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Language: Английский
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56Journal of Coordination Chemistry, Journal Year: 2022, Volume and Issue: 76(1), P. 28 - 44
Published: Dec. 26, 2022
AbstractA penta-coordinated dinuclear Zn(II) complex, [Zn2(L)(μ-PhCOO)(EtOH)] (1), and a hexa-coordinate tetranuclear Cd(II) [{Cd2(L)(EtOH)(η-OAc)}2]·2CH2Cl2 (2), have been synthesized by reactions of single-armed salamo-based ligand, H3L, two kinds transition metal salts, (Zn(NO3)2·6H2O Cd(OAc)2·2H2O), respectively. Complexes 1 2 characterized elemental analyses, single crystal X-ray diffraction, IR spectra UV-Vis spectra. Complex is composed totally deprotonated ligand (L)3- moiety, ions, one μ-PhCOO- counter-anion coordinated ethanol molecule. The unit packages the bridges adjacent ions molecule coordinates with Zn2 ion, so that both are slightly distorted trigonal bipyramidal configurations, τ5 values Zn1 0.86 0.65, consists discrete similar electroneutral tetra-nuclear units, A 2B, crystallized dichloromethane molecules. Each has symmetric structure made up completely moieties, four η-OAc- counter-anions Fluorescence properties Hirshfeld surfaces analyses studied as well.Keywords: Single-armed ligandcrystal structureHirshfeld surface analysisfluorescence property Disclosure statementNo potential conflict interest was reported authors.Additional informationFundingThis work supported Science Technology Program Gansu Province (21YF5GA057) National Natural Foundation China (21761018), which gratefully acknowledged.
Language: Английский
Citations
53