Nanoscale, Journal Year: 2024, Volume and Issue: unknown
Published: Jan. 1, 2024
The first example of a metallasilsesquioxane/phosphazene compound, Cu 9 Na 4 -based complex, exhibits high catalytic activity in toluene oxidation.
Language: Английский
Journal of Environmental Management, Journal Year: 2025, Volume and Issue: 373, P. 123989 - 123989
Published: Jan. 1, 2025
Language: Английский
Citations
3
Energy Conversion and Management X, Journal Year: 2025, Volume and Issue: unknown, P. 100931 - 100931
Published: Feb. 1, 2025
Language: Английский
Citations
3
Journal of Nanoparticle Research, Journal Year: 2024, Volume and Issue: 26(7)
Published: July 1, 2024
Language: Английский
Citations
11
Nucleosides Nucleotides & Nucleic Acids, Journal Year: 2025, Volume and Issue: unknown, P. 1 - 23
Published: Jan. 19, 2025
This article presents a new and facile method for the synthesis of Schiff base compounds with benzimidazole group using low-cost reusable calcium aluminate nanophosphorus catalyst (CaAl2O4). approach avoids harmful solvents reactants, supporting more environmentally friendly process. The maintained its activity heterogeneity over four cycles minimal loss efficiency. process was straightforward eliminated need column chromatography. ligand (HL=(E)-N-((6-(thiophen-2-yl)pyridin-2-yl)methylene)-1H-benzo[d]imidazol-2-amine)) synthesized by reaction 6-(thiophen-2-yl)pyridine-2-carbaldehyde 1H-benzimidazole-2-amine. Subsequently, metal(II) complexes Co(II), Ni(II), Cu(II) were prepared this ligand. Structural analysis both metal carried out various physicochemical spectroscopic methods. Ni(II) Co(II) found to adopt an octahedral geometry, while complex exhibited square-planar structure. Binding studies calf thymus DNA (CT-DNA) at pH 7.2 performed UV-visible spectroscopy, viscosity measurements, thermal denaturation showed that intercalate into produced distinct binding pattern. Molecular docking simulations AutoDock Vina provided insights interaction these B-DNA dodecamer. Furthermore, photonuclease against pUC19 DNA. Agarose gel electrophoresis exhibit photoinduced nuclease activity, confirming their ability cleave upon exposure light.
Language: Английский
Citations
1
Deleted Journal, Journal Year: 2024, Volume and Issue: 1(4), P. 100018 - 100018
Published: Sept. 11, 2024
Language: Английский
Citations
6
Catalysts, Journal Year: 2025, Volume and Issue: 15(2), P. 118 - 118
Published: Jan. 26, 2025
Nb-Sn, V-Sn mixed-metal oxides and Nb-Si, V-Si metal oxide–silicas were successfully synthesized through a “soft” templating method, in which appropriate amounts of salts (either niobium(V) chloride, or vanadium(IV) oxide sulfate hydrate tin(II) chloride dihydrate) tetraethyl orthosilicate (TEOS) mixed with hexadecyltrimethylammonium (HDTA) sodium dodecyl (SDS) solutions to obtain new series mesoporous oxides, followed by calcination at different temperatures. As-obtained samples characterized SEM, TEM, XRD, UV-Vis spectra techniques. The photocatalytic activities the evaluated degradation methyl orange II (MO) under simulated sunlight irradiation. effects species temperature on physicochemical characteristic activity investigated detail. results indicated that, compared pure showed superior performance for MO. A maximum discoloration rate 97.3% (with MO initial concentration 0.6·10−4 mol/dm3) was achieved 300 min NbSiOx material, much higher than that Degussa P25 same conditions. Additionally, tested photochemical oxidation process, i.e., advanced processes (AOPs) treat commercial non-ionic surfactant: propylene ethylene polymer mono(nonylphenyl) ether (N8P7, PCC Rokita). 99.9% 30 material.
Language: Английский
Citations
0
Chemical Communications, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
The thermodynamics of diazaphospholenes suggest a good balance between hydricity and regeneration capacity ( via electron reduction), inspiring us to identify privileged organocatalysts for electrochemical hydrogen evolution reactions.
Language: Английский
Citations
0
Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160957 - 160957
Published: Feb. 1, 2025
Language: Английский
Citations
0
Catalysts, Journal Year: 2025, Volume and Issue: 15(3), P. 239 - 239
Published: March 1, 2025
The transition to sustainable energy has given biodiesel prominence as a renewable alternative diesel. This review highlights the development and optimization of solid transesterification catalysts, contributing greatly efficiency synthesis. These heterogeneous catalysts are constituted titanium-, zinc-, bio-based systems significant advantages such reusability, thermal stability, ability be synthesized from low-grade feedstocks. Recent advancements in structural optimization, with nano-structured titanium dioxide having potential yielding higher production up yield 96–98% within 5–7 cycles, render improved stability catalytic performance. Several characterization techniques, Brunauer–Emmett–Teller method, X-ray diffraction, temperature-programmed desorption, instrumental these their effective design. However, despite substantial promise, there still problems dealt large-scale production, regeneration, service life catalysts. account collates recent innovations, analytical mechanisms, prospective directions which elucidate furthering technology chemicals.
Language: Английский
Citations
0
Molecular Catalysis, Journal Year: 2025, Volume and Issue: 578, P. 115025 - 115025
Published: March 14, 2025
Language: Английский
Citations
0