American Mineralogist,
Journal Year:
2023,
Volume and Issue:
108(9), P. 1732 - 1753
Published: March 23, 2023
Abstract
Banded
iron
formations
(BIF)
are
chemically
precipitated
sediments
that
can
record
Archean
ocean
geochemistry.
BIFs
laminated
silica-
and
iron-rich
deposits
host
a
range
of
iron(II,
III)
minerals,
including
hematite,
magnetite,
siderite,
greenalite,
minnesotaite,
stilpnomelane.
This
diverse
mineralogical
assemblage
reflects
secondary
mineralization
reactions
due
to
diagenesis
and/or
post-depositional
alteration.
While
petrographic
observations
sparingly
contain
the
silicate
recent
evidence
greenalite
nanoparticles
preserved
in
early-mineralizing
BIF
chert
suggest
this
mineral
was
primary
phase
progenitor
sediments.
Therefore,
it
is
critical
investigate
formation
alteration
constrain
environment
help
unravel
processes.
To
examine
how
silicates
precipitate
then
crystallize
transform
during
diagenesis,
we
simulated
these
two
processes
under
conditions.
We
first
poorly
ordered
Fe-rich
serpentine
with
subsidiary
ferrihydrite
at
neutral
pH
by
performing
situ
Fe(II)
oxidation
experiments
25
°C
presence
silica.
Subjected
80
°C,
rudimentary
Fe-phyllosilicate
transformed
into
crystalline
phyllosilicate
characterized
as
30%
cronstedtite
70%
accompanied
magnetite
persistent
ferrihydrite.
At
temperatures
≤150
continued
observe
ferrihydrite,
increased
formation,
elevated
incorporation
Mg
further
recrystallized
Mg-greenalite.
Our
findings
demonstrate
possible
mechanism
early
through
partial
support
likely
mineralizes
diagenesis.
Additionally,
contents
phyllosilicates
could
serve
tracer
for
signaling
phyllosilicate-fluid
interactions
temperatures.
Ultimately,
our
reveal
initial
iron-silica
coprecipitates
altered
providing
novel
insights
interpretation
ancient
assemblages.
Publications of the Astronomical Society of the Pacific,
Journal Year:
2024,
Volume and Issue:
136(5), P. 054302 - 054302
Published: May 1, 2024
Abstract
The
study
of
protoplanetary
disks
has
become
increasingly
important
with
the
Kepler
satellite
finding
that
exoplanets
are
ubiquitous
around
stars
in
our
galaxy
and
discovery
enormous
diversity
planetary
system
architectures
planet
properties.
High-resolution
near-IR
ALMA
images
show
strong
evidence
for
ongoing
formation
young
disks.
JWST
MIRI
mid-INfrared
Disk
Survey
(MINDS)
aims
to
(1)
investigate
chemical
inventory
terrestrial
planet-forming
zone
across
stellar
spectral
type,
(2)
follow
gas
evolution
into
disk
dispersal
stage,
(3)
structure
debris
thermal
mid-IR.
MINDS
survey
will
thus
build
a
bridge
between
properties
exoplanets.
comprises
52
targets
(Herbig
Ae
stars,
T
Tauri
very
low-mass
disks).
We
primarily
obtain
MIRI/MRS
spectra
high
signal-to-noise
ratio
(∼100–500)
covering
complete
wavelength
range
from
4.9
27.9
μ
m.
For
handful
selected
we
also
NIRSpec
IFU
resolution
spectroscopy
(2.87–5.27
m).
search
signposts
emission
micron-sized
dust—information
complementary
scattered
light
small
dust
grains
large
submillimeter
domain.
spatial
three
key
systems
have
shown
formation,
TW
Hya
HD
169142
using
coronagraph
at
15.5
m
10.65
respectively
PDS
70
NIRCam
imaging
1.87
narrow
4.8
medium
band
filter.
provide
here
an
overview
showcase
power
new
mid-IR
molecular
spectrum
where
report
detection
ion
CH3+
robust
confirmation
HCO
+
earlier
detected
Spitzer.
The Astrophysical Journal Letters,
Journal Year:
2025,
Volume and Issue:
980(1), P. L10 - L10
Published: Feb. 6, 2025
Abstract
The
Cassini
spacecraft
revealed
life-forming
elements
like
CHNOP
and
diverse
organic
compounds
from
Enceladus’s
ocean.
