Phosphine‐mediated one‐pot reactions: Syntheses of β‐acylated alkylidene indandiones and furo[2,3‐f]dibenzotropones via MBH‐type annulation/acylation or Wittig reaction DOI
Po‐Chung Chien,

You‐Jie Chen,

Gangababu Marri

et al.

Journal of the Chinese Chemical Society, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 7, 2024

Abstract Phosphine‐mediated one‐pot reactions have been developed that involve two mechanistically distinct assembled in one reaction vessel via the sequential addition process. The first step involves MBH‐type annulation of α , β ‐ynones to afford cyclic products each case, which then engages subsequent ‐acylation or intramolecular Wittig reactions. conditions are mild and efficient, providing acylated alkylidene indandiones 70%–99% yields furo[2,3‐ f ]dibenzotropones 65%–91% yields, respectively.

Language: Английский

Synthesis of Spirocyclic‐1,3‐indandione Containing‐Cyclopentenones and ‐Benzotropones DOI Open Access
Gitanjali Mishra,

Yazhinimuthu C.M.,

Barla Thirupathi

et al.

Chemistry - An Asian Journal, Journal Year: 2024, Volume and Issue: 19(20)

Published: July 31, 2024

Synthesis of functionalized 1,3-indandiones containing-cyclopentenones and -benzotropones has been achieved by the reaction 1,5-diphenylpenta-1,4-diyn-3-ones with 1,3-indandiones, bindone respectively. The developed method involves Michael-anti-Michael addition cascade reactions under transition-metal-free conditions. This is first report to synthesise diverse benzotropone fused transition metal-free conditions from bindone.

Language: Английский

Citations

0
Organocatalyzed Enantioselective [3+2] Cycloaddition Reactions for Synthesis of Dispiro[benzothiophenone-indandione-pyrrolidine] Derivatives DOI Creative Commons

Hongyan Liu,

Da‐Ming Du

Molecules, Journal Year: 2024, Volume and Issue: 29(20), P. 4856 - 4856

Published: Oct. 13, 2024

An organocatalytic enantioselective [3+2] cycloaddition reaction involving 2-arylidene-1,3-indandiones and

Language: Английский

Citations

0
Phosphine‐mediated one‐pot reactions: Syntheses of β‐acylated alkylidene indandiones and furo[2,3‐f]dibenzotropones via MBH‐type annulation/acylation or Wittig reaction DOI
Po‐Chung Chien,

You‐Jie Chen,

Gangababu Marri

et al.

Journal of the Chinese Chemical Society, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 7, 2024

Abstract Phosphine‐mediated one‐pot reactions have been developed that involve two mechanistically distinct assembled in one reaction vessel via the sequential addition process. The first step involves MBH‐type annulation of α , β ‐ynones to afford cyclic products each case, which then engages subsequent ‐acylation or intramolecular Wittig reactions. conditions are mild and efficient, providing acylated alkylidene indandiones 70%–99% yields furo[2,3‐ f ]dibenzotropones 65%–91% yields, respectively.

Language: Английский

Citations

0