Unbounding the Future: Designing NiAl‐Based Catalysts for Dry Reforming of Methane DOI

Wenzheng Zhang,

Huahua Zhao, Huanling Song

et al.

Chemistry - An Asian Journal, Journal Year: 2024, Volume and Issue: 19(17)

Published: June 6, 2024

Dry reforming of methane (DRM), the catalytic conversion CH

Language: Английский

Cs promoted Ni/ZrO2-Al2O3 catalysts for dry reforming of methane: Promotional effects of Cs for enhanced catalytic activity and stability DOI Creative Commons
Abdulaziz A.M. Abahussain, Ahmed S. Al‐Fatesh, Sunit Kumar Singh

et al.

Arabian Journal of Chemistry, Journal Year: 2023, Volume and Issue: 17(2), P. 105564 - 105564

Published: Dec. 19, 2023

Carbon Capture and Utilization (CCU) technologies offer a promising avenue for transforming captured CO2 into valuable products, serving as renewable fuels or precursors high-value synthesis. This study explores the dry reforming of methane (DRM) viable pathway to convert CH4 syngas, achieving high equilibrium conversion through use suitable catalysts. Conventional nickel-based catalysts are susceptible carbon deposition, necessitating innovative approaches enhance their performance. A tubular microreactor was employed conduct process at 800 °C, utilizing Cs-promoted Ni supported on 90 % Al2O3 10 ZrO2-based support composition. Catalyst preparation involved impregnation technique, subsequent characterization N2-physisorption, XRD, H2-TPR, TGA, TPD, Raman spectroscopy. The DRM reaction systematically investigated using Ni/ ZrO2- catalysts, with specific focus catalytic effects Cs promotion. Observations revealed that incorporation onto matrix led substantial increase in hydrogen yield selectivity across all catalyst compositions, accompanied by significant reduction deposition surface. optimal loading, determined be 3 wt% over catalyst, exhibited conversions 87 %, respectively, an H2/CO approaching 1 (0.95). research underscores potential Cs-modified enhancing efficiency CCU applications, providing insights optimizing formulations improved performance transformation processes.

Language: Английский

Citations

10
Hydrogen energy from biogas (CO2 and CH4) via dry reforming of methane: A review on confined Ni-catalysts DOI
Osarieme Uyi Osazuwa, Dai‐Viet N. Vo, Kim Hoong Ng

et al.

Process Safety and Environmental Protection, Journal Year: 2025, Volume and Issue: unknown, P. 107045 - 107045

Published: April 1, 2025

Language: Английский

Citations

0
Kinetic Modeling for Coke Combustion over a Nickel Catalyst Deactivated under Methane Dry Reforming Conditions DOI Creative Commons
Amaya Gil-Barbarin, Andoni Choya, Jose Ignacio Gutiérrez-Ortiz

et al.

ACS Omega, Journal Year: 2025, Volume and Issue: unknown

Published: April 21, 2025

This study validates the effectiveness of a composite kinetic processing approach combining isoconversional method and master-plot to determine triplet (reaction model, apparent pre-exponential factor, activation energy) for nonisothermal combustion at various heating rates coked nickel catalyst employed in dry reforming methane. First, average energy (164.5 kJ mol-1) was determined using Kissinger-Akahira-Sunose (KAS) method. Next, applied establish regeneration model function, revealing that carbon nanotubes followed reaction order (n = 1.36). The consistency kinetics validated by comparing experimental calculated thermoanalytical curves constant rate.

