International Journal of Hydrogen Energy, Journal Year: 2021, Volume and Issue: 46(13), P. 8932 - 8949
Published: Jan. 29, 2021
Language: Английский
International Journal of Hydrogen Energy, Journal Year: 2021, Volume and Issue: 46(13), P. 8932 - 8949
Published: Jan. 29, 2021
Language: Английский
International Journal of Hydrogen Energy, Journal Year: 2020, Volume and Issue: 45(58), P. 33352 - 33369
Published: Sept. 26, 2020
Language: Английский
Citations
35Applied Catalysis A General, Journal Year: 2021, Volume and Issue: 614, P. 118051 - 118051
Published: Feb. 19, 2021
Language: Английский
Citations
29Energy Conversion and Management, Journal Year: 2024, Volume and Issue: 306, P. 118305 - 118305
Published: March 15, 2024
Language: Английский
Citations
4Industrial & Engineering Chemistry Research, Journal Year: 2024, Volume and Issue: 63(28), P. 12459 - 12467
Published: July 2, 2024
The presence of ethanol as an impurity in industrial methanol significantly degrades the quality downstream products. Addressing challenge suppressing formation remains crucial synthesis methanol. In this context, we systematically characterized a series commercial catalysts and evaluated their catalytic performance for to elucidate relationship between catalyst structure selectivity. Our tests indicate that Cu–Zn–Al (NG), enhanced with ZrO2 promoter, can effectively inhibit formation, reducing it approximately 580 ppm after 1000 h. promoter stabilizes Cu0, ensuring is highly dispersed maintains homogeneous structure, which pivotal catalyst's exceptional performance. Analysis through temperature-programmed desorption density functional theory (DFT) demonstrates high dispersity Cu0 enhances adsorption CO H2. Additionally, uniform active site contributes increased selectivity while simultaneously formation. This study underscores significant potential incorporating suppress production under operating conditions.
Language: Английский
Citations
4International Journal of Hydrogen Energy, Journal Year: 2021, Volume and Issue: 46(13), P. 8932 - 8949
Published: Jan. 29, 2021
Language: Английский
Citations
26