid
charge–discharge
capabilities
long
cycle
life.