However,
the
availability
of
minor
but
bio-essential
nutrients
such
as
iron
sulfur
remains
unknown.
Here,
we
perform
geochemical
modeling
to
explore
their
chemistry
in
We
find
that
dissolved
predominantly
occurs
Fe(
ii
)
with
a
solubility
ranging
10
−8
−5
mole
(kg
H
2
O)
−1
(decreasing
increasing
pH).
Dissolved
sulfur,
mainly
present
HS
−
,
is
predicted
have
concentration
−6
−4
pH
has
only
effect
on
S
solubility.
Our
availabilities
Fe
are
close
measured
concentrations
inhabited
terrestrial
serpentinization
fluids,
implying
sufficient
support
potential
life.
results
also
suggest
reduction
ferric
or
sulfate
might
supply
enough
energy
for
chemotrophic
metabolisms
based
these
reactions
complement
previously
proposed
methanogenesis.
levels
bioproductivity
supported
by
overall
lower
than
those
sustained
other
nutrients,
still
orders
magnitude
higher
maximum
level
estimated
chemical
energy.
The Planetary Science Journal,
Journal Year:
2023,
Volume and Issue:
4(3), P. 42 - 42
Published: March 1, 2023
Abstract
Near-infrared
spectra
of
Umbriel
and
the
other
classical
Uranian
moons
exhibit
2.2
μ
m
absorption
bands
that
could
result
from
ammonia
(NH
3
)
bearing
species,
possibly
exposed
in
geologically
recent
past.
However,
has
an
ancient
surface
with
minimal
evidence
for
endogenic
activity,
raising
possibility
more
refractory
species
are
present,
and/or
NH
is
retained
over
long
timescales.
We
analyzed
33
to
investigate
its
band,
along
three
features
we
identified
near
2.14,
2.22,
2.24
m.
assessed
subobserver
longitudinal
distributions
these
four
bands,
finding
they
present
across
may
be
spatially
associated
geologic
such
as
craters
large
basins.
compared
15
candidate
constituents.
found
Umbriel’s
2.14
2.22
most
consistent
spectral
signature
organics,
band
best
matched
by
ice,
signatures
–H
2
O
mixtures,
aluminum-bearing
phyllosilicates,
sodium-bearing
carbonates.
some
constituents
do
not
match
properties
wavelength
regions,
highlighting
gaps
our
understanding
moons’
compositions.
alternatively
a
ν
overtone
mode
CO
ice.
If
on
Umbriel,
have
formed
contact
internal
ocean
were
subsequently
during
early
history.
Alternatively,
might
originated
undifferentiated
crust
or
delivered
impactors.
Meteoritics and Planetary Science,
Journal Year:
2023,
Volume and Issue:
59(5), P. 927 - 947
Published: May 10, 2023
Abstract
On
February
28,
2021,
a
fireball
dropped
∼0.6
kg
of
recovered
CM2
carbonaceous
chondrite
meteorites
in
South‐West
England
near
the
town
Winchcombe.
We
reconstruct
fireball's
atmospheric
trajectory,
light
curve,
fragmentation
behavior,
and
pre‐atmospheric
orbit
from
optical
records
contributed
by
five
networks.
The
progenitor
meteoroid
was
three
orders
magnitude
less
massive
(∼13
kg)
than
any
previously
observed
fall.
Winchcombe
meteorite
survived
entry
because
it
exposed
to
very
low
peak
dynamic
pressure
(∼0.6
MPa)
due
fortuitous
combination
parameters,
notably
velocity
(13.9
km
s
−1
).
A
near‐catastrophic
at
∼0.07
MPa
points
body's
fragility.
Low
speeds
which
cause
pressures
are
likely
necessary
conditions
for
small
survive
entry,
strongly
constraining
radiant
direction
general
antapex
direction.
Orbital
integrations
show
that
injected
into
near‐Earth
region
∼0.08
Myr
ago
never
had
perihelion
distance
smaller
∼0.7
AU,
while
other
with
known
orbits
approached
Sun
closer
(∼0.5
AU)
were
heated
least
100
K
higher
temperatures.
