Chemistry - An Asian Journal, Journal Year: 2024, Volume and Issue: 19(17)
Published: June 6, 2024
Dry reforming of methane (DRM), the catalytic conversion CH
Language: Английский
Chemistry - An Asian Journal, Journal Year: 2024, Volume and Issue: 19(17)
Published: June 6, 2024
Dry reforming of methane (DRM), the catalytic conversion CH
Language: Английский
Process Safety and Environmental Protection, Journal Year: 2024, Volume and Issue: 183, P. 244 - 259
Published: Jan. 5, 2024
Language: Английский
Citations
13Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: 13(2), P. 115407 - 115407
Published: Jan. 11, 2025
Language: Английский
Citations
1ACS Omega, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 19, 2025
Hydrogenation saturation of phenanthrene (a typical component coal tar) could not only improve the combustion performance fuel oil, but also obtain raw material for preparing high-energy-density fuel. Nickel-based catalysts have been considered promising hydrogenation due to their appealing capacity activate molecules. However, Ni derivation precursor greatly affects its activity. In this work, NiAl2O4 catalyst was obtained by sol-gel method. Under experimental conditions temperature 300 °C, pressure 5 MPa, and WHSV 0.52 h-1, conversion over can be up 99.7 93.9% perhydrophenanthrene yield, while those traditional Ni/Al2O3 are just 96.8 77.3%, respectively. Moreover, TOF (3.01 × 10-3 s-1) surpasses that (2.46 s-1), which indicates derived from has stronger According relevant characterizations, superior derives H2 adsorption dissociation ability formation an electron-deficient structure active metal Ni, contributes improved activation polycyclic aromatic hydrocarbons.
Language: Английский
Citations
1Process Safety and Environmental Protection, Journal Year: 2024, Volume and Issue: 187, P. 845 - 863
Published: May 6, 2024
Language: Английский
Citations
5Energy Conversion and Management, Journal Year: 2024, Volume and Issue: 311, P. 118227 - 118227
Published: May 8, 2024
Language: Английский
Citations
5Molecular Catalysis, Journal Year: 2024, Volume and Issue: 562, P. 114226 - 114226
Published: May 17, 2024
Language: Английский
Citations
5Molecular Catalysis, Journal Year: 2024, Volume and Issue: 562, P. 114216 - 114216
Published: May 13, 2024
This study investigates the molecular dynamics of methane dry reforming catalyzed by a novel nickel-strontium-zirconium-aluminum (5Ni+3Sr/10Zr+Al) catalyst, leveraging both Response Surface Methodology (RSM) and Radial Basis Function Neural Network (RBFNN) for predictive optimization. Focusing on impact operational parameters—hourly space velocity, reaction temperature, CO2:CH4 mole ratio—on conversion rates formation components, we aim to predict optimal conditions corresponding process variables. Through comparison three-layer Feed Forward Network, optimized at 3:10:1 topology, with traditional RSM approaches, our findings highlight superior capabilities ANN models. Notably, demonstrated exceptional performance Radj2and F_Ratio values significantly surpass those RSM, alongside lower statistical error terms. superiority is attributed ANN's robust handling nonlinear relationships between inputs outputs, asserting its potential enhancing accuracy in chemical At optimum predicted like 1 CH4/CO2,750 °C 12000 cm3g−1h−1 NiSrZrAl outperformed > 85 % CH4 CO2 H2/CO ∼1 up 20 h time stream. Our research underscores importance integrating advanced modeling techniques efficient accurate prediction catalytic reactions, offering valuable insights future applications engineering catalysis.
Language: Английский
Citations
4Journal of Industrial and Engineering Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 1, 2024
Language: Английский
Citations
4Molecular Catalysis, Journal Year: 2025, Volume and Issue: 577, P. 114963 - 114963
Published: March 3, 2025
Language: Английский
Citations
0Molecular Catalysis, Journal Year: 2025, Volume and Issue: 582, P. 115060 - 115060
Published: May 1, 2025
Language: Английский
Citations
0