Applied Organometallic Chemistry,
Journal Year:
2024,
Volume and Issue:
38(11)
Published: Aug. 6, 2024
ABSTRACT
Temperature
in
various
scientific
and
industrial
applications
requires
accurate
detection
measurement.
Herein,
a
range
of
novel
isostructural
lanthanide‐based
metal–organic
frameworks
(Ln‐MOFs),
[Eu
x
Tb
2−x
(3,5‐pdc)
3
(phen)
2
(H
O)
]
n
(x
=
0,
Tb‐MOF
;
2,
Eu‐MOF
0.002,
0.010,
0.020,
0.040,
0.080,
Eu
‐MOF
),
were
solvothermally
synthesized
using
3,5‐pyridinedicarboxylic
acid
(3,5‐H
pdc)
1,10‐phenanthroline
as
ligands.
Based
on
binuclear
second
building
units,
Ln‐MOFs
exhibited
2D
layered
structure
with
sql
topology.
The
luminescent
properties
series
show
systematic
tuning
shifted
from
green
to
red
by
adjusting
the
ratio
3+
.
temperature
sensing
experiments
showed
that
0.020
1.980
self‐calibration
response
293–413
K,
achieving
maximum
relative
sensitivity
(
S
r
)
2.46%·K
−1
at
413
outscoring
many
state‐of‐the‐art
sensors
reported
literature.
This
study
poses
great
promise
newly
designed
for
ultra‐sensitive
diverse
large‐scale
applications.
Journal of Materials Chemistry B,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
Luminescent
NiMOF
demonstrated
remarkable
capabilities
in
efficient,
sensitive
and
intelligent
detection
of
3-NT
biomarker
6-PTU
thyroid
drug
urine
through
luminescence
quenching
effects.
RSC Advances,
Journal Year:
2024,
Volume and Issue:
14(41), P. 30201 - 30229
Published: Jan. 1, 2024
Recently,
metal-organic
frameworks
(MOFs)
have
attracted
much
attention
as
versatile
materials
for
drug
delivery
and
personalized
medicine.
MOFs
are
porous
structures
made
up
of
metal
ions
coupled
with
organic
ligands.
This
review
highlights
the
synthesis
techniques
used
to
design
specific
features
such
surface
area
pore
size,
encapsulation
within
not
only
improves
their
stability
solubility
but
also
allows
controlled
release
kinetics,
which
therapeutic
efficacy
minimizes
adverse
effects.
Furthermore,
it
discusses
challenges
potential
advantages
MOF-based
delivery,
MOF
stability,
biocompatibility,
scale-up
production.
With
further
advancements
in
synthesis,
functionalization
techniques,
understanding
interactions
using
biological
systems,
can
significant
promise
expanding
medicine
improving
patient
outcomes.
