Root exudation of glyphosate in Eucalyptus urophylla S.T. Blake DOI
Rodrigo Eduardo Barros, Matheus Mendes Reis, Leonardo David Tuffi Santos

et al.

Journal of Environmental Science and Health Part B, Journal Year: 2024, Volume and Issue: unknown, P. 1 - 9

Published: Nov. 6, 2024

Glyphosate stands out in the eucalyptus management, which makes it essential to know its behavior, effects on plant, and possible environmental impacts. This study aimed identify quantify root exudation of glyphosate aminomethylphosphonic acid (AMPA) by Eucalyptus urophylla with chromatographic biological methods. The five doses were tested (0, 360, 720, 1080 1440 g a.e ha−1) E. plants. physiological intoxication evaluations performed after herbicide application. Water samples remaining from pots used for chemical quantification AMPA high-performance liquid chromatography. Cucurbita pepo plants as bioindicators water applying herbicide. increase promoted linear growth significantly reduced total dry mass production. had their photosynthetic, transpiratory, stomatal conductance rates increased. was not detected, but presence bioassay Root can result lesser action plant control cause contamination deeper soil layers.

Language: Английский

Aquatic ecotoxicity of glyphosate, its formulations, and co-formulants: evidence from 2010 to 2023 DOI Creative Commons
Szandra Klátyik, G. Simon,

Marianna Oláh

et al.

Environmental Sciences Europe, Journal Year: 2024, Volume and Issue: 36(1)

Published: Feb. 6, 2024

Abstract Glyphosate (GLY), the most widely used herbicide active ingredient (AI) in world, is frequently detected aquatic environments where it can affect non-target organisms. Globally, more than 2000 commercial GLY-based herbicides (GBHs) are to control weeds. Non-target organisms exposed complex pesticide formulations under real environmental conditions, but co-formulants contained GBHs classified as so-called inert and inactive ingredients terms of their biological effects. The main objective this comprehensive review compile results ecotoxicological studies on side-effects GLY, GBHs, formulating agents. Based demonstrated for a variety plant animal organisms, oxidative stress appears be major trigger these adverse effects, affecting integrity DNA other biochemical functions. Furthermore, there evidence impairment various physiological behavioral Adverse effects GLY have been observed even at very low concentrations. There also differences sensitivity tested, with similar lifestyles, habitats or identical taxa. typically investigate short-term single exposure GLY/GBH species, whilst reality multiple applications together pesticides common during cropping cycle. Moreover, interactions between GLY/GBHs contaminants rarely studied. Higher toxicity compared alone has often observed, demonstrating that highly toxic own markedly increase GBH formulation. possible impurities such heavy metals, cause additional problems environment food safety. widespread massive use leads increased hazards. In addition, need revision risk assessment system emphasized. According studies, current pollution by problematic cannot considered environmentally sustainable. It is, therefore, necessary least tighten permitted forms use.

Language: Английский

Citations

23

Immobilization of 4-MBA & Cu2+ on Au nanoparticles modified screen-printed electrode for glyphosate detection DOI

Wei Li,

Huarui Wu, Cong Wu

et al.

Talanta, Journal Year: 2025, Volume and Issue: 286, P. 127530 - 127530

Published: Jan. 10, 2025

Language: Английский

Citations

3

Recent advances in removing glyphosate herbicide and its aminomethylphosphonic acid metabolite in water DOI
Jordana Georgin, Dison S.P. Franco, Claudete Gindri Ramos

et al.

Journal of Molecular Liquids, Journal Year: 2024, Volume and Issue: 402, P. 124786 - 124786

Published: April 21, 2024

Language: Английский

Citations

18

Advances in green synthesis, modification strategies, and photocatalytic application of metal oxide nanoparticles for organic pollutants degradation: A comprehensive and in-depth review DOI
Zakariyya Uba Zango, Khalid Hassan Ibnaouf, Abdurrahman Garba

et al.

Journal of Molecular Liquids, Journal Year: 2025, Volume and Issue: unknown, P. 127497 - 127497

Published: April 1, 2025

Language: Английский

Citations

2

Characterization of Glyphosate Resistance and Degradation Profile of Caballeronia zhejiangensis CEIB S4-3 and Genes Involved in Its Degradation DOI Creative Commons

Manuel Isaac Morales-Olivares,

María Luisa Castrejón-Godínez,

Patricia Mussali-Galante

et al.

Microorganisms, Journal Year: 2025, Volume and Issue: 13(3), P. 651 - 651

Published: March 13, 2025

Herbicides are the most employed pesticides in agriculture worldwide; among them, glyphosate is successful herbicide molecule history. The extensive use of has been related to environmental pollution and toxic effects on non-target organisms. Effective remediation treatment alternatives must be developed reduce presence its adverse effects. Bioremediation using microorganisms proposed as a feasible alternative for treating pollution; due this, identifying characterizing capable biodegrading key task bioremediation polluted sites by this herbicide. This study characterized resistance profile degradation capacity bacterial strain Caballeronia zhejiangensis CEIB S4-3. According results growth inhibition assays agar plates, C. S4-3 can resist exposure high concentrations glyphosate, up 1600 mg/L glyphosate-based (GBH) formulation, 12,000 analytical-grade molecule. In assay liquid media, resisted all evaluated (25–400 mg/L). After 48 h exposure, GBH caused important (>80%) at between 100 400 mg/L, while inhibitions below 15% tested concentrations. Finally, was degrading 60% supplemented culture media (50 mg/L), when used sole carbon source, twelve hours; moreover, also degrade primary metabolite aminomethylphosphonic acid (AMPA). Genomic analysis revealed genes associated with two reported metabolic pathways degradation, sarcosine AMPA pathways. first report metabolism genus strain. from investigation demonstrate that exhibits significant potential biodegradation, suggesting applicability strategies targeting contaminant.