Geochimica et Cosmochimica Acta,
Journal Year:
2023,
Volume and Issue:
361, P. 245 - 264
Published: Sept. 30, 2023
The
CY
chondrites
are
a
group
of
thermally
metamorphosed
carbonaceous
chondrites.
Although
they
share
similarities
with
the
CM
and
CI
chondrites,
their
primary
properties
argue
for
distinct
classification.
Previous
studies
have
highlighted
isotopically
heavy
bulk
compositions
(δ17O=10
‰,
δ18O=21
Δ17O=0
‰)
exceptionally
high
sulphide
abundances
(10-30
vol%).
In
this
work
we
explore
petrography
alteration
history.
CYs
accreted
low
chondrules
(15-20
area%)
average
apparent
diameters
slightly
larger
(∼320-340
µm)
than
contrast
to
CMs,
record
an
early
episode
brecciation
prior
main
window
aqueous
alteration.
Subsequent
fluid
activity
produced
range
extents
both
CY2
CY1
documented.
Phyllosilicate
minerals
in
were
mix
serpentine
saponite
(including
occurrences
Na-saponite)
minor
quantities
chlorite
(within
chondrules).
An
initial
generation
Fe-sulphides
formed
by
sulfidation
metal,
precipitation
from
S-rich
fluids.
Three
generations
carbonates
recognized,
that
infilled
voids
left
co-precipitated
sulphide,
later
magnetite
final
Fe-Mg-bearing
which
large
(>100
clasts.
Only
first-generation
found
CY2s,
while
CY1s
preserve
all
three
generations.
Phosphates
occur
as
Ca-apatite
or
rarely
Mg-apatite
hydroxylapatite
compositions,
indicating
halogen
activities
Refractory
oxides
(ilmenite
Cr-spinel)
precipitates
adhering
margins
phyllosilicates.
They
late
sequence
attest
oxidizing
conditions.
During
late-stages
replaced
magnetite.
Thermal
metamorphism
(Stage
II-IV:
∼300-750
°C)
overprinted
leading
dehydration
recrystallization
phyllosilicate
matrix
decomposition
some
carbonate
phases.
Most
Fe-sulphide
grains
survived
heating
without
partial
pyrrhotite
troilite
under
closed
system
conditions
led
elevated
ƒS2
gas
resulted
stabilizing
effect.
Retrograde
reactions
between
trapped
S2
metal/magnetite
Fe-sulphides.
survival
stochiometric
evidence
near-closed
heating.
Analysis
organic
matter
Raman
spectroscopy
supports
interpretation
short-duration
(on
scale
minutes
days),
at
peak
temperatures
750-900
°C.
Thus,
impact
event
was
most
likely
cause
metamorphic
Geochimica et Cosmochimica Acta,
Journal Year:
2024,
Volume and Issue:
369, P. 1 - 16
Published: Jan. 28, 2024
The
CM
carbonaceous
chondrites
are
key
archives
for
understanding
the
earliest
history
of
solar
system.
Their
C-complex
asteroid
parent
body(ies)
underwent
aqueous
alteration,
among
products
which
carbonate
minerals
that
can
faithfully
record
conditions
their
formation.
In
this
study
we
report
carbon,
triple
oxygen
and
clumped
isotope
compositions
carbonates
in
six
span
a
range
degrees
alteration
(Allan
Hills
83100,
Cold
Bokkeveld,
LaPaz
Icefield
031166,
Lonewolf
Nunataks
94101,
Murchison,
Scott
Glacier
06043).
Δ17O
values
from
-1
to
-2.6‰
(±0.1),
where
calcite
dolomite
co-exist
differ
by
0.6
permil,
suggesting
precipitation
distinct
fluids.
Calculated
crystallization
temperatures
5
51⁰C
(typically
±10⁰C)
75
101(±15)⁰C
dolomite.
δ18OVSMOW
fluids
they
formed
ranges
-6.6
2.3‰,
with
no
relationship
δ13C
carbonates.
As
population
any
one
chondrite
include
multiple
generations
grains
at
different
conditions,
these
represent
mode
temperature
formation
each
meteorite.
We
observe
more
altered
meteorites
lower
higher.
These
correlations
consistent
being
prograde
reaction
whereby
hotter
had
undergone
greater
exchange
anhydrous
matrix.
Our
data
broadly
closed
system
model
water/rock
interaction,
but
mineral
latter
stages
may
be
linked
fluid
movement
via
fractures.