Language: Английский

Citations

0
Influence of Metal Composition and Support Material on Carbon Yield and Quality in the Direct Decomposition of Methane DOI Creative Commons

Uidam Jun,

Bon-Jun Ku,

Yeji Gwon

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(9), P. 1903 - 1903

Published: April 24, 2025

A series of catalysts were synthesized via a combination evaporation-induced self-assembly and spray pyrolysis; they then applied to the direct decomposition methane. Among them, Ni-Cu/MgO exhibited smallest Ni particle size (~9 nm), attributed Cu-induced suppression crystal growth during synthesis. These achieved highest carbon yield, primarily due enhanced dispersion nanoscale particles. The interaction between methane catalysts, as well structural electrical properties resulting nanotubes, such crystallinity conductivity, investigated with respect support material (MgO vs. Al2O3) metal composition (Ni Ni-Cu). findings provide valuable insights for designing advanced catalyst systems efficient conversion into high-value carbon-based materials.

Language: Английский

Citations

0
Dry Reforming of Methane over Mn-modified Ni-based Catalysts DOI Creative Commons

Alua M. Manabayeva,

Päivi Mäki‐Arvela, Zuzana Vajglová

et al.

Catalysis Letters, Journal Year: 2024, Volume and Issue: 154(8), P. 4780 - 4794

Published: April 24, 2024

Abstract Ni-based bi- and trimetallic Mn, Mg aluminum containing catalysts prepared by the solution combustion synthesis (SCS) method were tested in dry reforming of methane (DRM). As a comparison 12 wt.% Ni/α-Al 2 O 3 catalyst wet impregnation was also investigated. The characterized means XRD, N physisorption, H -TPR, CO -TPD, NH TPO, CHNS, TGA, SEM TEM. Formation crystalline MnAl 4 observed at high temperatures during SCS. average nickel particle size varied range 12–36 nm. Addition Mn promoted reduction Ni elevated amount strength basic sites. Graphical

Language: Английский

Citations

3
Ni-CeO2/TS-1 catalyze methane dry reforming: Improving catalytic performance and stability by modulating the amount and strength of Ni-O-X species DOI

Zhuwei Yang,

Linsen Li,

Xiao Yang

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 497, P. 154594 - 154594

Published: Aug. 6, 2024

Language: Английский

Citations

3
Fabrication of nickel aluminate based electrochemical sensor for dopamine detection DOI Creative Commons

R. Rangaswamy,

S.R. Manohara,

K.M. Supritha

et al.

Hybrid Advances, Journal Year: 2024, Volume and Issue: 6, P. 100221 - 100221

Published: June 6, 2024

Nickel aluminate nanoparticles (NiAl2O4 NPs) spinel structure is synthesized via a simple solution combustion method using aqueous nickel nitrate, aluminum nitrate and citric acid. The crystal microstructure of the prepared NiAl2O4 NPs are confirmed by powder X-ray diffraction (XRD), photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) spectrum, scanning transmission electron microscopy (SEM/TEM). characterized applied on glassy carbon electrode (GCE) to design electrochemical sensor for detection dopamine (DA) cyclic voltammograms (CV) differential pulse anodic stripping voltammograms. proposed exhibits excellent sensing activity with low limit 1.78 μM applicable wide linear concentration range 10 140 μM. Further, well resolved voltammogram in presence interfering uric acid ascorbic

Language: Английский

Citations

2
Enhanced catalytic performance induced by synergistic interaction between Pd species with NiAl2O4 spinel support for aqueous-phase hydrodechlorination of 4-chlorophenols DOI
Zheng Li,

Jiehao Xie,

Zipin Peng

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 497, P. 154399 - 154399

Published: July 31, 2024

Language: Английский

Citations

1
Advancements in dual-phase carbonate membranes for carbon capture and syngas production DOI Creative Commons

Liza Melia Terry,

Melvin Xin Jie Wee,

Claudia Li

et al.

Carbon Capture Science & Technology, Journal Year: 2024, Volume and Issue: 13, P. 100288 - 100288

Published: Sept. 4, 2024

Language: Английский

Citations

1
Exploring the superior mild temperature performance of nickel-infused fibrous titania silica for enhanced dry reforming of methane DOI

M. Alhassan,

Aishah Abdul Jalil, M.B. Bahari

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 1, 2024

Language: Английский

Citations

1