Language: Английский

Citations

1

Quantum Simulations and Experimental Insights into Glyphosate Adsorption Using Graphene-Based Nanomaterials DOI
Wanderson Souza Araújo, Celso R. C. Rêgo, Diego Guedes‐Sobrinho

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(24), P. 31500 - 31512

Published: June 6, 2024

The increasing global demand for food and agrarian development brings to light a dual issue concerning the use of substances that are crucial productivity yet can be harmful human health environment when misused. Herein, we combine insights from high-level quantum simulations experimental findings elucidate fundamental physicochemical mechanisms behind developing graphene-based nanomaterials adsorption emerging contaminants, with specific focus on pesticide glyphosate (GLY). We conducted comprehensive theoretical investigation supports as promising candidates detecting, sensing, capturing, removing GLY applications. By combining ab initio molecular dynamics density functional theory calculations, explored several chemical environments encountered by during its interaction substrates, including pristine punctual defect regions. Our results unveiled distinct behaviors: physisorption in doped graphene regions, chemisorption leading dissociation vacancy-type complex transformations involving capture N O atoms impurity-adsorbed graphene, resulting formation new GLY-derived compounds. were substantiated FTIR Raman spectroscopy, which proposed mechanism explaining nanomaterials. evaluation energies associated properties provides valuable into intricate nature these interactions, shedding potential applications guiding future investigations nanofilters water decontamination.

Language: Английский

Citations

5

Study on the deep removal of phosphorus in the by-product salts of glyphosate by sedimentation method DOI Creative Commons

Qisheng Wu,

Sen Wang, Jie Zhang

et al.

Desalination and Water Treatment, Journal Year: 2024, Volume and Issue: 317, P. 100271 - 100271

Published: Jan. 1, 2024

In this paper, phosphorus removal experiments were conducted on the by-product salt of glyphosate using a chemical precipitation process. The precipitates after characterized microscopical techniques, including scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), and energy-dispersive (EDS). Investigated efficiency polyaluminum chloride (PAC) coagulant evaluated influence various factors such as dosage, pH, settling time. experimental results indicate that when ratio dosage to total content is 10:1, with an initial solution pH 7 time 45 minutes, in can be reduced from 242 mg/L 6.49 mg/L, achieving rate 97.32%. composite polyacrylamide (PAM) parameters type polyacrylamide, selecting cationic molecular weight 300,000, 1:6, 7.5, 25 minutes reduce 1.94 99.20%.

Language: Английский

Citations

4

Bifunctional MOFs Nanozyme with Peroxidase Activity and Stimulus-responsive Fluorescent for Determination of Glyphosate DOI

Yumeng Guo,

Z. B. Chen,

Kai Zhang

et al.

Journal of Fluorescence, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 7, 2024

Language: Английский

Citations

4

Glyphosate photocatalytic degradation: Exploring trends, innovations and research gaps DOI Creative Commons
Felipe de J. Silerio-Vázquez, Manuel G. Roig, Luis A. González-Burciaga

et al.

Journal of Water Process Engineering, Journal Year: 2024, Volume and Issue: 66, P. 105948 - 105948

Published: Aug. 8, 2024

Glyphosate, a widely used herbicide, poses significant environmental and health risks due to its persistence in water systems potential carcinogenicity. Effective remediation strategies are critical. This study reviews recent advances the photocatalytic degradation of glyphosate, particularly via use solar visible light-active photocatalysts. These catalysts demonstrate an average efficiency 87.87 %, outperforming UV-active catalysts. Key advancements include hierarchical structures, Z-scheme mechanisms, composite materials, innovations such as doping with transition metals integrating plasmonic materials. approaches have enhanced light absorption, charge separation, overall performance. review also examines reactor designs, immobilized catalyst systems, magnetic photocatalysts, which represent steps toward practical applications. Significant research gaps remain, including need for standardized metrics, comprehensive pathway studies, scalable understanding influence matrix composition on treatment efficiency. The economic feasibility large-scale deployment, stability under real-world conditions, factors performance require further exploration. Future directions optimizing process parameters, exploring hybrid investigating processes natural developing cost-effective synthesis methods. emphasizes importance addressing these challenges develop sustainable efficient glyphosate Comprehensive comparisons between different sources, more studies utilizing real radiation, pilot-scale experiments essential advance application technologies. Furthermore, interdisciplinary collaboration will be key overcoming challenges.

Language: Английский

Citations

3

Cobalt ion-incorporated nanocrystalline spinel cubic zinc ferrite for targeted magnetic hyperthermia and sensing applications DOI Creative Commons
Mritunjoy Prasad Ghosh, Rahul Sonkar, Gongotree Phukan

et al.

RSC Advances, Journal Year: 2025, Volume and Issue: 15(17), P. 12964 - 12981

Published: Jan. 1, 2025

Cobalt ion-incorporated zinc ferrite nanoparticles have been tuned for controlled hyperthermia therapy and metribuzin herbicide sensing applications.

Language: Английский

Citations

0