Scientific Reports,
Journal Year:
2024,
Volume and Issue:
14(1)
Published: May 6, 2024
Abstract
Porosity
affects
key
astromaterial
processes
from
disruption
in
our
atmosphere
and
impact
with
the
ground,
to
comminution
of
boulders
by
thermal
slope
mechanics
on
asteroid
surfaces,
access
utilization
in-situ
resources.
Whereas
bulk
porosity
clay-rich
meteorites
is
well
established,
magnitude
their
surface
area
nano-scale
poorly
known.
Here
we
use
N
2
BET
gas
adsorption
measure
specific
nanoscale
pore
distribution
several
meteorites.
Two
recent
falls
Tarda
(C2-ung)
Aguas
Zarcas
(CM2)
have
areas
72.5
16.5
m
/g,
respectively.
However,
ranges
33.7
81.6
/g
depending
outgassing
conditions.
The
dominated
an
interconnected
network
~
3-nm-sized
pores,
whereas
shows
a
lower
density
3
nm
pores
broader
size
around
40
nm.
In
contrast,
Ivuna
Orgueil
(CI1)
15
18
/g:
low
values
compared
are
likely
due
neoformation
pore-blocking
minerals
during
atmospheric
exposure.
These
data
suggest
that
returned
samples
asteroids
Ryugu
Bennu,
which
mineralogically
texturally
similar
Tarda,
also
high
area.
Meteoritics and Planetary Science,
Journal Year:
2024,
Volume and Issue:
59(3), P. 560 - 567
Published: Jan. 26, 2024
Abstract
The
matrix
of
the
C2‐ungrouped
Tarda
meteorite
contains
abundant
smectite
minerals
that
swell
and
crumble
when
exposed
to
polar
liquids,
causing
sample
rapidly
slake.
This
phenomenon
presents
a
serious
challenge
polishing
meteorite,
as
common
liquids
used
on
carbonaceous
chondrites,
such
water,
ethanol,
ethylene
glycol,
isopropyl
alcohol,
are
will
cause
swell,
making
it
unsuitable
for
some
analyses.
Hexane
mineral
oil
nonpolar
were
found
not
induce
swelling
highly
expansive
montmorillonite‐clay
analog
material
effectively
integrated
into
procedure
Tarda.
Here,
we
detail
mounting,
cutting,
prepare
surface
is
suitable
variety
sensitive
techniques,
electron
microprobe
analysis.
work
offers
practical
methodology
preparation
other
clay‐rich
samples,
which
may
include
recently
returned
Ryugu
Bennu
materials.
Meteoritics and Planetary Science,
Journal Year:
2022,
Volume and Issue:
59(5), P. 1043 - 1067
Published: Dec. 21, 2022
Abstract
The
Winchcombe
meteorite
is
a
CM
chondrite
breccia
composed
of
eight
distinct
lithological
units
plus
cataclastic
matrix.
degree
aqueous
alteration
varies
between
intensely
altered
CM2.0
and
moderately
CM2.6.
Although
no
lithology
dominates,
three
heavily
rock
types
(CM2.1–2.3)
represent
>70
area%.
Tochilinite–cronstedtite
intergrowths
(TCIs)
are
common
in
several
lithologies.
Their
compositions
can
vary
significantly,
even
within
single
lithology,
which
prevent
clear
assessment
extent
if
only
TCI
composition
considered.
We
suggest
that
this
due
to
early
under
localized
geochemical
microenvironments
creating
diversity
because
later
reprocessing
was
incomplete,
leaving
record
the
parent
body's
fluid
history.
In
Winchcombe,
fragments
primary
accretionary
held
matrix
(~15
area%).
This
material
impact‐derived
fallback
debris.
Its
grain
size
texture
disruption
original
asteroid
responded
by
intergranular
fracture
at
sizes
<100
μm,
while
larger
phases,
such
as
whole
chondrules,
splintered
apart.
Re‐accretion
formed
poorly
lithified
body.
During
atmospheric
entry,
meteoroid
broke
apart
with
new
fractures
preferentially
cutting
through
weaker
separating
into
its
component
clasts.
strength
imparts
control
on
survival
meteoroids.
Winchcombe's
unweathered
state
lithologies
make
it
an
ideal
sample
for
exploring
geological
history
group.