Applied Organometallic Chemistry,
Journal Year:
2024,
Volume and Issue:
38(11)
Published: Aug. 6, 2024
ABSTRACT
Temperature
in
various
scientific
and
industrial
applications
requires
accurate
detection
measurement.
Herein,
a
range
of
novel
isostructural
lanthanide‐based
metal–organic
frameworks
(Ln‐MOFs),
[Eu
x
Tb
2−x
(3,5‐pdc)
3
(phen)
2
(H
O)
]
n
(x
=
0,
Tb‐MOF
;
2,
Eu‐MOF
0.002,
0.010,
0.020,
0.040,
0.080,
Eu
‐MOF
),
were
solvothermally
synthesized
using
3,5‐pyridinedicarboxylic
acid
(3,5‐H
pdc)
1,10‐phenanthroline
as
ligands.
Based
on
binuclear
second
building
units,
Ln‐MOFs
exhibited
2D
layered
structure
with
sql
topology.
The
luminescent
properties
series
show
systematic
tuning
shifted
from
green
to
red
by
adjusting
the
ratio
3+
.
temperature
sensing
experiments
showed
that
0.020
1.980
self‐calibration
response
293–413
K,
achieving
maximum
relative
sensitivity
(
S
r
)
2.46%·K
−1
at
413
outscoring
many
state‐of‐the‐art
sensors
reported
literature.
This
study
poses
great
promise
newly
designed
for
ultra‐sensitive
diverse
large‐scale
applications.
Dalton Transactions,
Journal Year:
2024,
Volume and Issue:
53(24), P. 10070 - 10074
Published: Jan. 1, 2024
A
new
Eu-MOF
is
prepared,
involving
in
situ
generation
of
oxalate
and
2,5-pyrazinedicarboxylate
ligands,
activated
at
different
temperatures
to
obtain
two
MOFs
(1a
1b),
which
1b
able
selectively
capture
C
2
H
from
/CO
.
Pharmaceutics,
Journal Year:
2024,
Volume and Issue:
16(6), P. 793 - 793
Published: June 11, 2024
Kidney
diseases
are
important
that
affect
human
health
worldwide.
According
to
the
2020
World
Health
Organization
(WHO)
report,
kidney
have
become
top
10
causes
of
death.
Strengthening
prevention,
primary
diagnosis,
and
action
kidney-related
is
great
significance
in
maintaining
improving
quality
life.
It
increasingly
challenging
address
clinical
needs
with
present
technologies
for
diagnosing
treating
renal
illness.
Fortunately,
metal-organic
frameworks
(MOFs)
shown
promise
diagnosis
treatment
diseases.
This
review
summarizes
research
progress
MOFs
disease
recent
years.
Firstly,
we
introduce
basic
structure
properties
MOFs.
Secondly,
focus
on
utilization
In
disease,
usually
designed
as
biosensors
detect
biomarkers
related
disease.
can
not
only
be
used
an
effective
adsorbent
uremic
toxins
during
hemodialysis
but
also
a
precise
intelligent
drug
delivery
carriers.
They
combined
nano-chelation
technology
solve
problem
imbalance
trace
elements
Finally,
describe
current
challenges
prospects
Applied Organometallic Chemistry,
Journal Year:
2024,
Volume and Issue:
38(11)
Published: Aug. 6, 2024
ABSTRACT
Temperature
in
various
scientific
and
industrial
applications
requires
accurate
detection
measurement.
Herein,
a
range
of
novel
isostructural
lanthanide‐based
metal–organic
frameworks
(Ln‐MOFs),
[Eu
x
Tb
2−x
(3,5‐pdc)
3
(phen)
2
(H
O)
]
n
(x
=
0,
Tb‐MOF
;
2,
Eu‐MOF
0.002,
0.010,
0.020,
0.040,
0.080,
Eu
‐MOF
),
were
solvothermally
synthesized
using
3,5‐pyridinedicarboxylic
acid
(3,5‐H
pdc)
1,10‐phenanthroline
as
ligands.
Based
on
binuclear
second
building
units,
Ln‐MOFs
exhibited
2D
layered
structure
with
sql
topology.
The
luminescent
properties
series
show
systematic
tuning
shifted
from
green
to
red
by
adjusting
the
ratio
3+
.
temperature
sensing
experiments
showed
that
0.020
1.980
self‐calibration
response
293–413
K,
achieving
maximum
relative
sensitivity
(
S
r
)
2.46%·K
−1
at
413
outscoring
many
state‐of‐the‐art
sensors
reported
literature.
This
study
poses
great
promise
newly
designed
for
ultra‐sensitive
diverse
large‐scale
applications.
