Highly-toughened PLLA/PVA biodegradable blends: graft copolymer tailored crystallization and phase morphology

Polymer, Journal Year: 2024, Volume and Issue: 312, P. 127606 - 127606

Published: Sept. 7, 2024

Language: Английский

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Synthesis of a phosphorus-containing L-lactic acid-based flame-retardant plasticizer for simultaneously enhancing flexibility and flame retardancy of poly(lactic acid)

International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: 279, P. 135420 - 135420

Published: Sept. 7, 2024

Language: Английский

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3D-Printed PLA/PEG Bone Scaffold: Body-Adaptive Thermally Responsive Shape Memory and Enhanced Biological Performance

Surfaces and Interfaces, Journal Year: 2024, Volume and Issue: unknown, P. 105712 - 105712

Published: Dec. 1, 2024

Language: Английский

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Phosphorus-nitrogen-containing flame-retardant plasticizers derived from L-lactic acid for poly (lactic acid) improved toughness, flame retardancy and crystallization

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 157143 - 157143

Published: Oct. 1, 2024

Language: Английский

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Tuned flexibility with phenethyl esters plasticized polylactic acid

Materials Today Communications, Journal Year: 2025, Volume and Issue: unknown, P. 112437 - 112437

Published: April 1, 2025

Language: Английский

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Eco-friendly additives for biodegradable polyesters: Recent progress in performance optimization and environmental impact reduction

Sustainable materials and technologies, Journal Year: 2025, Volume and Issue: unknown, P. e01395 - e01395

Published: April 1, 2025

Language: Английский

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Naturally occurring eugenyl acetate as biobased plasticizer for sustainable polylactide formulations with improved toughness

International Journal of Biological Macromolecules, Journal Year: 2025, Volume and Issue: 311, P. 144152 - 144152

Published: May 12, 2025

In this study, we explore the potential of eugenyl acetate (EAc), a naturally occurring ester eugenol, as biobased plasticizer to overcome intrinsic brittleness polylactide (PLA) derived from starch. A theoretical assessment miscibility between PLA and EAc is carried out. Our findings demonstrate that shows exceptional with PLA, confirmed by their similar solubility parameters (EAc-19.83 MPa1/2, PLA-20.66 MPa1/2), an interaction parameter χ = 0.39. The incorporation improves ductility strain at break increasing 427.7 % 20 wt% EAc, compared brittle 10.2 for neat PLA. plasticizing effect also leads considerable reduction in glass transition temperature 60.4 °C 35.7 EAc. Scanning electron microscopy reveals no phase separation development plastic deformation formulations 15-20 Additionally, all plasticized exhibit full biodegradation controlled compost conditions <8 weeks. These results contribute advancing PLA-based are both high-performance eco-friendly, supporting broader goals sustainable polymer science.

Language: Английский

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Towards sustainable bioplasticizers from biomass to polymers applications: A review

Sustainable materials and technologies, Journal Year: 2024, Volume and Issue: unknown, P. e01194 - e01194

Published: Nov. 1, 2024

Language: Английский

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Menthol and organic acid-based hydrophobic deep eutectic solvents as plasticizers in biodegradable poly (lactic acid) films

Food Packaging and Shelf Life, Journal Year: 2024, Volume and Issue: 47, P. 101415 - 101415

Published: Dec. 13, 2024

Language: Английский

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